N,N',N'',N'''-tetra(naphthalen-1-yl)-N,N',N'',N'''-tetraphenylpyrene-1,3,6,8-tetraamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: N,N',N'',N'''-tetra(naphthalen-1-yl)-N,N',N'',N'''-tetraphenylpyrene-1,3,6,8-tetraamine
• 英文别名: 1-N,3-N,6-N,8-N-tetranaphthalen-1-yl-1-N,3-N,6-N,8-N-tetraphenylpyrene-1,3,6,8-tetramine
• 化学式: C₈₀H₅₄N₄
• 分子量: 1071.34
• InChiKey: KAYNZDWNIRHUGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  23
• 重原子数：
  84
• 可旋转键数：
  12
• 环数：
  16.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N-苯基-1-萘胺 、 1,3,6,8-四溴芘 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以52%的产率得到N,N',N'',N'''-tetra(naphthalen-1-yl)-N,N',N'',N'''-tetraphenylpyrene-1,3,6,8-tetraamine
  参考文献：
  名称：

  Tetrasubstituted-pyrene derivatives for electroluminescent application

  摘要：

  Tetrasubstituted-pyrenes containing peripheral diarylamines (1-4) or fluorenes (5-6) have been synthesized. These compounds are highly fluorescent and possess high morphological stability and thermal stability. Compounds containing peripheral arylamines (1-3) can be used as the hole-transport and green-emitting materials for two-layered electroluminescent devices. Compounds with peripheral fluorenes (5-6) are efficient blue emitters and exhibit ambipolar carrier-transport characteristics with high electron mobilities (10(-3)-10(-2) cm(2)/V s) and high hole mobilities (>10(-3) cm(2)/V s). Non-doped blue-emitting devices with promising electroluminescent performance (i.e., high efficiency and narrow/saturated emission) can be achieved using fluorene-substituted pyrenes as either the holetransport/emitting layer or the electron-transport/emitting layer in the two-layered devices. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.orgel.2014.06.003

文献信息

• 1,3,6,8 tetrasubstituted pyrene compound, organic EL element using the same, and organic EL display using the same
  申请人：FUJITSU LIMITED

  公开号：EP1403354A1

  公开（公告）日：2004-03-31

  The present invention aims to provide an organic EL element having excellent light-emitting efficiency, emission luminance and color purity of green light. The organic EL element contains an organic thin film layer interposed between a positive electrode and a negative electrode, this organic thin film layer comprising a 1,3,6,8-tetrasubstituted pyrene compound represented by the following formula (1) as a luminescent material:    wherein R1 to R4 may be the same or different, and represent a group represented by the following formula (2):    wherein R5 and R6 may be the same or different, and represent a hydrogen atom or a substituent group.

  本发明旨在提供一种有机电致发光元件，它具有优异的发光效率、发射亮度和绿光色纯度。该有机电致发光元件包含一个夹在正极和负极之间的有机薄膜层，该有机薄膜层包含由下式（1）表示的 1，3，6，8-四取代芘化合物作为发光材料： 其中 R1 至 R4 可以相同或不同，并代表下式（2）所代表的基团： 其中 R5 和 R6 可以相同或不同，并代表氢原子或取代基。
• 1,3,6,8-Tetrasubstituted pyrene compound, organic EL element using the same, and organic EL display using the same
  申请人：FUJITSU LIMITED

  公开号：US20040053069A1

  公开（公告）日：2004-03-18

  The present invention aims to provide an organic EL element having excellent light-emitting efficiency, emission luminance and color purity of green light. The organic EL element contains an organic thin film layer interposed between a positive electrode and a negative electrode, this organic thin film layer comprising a 1,3,6,8-tetrasubstituted pyrene compound represented by the following formula (1) as a luminescent material: 1 wherein R 1 to R 4 may be the same or different, and represent a group represented by the following formula (2): 2 wherein R 5 and R 6 may be the same or different, and represent a hydrogen atom or a substituent group.
• Organic electroluminescence element
  申请人：Kinoshita Masaru

  公开号：US20080174236A1

  公开（公告）日：2008-07-24

  An organic electroluminescence element includes at least a light-emitting layer between a pair of electrodes, wherein the light-emitting layer is divided into at least three layers, an intermediate layer containing an electron blocking material or a hole blocking material is disposed between the divided light-emitting layers, an Ea value of the electron blocking material is smaller than an Ea value of a host material of the divided light-emitting layer adjacent on a cathode side or an Ip value of the hole blocking material is larger than an Ip value of a host material of the divided light-emitting layer adjacent on the anode side of the intermediate layer, and a difference of ΔEa or ΔIp is controlled to specific range.
• PYRENE POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Fukushima Daisuke

  公开号：US20100109517A1

  公开（公告）日：2010-05-06

  A polymer compound comprising a constitutional unit of the formula (1), and a repeating unit of any of the formulae (2) to (4): (wherein, x3, y1, y2, z1 to z3 are 0 or 1. y3 represents an integer of 0 to 2. u represents an integer of 0 to 8. Z represents a pyrene residue, Ar 1 represents an arylene group or di-valent heterocyclic group, and Ar 2 represents an aryl group or mono-valent heterocyclic group.)
• US9012034B2
  申请人：——

  公开号：US9012034B2

  公开（公告）日：2015-04-21