2,4-dipentyl-5-methyldioxolane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: 2,4-dipentyl-5-methyldioxolane
• 英文别名: 4-Methyl-2,5-dipentyl-1,3-dioxolane；4-methyl-2,5-dipentyl-1,3-dioxolane
• 化学式: C₁₄H₂₈O₂
• 分子量: 228.375
• InChiKey: SGFHUAGMYBRRMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3-辛二醇 在 Ru(PPh₃)3Cl₂/C_W 氧气 作用下， 以 various solvent(s) 为溶剂， 60.0 ℃ 、101.33 kPa 条件下， 反应 15.0h， 生成 2,4-dipentyl-5-methyldioxolane 、 正己醛
  参考文献：
  名称：

  Oxidative Cleavage of vic-Diols to Aldehydes with Dioxygen Catalyzed by Ru(PPh₃)₃Cl₂ on Active Carbon

  摘要：

  [GRAPHICS]A variety of vic-diols were first successfully cleaved to the corresponding aldehydes with dioxygen catalyzed by RU(PPh3)(3)Cl-2 on active carbon in fair to good yields. For example, treatment of 1,2-octandiol and 1,2-cyclooctanediol with dioxygen in the presence of Ru(PPh3)(3)Cl-2/C in PhCF3 at 60 degrees C for 15 h produced heptanal and 1,8-octanedial in 77% and 76% yields, respectively.

  DOI：

  10.1021/ol990117w

文献信息

• Oxidative Cleavage of <i>vic</i>-Diols to Aldehydes with Dioxygen Catalyzed by Ru(PPh₃)₃Cl₂ on Active Carbon
  作者：Eiichiro Takezawa、Satoshi Sakaguchi、Yasutaka Ishii

  DOI：10.1021/ol990117w

  日期：1999.9.1

  [GRAPHICS]A variety of vic-diols were first successfully cleaved to the corresponding aldehydes with dioxygen catalyzed by RU(PPh3)(3)Cl-2 on active carbon in fair to good yields. For example, treatment of 1,2-octandiol and 1,2-cyclooctanediol with dioxygen in the presence of Ru(PPh3)(3)Cl-2/C in PhCF3 at 60 degrees C for 15 h produced heptanal and 1,8-octanedial in 77% and 76% yields, respectively.