9,10-di(2-hydroxyethylthiamethyl)anthracene

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9,10-di(2-hydroxyethylthiamethyl)anthracene
• 英文别名: 2-[[10-(2-Hydroxyethylsulfanylmethyl)anthracen-9-yl]methylsulfanyl]ethanol
• 化学式: C₂₀H₂₂O₂S₂
• 分子量: 358.525
• InChiKey: GGQQWWCCUPJIEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  91.1
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  9,10-二(氯甲基)蒽 在 potassium carbonate 、 硫脲 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 7.0h， 生成 9,10-di(2-hydroxyethylthiamethyl)anthracene
  参考文献：
  名称：

  The synthesis and complexation studies of thia-anthracene receptors

  摘要：

  Systematic studies towards the formation of thia-anthracene receptors were performed. Anthracene podand 3 consisting of two anthryl groups connected by the SCH2CH2CH2S spacer group was prepared in 99% yield. The complexation properties of this compound were investigated using UV-VIS and fluorescence titration techniques. Addition of silver salts into a solution of the fluorophore strongly modifies the absorption and fluorescence spectra and the association constants were found to be K-1 = 2 x 10(5) and K-2 = 8 x 10(4) M-1 for the 1:1 and 1:2 complexes, respectively. Addition of metal ions, as Cu2+, Zn2+, Cd2+, Hg2+, Ni2+, and Co2+, did not lead to any change in the photophysical properties of compound 3. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00654-7

文献信息

• The synthesis and complexation studies of thia-anthracene receptors
  作者：Ryszard Ostaszewski、Luca Prodi、Marco Montalti

  DOI：10.1016/s0040-4020(99)00654-7

  日期：1999.9

  Systematic studies towards the formation of thia-anthracene receptors were performed. Anthracene podand 3 consisting of two anthryl groups connected by the SCH2CH2CH2S spacer group was prepared in 99% yield. The complexation properties of this compound were investigated using UV-VIS and fluorescence titration techniques. Addition of silver salts into a solution of the fluorophore strongly modifies the absorption and fluorescence spectra and the association constants were found to be K-1 = 2 x 10(5) and K-2 = 8 x 10(4) M-1 for the 1:1 and 1:2 complexes, respectively. Addition of metal ions, as Cu2+, Zn2+, Cd2+, Hg2+, Ni2+, and Co2+, did not lead to any change in the photophysical properties of compound 3. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.