11,14-bis(dodecanoyloxy)triptycene

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 11,14-bis(dodecanoyloxy)triptycene
• 英文别名: (6-Dodecanoyloxy-3-pentacyclo[6.6.6.02,7.09,14.015,20]icosa-2,4,6,9,11,13,15,17,19-nonaenyl) dodecanoate
• 化学式: C₄₄H₅₈O₄
• 分子量: 650.942
• InChiKey: KUPBIBLRBKGODT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  48
• 可旋转键数：
  24
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  月桂酰氯 、 triptycene-1,4-diol 在 吡啶 作用下， 以 甲苯 为溶剂， 反应 22.0h， 以50%的产率得到11,14-bis(dodecanoyloxy)triptycene
  参考文献：
  名称：

  Liquid crystalline triptycene derivatives

  摘要：

  A route to triptycenes substituted with one, two, five, and six paraffinic chains was developed using the Diels-Alder reaction as the key reaction. 1,4,5,8-Tetrakis(dodecyloxy)-11-hydroxy-14-(dode-canoyloxy)triptycene, 1,4,5,8-tetrakis(dodecyloxy)-11,14-bis(dodecanoyloxy)triptycene, and 1,4,5,8-11,14-hexakis(dodecyloxy)triptycene were obtained in a nine-step procedure starting from diaminoanthrarufin. The five-chain derivative demonstrates original mesomorphic properties.

  DOI：

  10.1021/jo00061a012

文献信息

• Liquid crystalline triptycene derivatives
  作者：Sophie Norvez

  DOI：10.1021/jo00061a012

  日期：1993.4

  A route to triptycenes substituted with one, two, five, and six paraffinic chains was developed using the Diels-Alder reaction as the key reaction. 1,4,5,8-Tetrakis(dodecyloxy)-11-hydroxy-14-(dode-canoyloxy)triptycene, 1,4,5,8-tetrakis(dodecyloxy)-11,14-bis(dodecanoyloxy)triptycene, and 1,4,5,8-11,14-hexakis(dodecyloxy)triptycene were obtained in a nine-step procedure starting from diaminoanthrarufin. The five-chain derivative demonstrates original mesomorphic properties.