二环[2.2.1]庚烷-2-磺酸,酰肼 | 97325-36-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 二环[2.2.1]庚烷-2-磺酸,酰肼
• 英文名称: 2-propenoic acid 2-hydroxy-1,1,2-trimethylpropyl ester
• 英文别名: (3-Hydroxy-2,3-dimethylbutan-2-yl) prop-2-enoate
• CAS: 97325-36-5
• 化学式: C₉H₁₆O₃
• 分子量: 172.224
• InChiKey: WFWOOWWOUDZVSA-UHFFFAOYSA-N

物化性质

• 沸点：
  236.8±23.0 °C(Predicted)
• 密度：
  0.993±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2916129000

SDS

Name:	Pinacol mono acylate Material Safety Data Sheet
Synonym:	None Known
CAS:	97325-36-5

Section 1 - Chemical Product MSDS Name:Pinacol mono acylate Material Safety Data Sheet
Synonym:None Known

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
97325-36-5	Pinacol mono acylate	100	unlisted

Hazard Symbols: XN
Risk Phrases: 20/21/22

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Harmful if inhaled.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Clear liquid
Color: Not available.
Odor: characteristic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 205 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H16O3
Molecular Weight: 172.11

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 97325-36-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Pinacol mono acylate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Products which are considered hazardous for supply are classified as Special Waste and the disposal of such chemicals is covered by regulations which may vary according to location. Contact a specialist disposal company or the local waste regulator for advice. Empty containers must be decontaminated before returning for recycling.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 97325-36-5: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 97325-36-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 97325-36-5 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  四氟乙烯 、 NB-F-OH 、 2-甲基-2-金刚烷醇丙烯酸酯 、 1,3-金刚烷二醇单丙烯酸酯 、 二环[2.2.1]庚烷-2-磺酸,酰肼 生成 TFE/NB-F-OH/PinAc/HAdA/MAdA pentapolymer
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Hydrophobe und/oder abhäsive Masse, reaktive Verdünner, Weichmacher und deren Verwendung
  申请人：Hinterwaldner, Rudolf

  公开号：EP0408085A2

  公开（公告）日：1991-01-16

  Gegenstand der Erfindung sind neue hydrophobe und/oder abhäsive Massen, reaktive Verdünner, Weichmacher mit einem Gehalt an einer monomeren, oligomeren und/oder polymeren methylgruppenreichen Kohlenwasserstoffverbindung und/oder deren Derivate mit der allgemeinen Formel worin bedeuten: R1, R2, R3 und R4 = H, -CH3 und/oder -CH2-CH3 A und B = H, -CH3, -CH2-CH3 und/oder ein Rest der vorstehenden allgemeinen Formel 2, und n = eine ganze Zahl zwischen 0 und 20.000.000, vorzugsweise 50 bis 1.000.000, insbesondere 50 bis 500.000, enthält und der Methylgruppengehalt mindestens 2,0, vorzugsweise 3.0 bis 4,0 Mol pro Monomer bzw. Monomereinheit beträgt. Mit diesen neuen methylgruppenreichen Verbindungen lassen sich auf wirtschaftliche Weise viele anorganische, metallorganische und/oder organische Stoffe hydrophob und/oder abhäsiv ausrüsten oder damit Filme oder Folien mit hydrophoben und/oder abhäsiven Eigenschaften herstellen. Die flüssigen Verbindungen können auch als reaktive Verdünner und/oder Weichmacher eingesetzt werden.

  本发明涉及新的疏水性和/或粘合性组合物、活性稀释剂、增塑剂，其中含有通式如下的富含甲基基团的单体、低聚和/或聚合烃化合物和/或其衍生物 其中 R1、R2、R3 和 R4 = H、-CH3 和/或 -CH2-CH3 A 和 B = H、-CH3、-CH2-CH3 和/或上述通式 2 的基团，n = 0 至 20,000,000 之间的整数，最好是 50 至 1,000,000，特别是 50 至 500,000，每个单体或单体单元的甲基含量至少为 2.0 摩尔，最好是 3.0 至 4.0 摩尔。使用这些富含甲基基团的新化合物，可以使许多无机、有机金属和/或有机材料具有疏水性和/或粘合性，或以经济的方式生产出具有疏水性和/或粘合性的薄膜或箔片。 液态化合物还可用作活性稀释剂和/或增塑剂。
• Photoresists with hydroxylated, photoacid-cleavable groups
  申请人：E.I. du Pont de Nemours and Company

  公开号：EP1411389A1

  公开（公告）日：2004-04-21

  The present invention pertains to photoimaging and the use of photoresists (positive-working and/or negative-working) for imaging in the production of semiconductor devices. The present invention also pertains to novel hydroxy ester-containing polymer compositions that are useful as base resins in resists and potentially in many other applications.

  本发明涉及半导体器件生产中的光成像和用于成像的光刻胶（正片工作和/或负片工作）。本发明还涉及新型含羟基酯聚合物组合物，该组合物可用作光刻胶的基底树脂，也可用于许多其他应用。
• Processes for preparing photoresist compositions
  申请人：E.I. DUPONT DE NEMOURS AND COMPANY

  公开号：EP1479700A1

  公开（公告）日：2004-11-24

  An anhydrous, liquid phase process for preparing polymers of enhanced purity and low polydispersity comprising the steps of polymerization, optional purification, transesterification, optional purification, catalyst removal, and solvent exchange. The resultant polymer in solution can be used directly, without further processing steps, to prepare a photoresist composition.

  一种用于制备纯度更高、多分散性更低的聚合物的无水液相工艺，包括聚合、可选提纯、酯交换、可选提纯、去除催化剂和溶剂交换等步骤。所得溶液聚合物可直接用于制备光刻胶组合物，无需进一步加工步骤。
• ACTIVE-ENERGY-RAY-CURABLE COMPOSITION
  申请人：Ricoh Company, Ltd.

  公开号：EP3061795A1

  公开（公告）日：2016-08-31

  An active-energy-ray-curable composition including a (meth)acrylic acid ester compound containing a tertiary hydroxyl group in a molecule of the (meth)acrylic acid ester compound and represented by General Formula (1) below, where in the General Formula (1), OH represents a tertiary hydroxyl group, m and n represent an integer of a range of from 1 through 2, R1 represents a hydrogen atom or a methyl group, and X represents a group formed of an aliphatic hydrocarbon containing from 4 through 10 carbon atoms or a group formed of an aliphatic cyclic hydrocarbon containing from 4 through 10 carbon atoms.

  一种活性能量射线固化组合物，包括一种(甲基)丙烯酸酯化合物，该(甲基)丙烯酸酯化合物分子中含有一个叔羟基，并由下式(1)表示、 在通式（1）中，OH 代表叔羟基，m 和 n 代表 1 至 2 之间的整数，R1 代表氢原子或甲基，X 代表由含有 4 至 10 个碳原子的脂肪族烃组成的基团或由含有 4 至 10 个碳原子的脂肪族环状烃组成的基团。
• Purification means
  申请人：——

  公开号：US20030144470A1

  公开（公告）日：2003-07-31

  Polymers derived from 4-acyloxystyrene are purified by fractionalization plus heating and cooling of the polymers in alcoholic solvents.

  4-acyloxystyrene 衍生的聚合物是通过分馏以及在酒精溶剂中加热和冷却来提纯的。