6-methoxyanthracene-2-neopentyl carboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 6-methoxyanthracene-2-neopentyl carboxylate
• 英文别名: 2,2-Dimethylpropyl 6-methoxyanthracene-2-carboxylate；2,2-dimethylpropyl 6-methoxyanthracene-2-carboxylate
• 化学式: C₂₁H₂₂O₃
• 分子量: 322.404
• InChiKey: CWLAPFPSFRSDGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  新戊醇 、 6-methoxy-2-anthracene carboxylic acid 在 对甲苯磺酸 作用下， 以 苯 为溶剂， 反应 72.0h， 以71%的产率得到6-methoxyanthracene-2-neopentyl carboxylate
  参考文献：
  名称：

  Novel Fluorescence Probes Based on 2,6-Donor−Acceptor-Substituted Anthracene Derivatives

  摘要：

  The fluorescence properties of selected derivatives of 6-methoxyanthracene-2-carboxylic acid were studied. The corresponding ester and oxazoline derivatives exhibit a moderate solvatochromism, which is caused by the donor-acceptor interplay, The fluorescence band shift and intensity of oxazoline If may be reversibly modulated by protonation or complexation with silver ions; thus, the oxazoline heterocycle serves as a useful substituent with switchable acceptor strength.

  DOI：

  10.1021/ol006291y

文献信息

• Novel Fluorescence Probes Based on 2,6-Donor−Acceptor-Substituted Anthracene Derivatives
  作者：Heiko Ihmels、Andreas Meiswinkel、Christian J. Mohrschladt

  DOI：10.1021/ol006291y

  日期：2000.9.1

  The fluorescence properties of selected derivatives of 6-methoxyanthracene-2-carboxylic acid were studied. The corresponding ester and oxazoline derivatives exhibit a moderate solvatochromism, which is caused by the donor-acceptor interplay, The fluorescence band shift and intensity of oxazoline If may be reversibly modulated by protonation or complexation with silver ions; thus, the oxazoline heterocycle serves as a useful substituent with switchable acceptor strength.