ethyl N-trifluoroacetyl-N-(dichlorophosphonomethyl)glycinate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: ethyl N-trifluoroacetyl-N-(dichlorophosphonomethyl)glycinate
• 英文别名: [Dichloro-[(2-ethoxy-2-oxoethyl)-(2,2,2-trifluoroacetyl)amino]methyl]phosphonic acid
• 化学式: C₇H₉Cl₂F₃NO₆P
• 分子量: 362.027
• InChiKey: XDCIZODHDDBBJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  20
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  104
• 氢给体数：
  2
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  ethyl N-trifluoroacetyl-N-(dichlorophosphonomethyl)glycinate 在 三乙胺 作用下， 生成 ethyl N-trifluoroacetyl-N-(diallyloxyphosphonomethyl)glycinate
  参考文献：
  名称：

  Ester derivatives of n-trifluoroacetyl-n-phosphonomethylglycine and the

  摘要：

  这项披露涉及N-三氟乙酰-N-磷酰甲基甘氨酸的酯衍生物，包含相同物质的除草剂组合物以及其除草用途。N-三氟乙酰-N-磷酰甲基甘氨酸的酯衍生物可用作除草剂。

  公开号：

  US04218235A1

文献信息

• Thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine
  申请人：Monsanto Company

  公开号：US04175946A1

  公开（公告）日：1979-11-27

  This disclosure relates to thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters, to herbicidal compositions containing same and to the herbicidal use thereof. The thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters are useful as herbicides.

  这项披露涉及N-三氟乙酰-N-磷酸甲基甘氨酸酯的硫代衍生物，含有相同成分的除草剂组合物，以及其除草用途。N-三氟乙酰-N-磷酸甲基甘氨酸酯的硫代衍生物可用作除草剂。
• Amide and hydrazide derivatives of
  申请人：Monsanto Company

  公开号：US04353731A1

  公开（公告）日：1982-10-12

  This disclosure relates to alkyl N-trifluoroacetyl-N-phosphonomethylglycine amide and hydrazide derivatives, to herbicidal compositions containing same and to the herbicidal use thereof. These amide and hydrazide derivatives are useful as pre-emergent and/or post-emergent herbicides.

  本公开涉及烷基N-三氟乙酰-N-磷酰甲基甘氨酸酰胺和肼衍生物，以及含有它们的除草剂组合物，以及其除草用途。这些酰胺和肼衍生物可用作前除草剂和/或后除草剂。
• Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the
  申请人：Monsanto Company

  公开号：US04180394A1

  公开（公告）日：1979-12-25

  This disclosure relates to derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates wherein different moieties are attached to the phosphorus atom, to herbicidal compositions containing same and to the herbicidal use thereof.

  本披露涉及N-三氟乙酰-N-磷酰甲基甘氨酸衍生物，其中不同的基团附着在磷原子上，以及包含它们的除草剂组合物和其除草用途。
• Thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine and their herbicidal use
  申请人：MONSANTO COMPANY

  公开号：EP0008158A1

  公开（公告）日：1980-02-20

  This disclosure relates to thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters, to herbicidal compositions containing same and to the herbicidal use thereof. The thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters are useful as herbicides. The novel N-trifluoroacetyl-N-phosphonomethyl-glycinate thio derivatives of this invention are those having the formula wherein R is an alkyl group containing from 1 to 10 carbon atoms, a chloro lower alkyl group containing from 1 to 4 carbon atoms and 1 to 3 chlorine groups, a lower alkoxy lower alkyl group containing from 3 to 6 carbon atoms or an alkoxyalkoxyalkyl group containing from 5 to 9 carbon atoms and R' is a member of the group consisting of lower alkylthio. lower alkenylthio, benzylthio, phenylthio, or substituted phenylthio wherein the phenyl group contains 1 to 2 substituents selected from the group consisting of halo, lower alkyl and lower alkoxy.

  本公开涉及 N-三氟乙酰基-N-膦酰甲基甘氨酸酯的硫代衍生物、含有这些衍生物的除草组合物及其除草用途。N- 三氟乙酰基-N-膦酰甲基甘氨酸酯的硫代衍生物可用作除草剂。 本发明的新型 N-三氟乙酰基-N-膦酰甲基甘氨酸硫代衍生物是具有以下式子的衍生物 其中 R 是含 1 至 10 个碳原子的烷基、含 1 至 4 个碳原子和 1 至 3 个氯基团的氯代低 级烷基、含 3 至 6 个碳原子的低级烷氧基低级烷基或含 5 至 9 个碳原子的烷氧基烷基，而 R' 是由低级烷硫基、低级烯硫基、苄硫基、苯硫基或取代苯硫基组成的组的成员，其中苯基含有 1 至 2 个选自卤代、低级烷基和低级烷氧基组成的组的取代基。
• Amide and hydrazide derivatives of N-trifluoracetyl-N-phosphonomethylglycine, herbicidal compositions and their use
  申请人：MONSANTO COMPANY

  公开号：EP0008852A1

  公开（公告）日：1980-03-19

  This disclosure relates to alkyl N-trifluoroacetyl-N-phosphonomethylglycine amide and hydrazide derivatives, to herbicidal compositions containing same and to the herbicidal use thereof. These amide and hydrazide derivatives are useful as pre-emergent and/or post-emergent herbicides. The novel N-trifluoroacetyl-N-phosphonomethyl- glycinate amide and hydrazide derivatives of this invention are those havina the formula wherein R is an alkyl group of from 1 to 10 carbon atoms, a chloro lower alkyl group, a lower alkoxy lower alkyl group containing from 3 to 6 carbon atoms or a lower alkoxy lower alkoxy lower alkyl group containing from 5 to 9 carbon atoms, R' is hydrogen, lower alkyl, lower alkenyl or lower alkynyl, Z is a member of the class consisting of alkyl of from 1 to 6 carbon atoms, alkenyl of from 2 to 6 carbon atoms, alkynyl of from 3 to 6 carbon atoms, cycloalkyl containing from 3 to 7 carbon atoms or a R2 N - R3 group wherein R2 is lower alkyl, phenyl or substituted phenyl and R3 is hydrogen or lower alkyl and together with the nitrogen atom R2 and R3 can form a heterocyclic ring.

  本公开涉及烷基 N-三氟乙酰基-N-膦酰甲基甘氨酸酰胺和酰肼衍生物、含有这些衍生物的除草组合物及其除草用途。这些酰胺和酰肼衍生物可用作芽前和/或芽后除草剂。 本发明的新型 N-三氟乙酰基-N-膦酰甲基甘氨酸酰胺和酰肼衍生物是那些具有以下式子的衍生物 其中 R 是含 1 至 10 个碳原子的烷基、氯代低级烷基、含 3 至 6 个碳原子的低级烷氧基或含 5 至 9 个碳原子的低级烷氧基，R'是氢、低级烷基、低级烯基或低级炔基，Z 是由含 1 至 6 个碳原子的烷基、含 2 至 6 个碳原子的烯基、含 1 至 10 个碳原子的氯代低级烷基、含 3 至 6 个碳原子的低级烷氧基或含 5 至 9 个碳原子的低级烷氧基组成的类别的成员、R'是氢、低级烷基、低级烯基或低级炔基，Z 是由 1-6 个碳原子的烷基、2-6 个碳原子的烯基、3-6 个碳原子的炔基、含 3-7 个碳原子的环烷基或 R2 N - R3 基团（其中 R2 是低级烷基、苯基或取代苯基，R3 是氢或低级烷基，与氮原子 R2 和 R3 一起可形成杂环）组成的类别的成员。