N¹,N⁴-di(naphthalen-1-yl)-N¹,N⁴-diphenylbenzene-1,4-diamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N¹,N⁴-di(naphthalen-1-yl)-N¹,N⁴-diphenylbenzene-1,4-diamine
• 英文别名: N,N'-dinaphthyl-N,N'-diphenyl-1,4-phenylenediamine；1-N,4-N-dinaphthalen-1-yl-1-N,4-N-diphenylbenzene-1,4-diamine
• 化学式: C₃₈H₂₈N₂
• 分子量: 512.654
• InChiKey: QPXAXMJMFWSMDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  对溴碘苯 、 N-苯基-1-萘胺 在 copper(l) iodide 、 sodium t-butanolate 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以94%的产率得到N-(4-溴苯基)-N-苯基-1-萘胺
  参考文献：
  名称：

  Chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or ligand-free copper catalysts

  摘要：

  We report the chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or a ligand-free copper catalyst. The reactions by these two types of catalysts proceeded with a high chemoselectivity and afforded monobrominated triarylamines in good yields. These products are useful intermediates for the synthesis of unsymmetrical bistriarylamines. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2015.01.028

文献信息

• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND DIAGNOSTIC COMPOSITION INCLUDING THE ORGANOMETALLIC COMPOUND
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20200044166A1

  公开（公告）日：2020-02-06

  An organometallic compound represented by Formula 1: wherein, Formula 1, R 1 to R 10 and A 1 to A 7 are the same as described in the detailed description of the specification.

  一种由化学式1表示的有机金属化合物： 其中，化学式1中的R1至R10和A1至A7的详细描述与规范中的描述相同。
• ORGANIC ELECTROLUMINESCENT ELEMENT AND DISPLAY DEVICE
  申请人：SONY CORPORATION

  公开号：US20150171356A1

  公开（公告）日：2015-06-18

  An organic electroluminescence device that includes, between an anode 41 and a cathode 42 , an organic layer stacked structure 43 that comprises stacked plural emitting layers that emit light of different colors, wherein the organic electroluminescent device comprises, between the emitting layers, at least one intermediate layer that comprises a compound represented by the following formula (1) in which at least one of Ar 1 , Ar 2 and Ar 3 is a group represented by the following formula (2):
• ORGANIC LIGHT-EMITTING ELEMENT AND DISPLAY APPARATUS
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20150333279A1

  公开（公告）日：2015-11-19

  Provided is an organic light-emitting element having high luminous efficiency and a long lifetime. The organic light-emitting element includes a pair of electrodes and an organic compound layer placed between the pair of electrodes, in which the organic compound layer includes an iridium complex having a benzo[f]isoquinoline of a specific structure as a ligand and a metal complex compound of a specific structure.
• US7396599B2
  申请人：——

  公开号：US7396599B2

  公开（公告）日：2008-07-08
• US8530062B2
  申请人：——

  公开号：US8530062B2

  公开（公告）日：2013-09-10