pentadecyl caproate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: pentadecyl caproate
• 英文别名: hexanoic acid pentadecyl ester；Hexansaeure-pentadecylester；Pentadecyl hexanoate
• 化学式: C₂₁H₄₂O₂
• 分子量: 326.563
• InChiKey: SEUYDDRXLZSABP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  23
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-十五醇 、 己酸 在 silphos 作用下， 反应 0.08h， 以90%的产率得到pentadecyl caproate
  参考文献：
  名称：

  在作为多相膦试剂的 Silphos [PCl3-n(SiO2)n] 存在下羧酸和醇的无溶剂酯化

  摘要：

  摘要 报道了一种使用多相膦试剂 silphos [PCl3-n(SiO2)n] 从各种芳香族和脂肪酸与伯醇、仲醇和叔醇制备酯的有效无溶剂方法，收率良好。图形概要

  DOI：

  10.1080/00397911.2011.555903

文献信息

• Temperature-sensitive color-memorizing microcapsulated pigment
  申请人：THE PILOT INK CO., LTD.

  公开号：EP0708153A1

  公开（公告）日：1996-04-24

  A microcapsulated pigment contains, as reaction media one or more specific aliphatic acid alcohol esters obtained from monohydric aliphatic alcohols having odd numbers of carbon atoms and aliphatic carboxylic acids, these reaction media in a homogenious compatible state with chromatic components are occluded in microcapsules to obtain characteristics of thermochromism with a hysteresis range (segment HG) from 8°C to 30°C.

  微胶囊颜料含有一种或多种特定的脂肪族酸醇酯作为反应介质，这些反应介质是从具有奇数碳原子数的一元脂肪族醇和脂肪族羧酸中获得的，这些反应介质在与色素成分均匀相容的状态下被包裹在微胶囊中，从而获得热致变色的特性，其滞后范围（HG 段）为 8°C 至 30°C。
• Thermochromic microencapsulated pigments
  申请人：THE PILOT INK CO., LTD.

  公开号：EP1084860A2

  公开（公告）日：2001-03-21

  Disclosed is a thermochromic microencapsulated pigment which comprises as four essential components (a) an electron-donating chromatic organic compound, (b) an electron-accepting compound, (c) a reaction medium determining the temperatures at which the color reactions of component (a) with component (b) take place, and (d) a color change temperature regulator, the color change temperature regulator (d) comprising one or more compounds selected from the group consisting of esters, alcohols, ketones, acid amides, hydrocarbons, and fatty acids and having a melting point Y (°C) satisfying the relationship (X+30)°C≤Y≤200°C, wherein X (°C) is the melting point of component (c), and the four essential components being microencapsulated.

  本发明公开了一种热致变色微胶囊颜料，它由四种基本成分组成：(a) 一种电子供色有机化合物；(b) 一种电子受色化合物；(c) 一种决定成分(a)与成分(b)发生颜色反应的温度的反应介质；(d) 一种变色温度调节剂、变色温度调节剂(d)包括一种或多种从酯、醇、酮、酸酰胺、烃和脂肪酸组成的组中选出的化合物，其熔点 Y(℃)满足(X+30)℃≤Y≤200℃的关系，其中 X(℃)是组分(c)的熔点，四种基本组分被微胶囊化。
• Thermally color-developing reversibly thermochromic pigment
  申请人：THE PILOT INK CO., LTD.

  公开号：EP1323540A2

  公开（公告）日：2003-07-02

  A thermally color-developing reversibly thermochromic pigment which shows a uniform color density in the coloring temperature range and also shows an optional ΔH value within a range of from 3 to 40°C of the ΔH value (hysteresis temperature range) in a temperature-color density curve. Thermally color-developing reversibly thermochromic pigments of a three component system having a ΔH value of within a range of from 7 to 40°C in which at least essential three components including (a) an electron-donating chromic organic compound, (b) a specified compound selected from gallic acid esters and (c) a reaction medium selected from alcohols, esters, ketones and hydrocarbons, which reversibly generates color reactions of both of the compounds within a specified temperature range and has a melting point of less than 50°C, are microencapsulated, and of a four component system having a ΔH value of within a range of from 3 to 25°C in which a compound (d) selected from monomer compounds having a melting point of 50°C or more or polymer compounds having a softening point of 70°C or more is added to the three component system.

