二氯甲基环己烯 | 51317-57-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 中文名称: 二氯甲基环己烯
• 英文名称: dichloromethyl-cyclohexene
• 英文别名: 1-Dichlormethyl-cyclohexen；1-(Dichloromethyl)cyclohexene；1-(dichloromethyl)cyclohexene
• CAS: 51317-57-8
• 化学式: C₇H₁₀Cl₂
• 分子量: 165.062
• InChiKey: OKYQHVUHPRMDBI-UHFFFAOYSA-N

物化性质

• 沸点：
  167.9±33.0 °C(Predicted)
• 密度：
  1.182±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  氯仿 、 环己烯 生成 四氯化碳 、 7,7-双氯环庚烷 、 氯代环己烷 、 二氯甲基环己烷 、 二氯甲基环己烯 、 环己烷,(氯甲基)- 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Sonolysis of Chloroform

  摘要：

  AbstractChloroform is decomposed by irradiation with ultrasonic waves to yield a large number of products. The major products are various unsaturated compounds. Decomposition occurs only in the presence of a monoatomic‐ or diatomic gas. Free radicals and carbenes are postulated as intermediates of sonolysis which can only be scavenged by volatile additives such as O2 or c‐hexene. In the presence of 10% c‐hexene, the rate of sonolysis of chloroform is increased and various additional products are formed. Pure c‐hexene is decomposed at a much lower rate than chloroform. The sonolysis of chloroform proceeds at a rate comparable to that of water.

  DOI：

  10.1002/bbpc.198400048

文献信息

• Sonolysis of Chloroform
  作者：A. Henglein、Ch.-H. Fischer

  DOI：10.1002/bbpc.198400048

  日期：1984.12

  AbstractChloroform is decomposed by irradiation with ultrasonic waves to yield a large number of products. The major products are various unsaturated compounds. Decomposition occurs only in the presence of a monoatomic‐ or diatomic gas. Free radicals and carbenes are postulated as intermediates of sonolysis which can only be scavenged by volatile additives such as O2 or c‐hexene. In the presence of 10% c‐hexene, the rate of sonolysis of chloroform is increased and various additional products are formed. Pure c‐hexene is decomposed at a much lower rate than chloroform. The sonolysis of chloroform proceeds at a rate comparable to that of water.