bis(tetrabutylammonium) hexachloroplatinate(IV)

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bis(tetrabutylammonium) hexachloroplatinate(IV)
• 英文别名: tetrabutylammonium hexachloroplatinate(IV)
• 化学式: 2C₁₆H₃₆N*Cl₆Pt
• 分子量: 892.735
• InChiKey: VJHACFMBEHRLCE-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  9.14
• 重原子数：
  24.0
• 可旋转键数：
  12.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  bis(tetrabutylammonium) hexachloroplatinate(IV) 在 AlCl₃ 作用下， 以 1,2-二氯乙烷 为溶剂， 生成
  参考文献：
  名称：

  Simple Preparations of Pd₆Cl₁₂, Pt₆Cl₁₂, and Q_n[Pt₂Cl_8+n], n = 1, 2 (Q = TBA⁺, PPN⁺) and Structural Characterization of [TBA][Pt₂Cl₉] and [PPN]₂[Pt₂Cl₁₀]·C₇H₈

  摘要：

  The hexanuclear Pd6Cl12, i.e., the crystal phase classified as beta-PdCl2, was obtained by reacting [TBA](2)[Pd2Cl6] with AlCl3 (or FeCl3) in CH2Cl2. The action of AlCl3 On PtCl42-, followed by digestion of the resulting solid in 1,2-C2H4Cl2 (DCE), CHCl3, or benzene, produced Pt6Cl12 center dot DCE, Pt6Cl12-CHCl3, or Pt6Cl12 center dot C6H6, respectively. Treating [TBA](2)-[PtCl6] with a slight excess of AlCl3 afforded [TBA][Pt2Cl9], whose anion was established crystallographically to be constituted by two, "PtCl6" octahedra Sharing a face. Dehydration of H2PtCl6 center dot nH(2)O with SOCl2 gave an amorphous com