methylpropenoic acid 2-(((4-benzoylphenoxy)carbonyl)amino)ethyl ester

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: methylpropenoic acid 2-(((4-benzoylphenoxy)carbonyl)amino)ethyl ester
• 英文别名: 2-(((4-benzoylphenoxy)carbonyl)amino)ethyl methacrylate；2-[(4-Benzoylphenoxy)carbonylamino]ethyl 2-methylprop-2-enoate
• 化学式: C₂₀H₁₉NO₅
• 分子量: 353.375
• InChiKey: OUZNSKVEWYKOCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  81.7
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲基丙烯酸异氰基乙酯 、 对羟基苯乙酮 在 二月桂酸二丁基锡 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以68%的产率得到methylpropenoic acid 2-(((4-benzoylphenoxy)carbonyl)amino)ethyl ester
  参考文献：
  名称：

  新型单体光引发剂的结构反应关系

  摘要：

  合成了两组不同的含I型或II型光引发剂的甲基丙烯酸酯，并评估了它们在UV固化中的用途。首先，通过α-溴甲基丙烯酸叔丁酯（TBBr）与2-羟基-1-[[4-（2-羟基乙氧基）苯基] -2-甲基-1-叔丁基的反应合成了一组新的单体光引发剂（MPI）。丙酮（Irgacure 2959），1-羟基-环己基-苯基酮（Irgacure 184）和4-羟基苯乙酮分别得到单体MPI 1，MPI 3和MPI 4；和MPI的转换1至MPI 2通过裂解叔丁基酯基与三氟乙酸。第二组光引发剂是通过使甲基丙烯酸2-异氰酸根合乙酯（IEM）与Irgacure 2959（MPI 5）和4-羟基二苯甲酮（MPI 6）反应而合成的）。发现所有这些MPI在UV区域的吸收范围与其非单体类似物相似。利用光差示扫描量热仪研究了它们在1,6-己二醇二丙烯酸丁酯（HDDA），甲基丙烯酸2-羟乙酯（HEMA）和三羟甲基丙烷三丙烯酸酯（TM

  DOI：

  10.1016/j.jphotochem.2016.06.015

文献信息

• INK COMPOSITION, IMAGE FORMATION METHOD, AND PRINTED MATTER
  申请人：FUJIFILM Corporation

  公开号：EP2889340A1

  公开（公告）日：2015-07-01

  An ink composition includes a compound having two or more partial structures represented by the following Formula (A) in a molecule (Component a), a compound selected from the group consisting of a compound represented by the following Formula (B1) and a compound represented by the following Formula (B2) (Component b), and a color material (Component c).

  油墨组合物包括在一个分子中具有下式（A）所代表的两个或多个部分结构的化合物（成分 a）、选自下式（B1）所代表的化合物和下式（B2）所代表的化合物（成分 b）组成的组的化合物，以及色料（成分 c）。
• LATEX FUNCTIONALIZED WITH PHOSPHORUS ACID AND PHOTOINITIATOR GROUPS
  申请人：Dow Global Technologies Llc

  公开号：EP3269784A1

  公开（公告）日：2018-01-17

  The present invention is a composition comprising a stable aqueous dispersion of polymer particles comprising structural units of a phosphorus acid monomer or a salt thereof and structural units of a photoinitiator monomer. Gloss retention of paints containing the latex described herein is markedly improved over paints that do not have photoinitiator chemically bound to the latex particles.

  本发明是一种组合物，由稳定的聚合物颗粒水分散体组成，该聚合物颗粒包含磷酸单体或其盐的结构单元和光引发剂单体的结构单元。与没有光引发剂与胶乳颗粒化学结合的涂料相比，含有本发明所述胶乳的涂料的光泽保持率明显提高。
• PROCESS FOR PREPARING LATEX FUNCTIONALIZED WITH PHOSPHORUS ACID AND PHOTOINITIATOR GROUPS
  申请人：Dow Global Technologies Llc

  公开号：EP3272778A1

  公开（公告）日：2018-01-24

  The present invention is a process for preparing a stable aqueous dispersion of polymer particles comprising structural units of a phosphorus acid monomer or a salt thereof and structural units of a photoinitiator monomer. Gloss retention of paints containing the latex prepared by the process of the present invention are improved over paints that do not have photoinitiator chemically bound to the latex particles.

  本发明是一种制备稳定的聚合物颗粒水性分散体的工艺，该分散体包含磷酸单体或其盐的结构单元和光引发剂单体的结构单元。与没有光引发剂与胶乳颗粒化学结合的涂料相比，含有本发明工艺制备的胶乳的涂料的光泽保持率有所提高。
• INK COMPOSITION, IMAGE FORMING METHOD, AND PRINTED MATERIAL
  申请人：HIRONAKA Koji

  公开号：US20120213978A1

  公开（公告）日：2012-08-23

  Provided is an ink composition having excellent dischargeability during image recording by an inkjet method and having excellent water resistance, solvent resistance, and adhesiveness to a recording medium of the recorded image. The ink composition includes a structure represented by the structural formula (A), a compound having at least any one of a residue formed by removing one hydrogen atom from a compound represented by the general formula (B1) and a residue formed by removing one hydrogen atom from a compound represented by the general formula (B2) in one molecule or plural molecules, and a coloring material.
• Structure-reactivity relationships of novel monomeric photoinitiators
  作者：Sesil Agopcan Cınar、Melek Naz Guven、Tugce Nur Eren、Belgin Cesur、Mina Aleksanyan、Burcu Dedeoglu、Neren Okte、Viktorya Aviyente、Fabrice Morlet-Savary、Jacques Lalevée、Duygu Avci

  DOI：10.1016/j.jphotochem.2016.06.015

  日期：2016.10

  Two different groups of methacrylates containing Type I or Type II photoinitiating moieties were synthesized and evaluated for use in UV curing applications. The first, a novel group of monomeric photoinitiators (MPIs) were synthesized by reactions of tert-butyl α-bromomethacrylate (TBBr) with 2-hydroxy-1-[4-(2-hydroxyethoxy)phenyl]-2-methyl-1-propanone (Irgacure 2959), 1-hydroxy-cyclohexyl-phenyl-ketone

  合成了两组不同的含I型或II型光引发剂的甲基丙烯酸酯，并评估了它们在UV固化中的用途。首先，通过α-溴甲基丙烯酸叔丁酯（TBBr）与2-羟基-1-[[4-（2-羟基乙氧基）苯基] -2-甲基-1-叔丁基的反应合成了一组新的单体光引发剂（MPI）。丙酮（Irgacure 2959），1-羟基-环己基-苯基酮（Irgacure 184）和4-羟基苯乙酮分别得到单体MPI 1，MPI 3和MPI 4；和MPI的转换1至MPI 2通过裂解叔丁基酯基与三氟乙酸。第二组光引发剂是通过使甲基丙烯酸2-异氰酸根合乙酯（IEM）与Irgacure 2959（MPI 5）和4-羟基二苯甲酮（MPI 6）反应而合成的）。发现所有这些MPI在UV区域的吸收范围与其非单体类似物相似。利用光差示扫描量热仪研究了它们在1,6-己二醇二丙烯酸丁酯（HDDA），甲基丙烯酸2-羟乙酯（HEMA）和三羟甲基丙烷三丙烯酸酯（TM