  一种热显色可逆热致变色颜料，在着色温度范围内显示出均匀的色密度，同时在温度-色密度曲线上显示出ΔH 值在ΔH 值的 3 至 40°C 范围内（滞后温度范围）的可选ΔH 值。热显色可逆热致变色颜料的三组分体系，其 ΔH 值在 7 至 40°C 范围内，其中至少必不可少的三组分包括：(a) 电子负载铬有机化合物；(b) 选自没食子酸酯的特定化合物；(c) 选自醇、酯、酮和烃的反应介质、(c)选自醇、酯、酮和碳氢化合物的反应介质；(d)选自熔点为 50℃或以上的单体化合物或软化点为 70℃或以上的聚合物化合物的化合物；(e)选自熔点为 50℃或以上的单体化合物或软化点为 70℃或以上的聚合物化合物的反应介质。
• MICRO-REACTOR FOR TESTING, GENETIC TESTING APPARATUS, AND GENETIC TESTING METHOD
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1746158A1

  公开（公告）日：2007-01-24

  A micro-reactor for analyzing a sample, comprises (1) a plate-shaped chip; (2) a plurality of reagent storage sections each having a chamber to store respective agents; (3) a reagent mixing section to mix plural reagents fed from the plurality of reagent storage sections so as to produce a mixed reagent; (4) a sample receiving section having an injection port through which a sample is injected from outside; and (5) a reacting section to mix and react the mixed reagent fed from the reagent mixing section and the sample fed from the sample receiving section. The plurality of reagent storage sections, the reagent mixing section, the sample receiving section and the reacting section are incorporated in the chip and are connected through flow paths, and the reagent mixing section includes a feed-out preventing mechanism to prevent an initially-mixed reagent from being fed out to the reacting section.

  一种用于分析样品的微反应器，包括：(1) 一个板状芯片；(2) 多个试剂存储部，每个试剂存储部都有一个腔室，用于存储各自的试剂；(3) 一个试剂混合部，用于混合从多个试剂存储部输入的多个试剂，以产生混合试剂；(4) 一个样品接收部，该接收部有一个注入口，可从外部注入样品；以及 (5) 一个反应部，用于将从试剂混合部输入的混合试剂和从样品接收部输入的样品混合并进行反应。多个试剂存储部分、试剂混合部分、样品接收部分和反应部分被集成在芯片中，并通过流路连接，试剂混合部分包括一个防止馈出机构，以防止最初混合的试剂被馈送到反应部分。
• MICRO OVERALL ANALYSIS SYSTEM, INSPECTION CHIP, AND INSPECTION METHOD
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1887363A1

  公开（公告）日：2008-02-13

  A micro integrated analysis system includes a testing chip, system main body and heat-insulating section. The chip has a pump connecting section to communicate with micro pumps; a mixing flow path for mixing a specimen and reagent and for reaction processing by heating; and a testing flow path for performing a predetermined test of a mixed solution heated and processed for reaction. The system main body has a holding section to hold the testing chip; micro pumps for injecting a specimen and reagent; a heating section for heating the mixing flow path; and a detection section for performing a test in the testing flow path. The heat-insulating section insulates flow path portions continuing from both an inlet end and outlet end of a heated flow path area of the mixing flow path, from heat of the heating section so as to prevent a rise in temperature.

  微型综合分析系统包括测试芯片、系统主体和隔热部分。芯片有一个泵连接部分，用于与微型泵通信；一个混合流路，用于混合试样和试剂，并通过加热进行反应处理；以及一个测试流路，用于对加热和反应处理的混合溶液进行预定测试。系统主体具有用于容纳测试芯片的容纳部；用于注入试样和试剂的微型泵；用于加热混合流路的加热部；以及用于在测试流路中执行测试的检测部。隔热部分将从混合流路的加热流路区域的入口端和出口端延伸的流路部分与加热部分的热量隔开，以防止温度升高。