全氟-1,3,5-三苯基苯 | 59831-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 全氟-1,3,5-三苯基苯
• 英文名称: perfluoro-1,3,5-triphenylbenzene
• 英文别名: perfluoro(1,3,5-triphenylbenzene)；Perfluor-1,3,5-triphenylbenzol；1,2,3,4,5-pentafluoro-6-[2,4,6-trifluoro-3,5-bis(2,3,4,5,6-pentafluorophenyl)phenyl]benzene
• CAS: 59831-92-4
• 化学式: C₂₄F₁₈
• 分子量: 630.235
• InChiKey: UVJSKKCWUVDYOA-UHFFFAOYSA-N

物化性质

• 沸点：
  356.8±37.0 °C(Predicted)
• 密度：
  1.745±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  42
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  溴五氟苯 、 1,3,5-三溴-2,4,6-三氟苯 以 四氢呋喃 、 1,4-二氧六环 、 甲苯 为溶剂， 反应 24.0h， 以81%的产率得到全氟-1,3,5-三苯基苯
  参考文献：
  名称：

  全氟亚苯基树枝状大分子的合成、表征和电子传输性能

  摘要：

  DOI：

  10.1021/ja994083z

文献信息

• Dopants for a Perfluorinated Graded Index Polymer Optical Fiber
  作者：Masaki Naritomi、Hidenobu Murofushi、Naotoshi Nakashima

  DOI：10.1246/bcsj.77.2121

  日期：2004.11

  A perfluorinated graded index polymer optical fiber (PFGI-POF) has been developed and manufactured for data communication to provide a high bandwidth with easy termination and cabling. In the PFGI-...

  一种全氟化渐变折射率聚合物光纤 (PFGI-POF) 已开发和制造用于数据通信，以提供高带宽、易于端接和布线。在 PFGI-...
• NOVEL FLUORINE COMPOUND, PROCESS FOR PRODUCING THE SAME, AND POLYMER THEREOF
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1285905A1

  公开（公告）日：2003-02-26

  A novel polymer useful as an optical resin material excellent in heat resistance, a novel monomer for obtaining the polymer, etc., are provided. A fluorinated diene represented by CF2=CF(CF2)nC(CF3)ROCF=CF2 (wherein R is a fluorine atom or a trifluoromethyl group, and n is an integer of from 1 to 3), and a polymer thereof.

  本发明提供了一种作为光学树脂材料使用的耐热性能优异的新型聚合物、一种用于获得该聚合物的新型单体等。由 CF2=CF(CF2)nC(CF3)ROCF=CF2 表示的氟化二烯（其中 R 为氟原子或三氟甲基，n 为 1 至 3 的整数）及其聚合物。
• DEVICE AND METHOD FOR REFINING SOLID MATERIAL
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1403237A1

  公开（公告）日：2004-03-31

  To provide a device for refining a solid material and a process for refining it, whereby from the supply of the material to the operation for recovery of crystals can be carried out batch-wisely or continuously, and inclusion of foreign matters such as particles can be efficiently prevented. A device for refining an evaporable or sublimable solid material, which comprises a housing, and at least one rotatable roller for evaporation and at least one rotatable roller for precipitation, installed in the housing.

  提供一种用于精炼固体材料的装置和精炼工艺，从而可以批量或连续地进行从材料供应到晶体回收的操作，并有效地防止颗粒等异物的混入。一种用于提炼可蒸发或可升华固体材料的装置，包括一个外壳，以及安装在外壳中的至少一个用于蒸发的可旋转辊和至少一个用于沉淀的可旋转辊。
• CROSSLINKABLE FLUOROAROMATIC PREPOLYMER AND USE THEREOF
  申请人：ASAHI GLASS COMPANY LTD.

  公开号：EP1669389A1

  公开（公告）日：2006-06-14

  To provide a crosslinkable fluorinated aromatic prepolymer which is capable of forming a cured product having a low relative permittivity, high heat resistance, low birefringence and high flexibility, and its uses. A crosslinkable fluorinated aromatic prepolymer which is obtained by subjecting a compound (Y-1) having a crosslinkable functional group (A) and a phenolic hydroxyl group and/or a compound (Y-2) having a crosslinkable functional group (A) and a fluorinated aromatic ring, to a condensation reaction in the presence of a HF-removing agent, with a fluorinated aromatic compound (B) represented by the formula (1): (wherein n is an integer of from 0 to 2, each of a and b which are independent of each other, is an integer of 0 to 3, and each of Rf1 and Rf2 represents a fluorinated alkyl group having at most 8 carbon atoms and a compound (C) having at least 3 phenolic hydroxyl groups, and which has crosslinkable functional groups (A) and ether bonds and has a number average molecular weight of from 1×103 to 5×105.

  提供一种可交联含氟芳香族预聚物，它能够形成具有低相对介电常数、高耐热性、低双折射和高柔韧性的固化产品及其用途。 一种可交联的氟化芳香族预聚物，它是将具有可交联官能团（A）和酚羟基的化合物（Y-1）和/或具有可交联官能团（A）和氟化芳香环的化合物（Y-2）与由式（1）表示的氟化芳香族化合物（B）在氢氟酸去除剂存在下进行缩合反应而得到的： (其中 n 为 0 至 2 的整数，a 和 b 互不相关，均为 0 至 3 的整数，Rf1 和 Rf2 分别代表具有至多 8 个碳原子的氟化烷基和具有至少 3 个酚羟基的化合物 (C)，该化合物具有可交联官能团 (A) 和醚键，其平均分子量为 1×103 至 5×105。
• CROSSLINKABLE FLUORINE-CONTAINING AROMATIC PREPOLYMER AND USE THEREOF
  申请人：Asahi Glass Company, Limited

  公开号：EP1897897A1

  公开（公告）日：2008-03-12

  To provide a crosslinkable fluorinated aromatic prepolymer which is capable of forming a cured product having high transparency, a low relative permittivity, high heat resistance, low birefringence and high flexibility, and its uses. A crosslinkable fluorinated aromatic prepolymer which is obtained by subjecting a compound (Y-1) having a polymerizable double bond (A) and/or a phenolic hydroxyl group and a compound (Y-2) having a polymerizable double bond (A) and a fluorinated aromatic ring, to a condensation reaction in the presence of a HF-removing agent, with a fluorinated aromatic compound (B) represented by the following formula (1): (wherein n is an integer of from 0 to 3, each of a and b which are independent of each other, is an integer of from 0 to 3, and each of Rf1 and Rf2 is a fluorinated alkyl group having at most 8 carbon atoms), and a compound (C) having at least 3 phenolic hydroxyl groups, the respective phenolic hydroxyl groups not being present in the same aromatic ring, and which has polymerizable double bonds (A) and ether bonds and has a number average molecular weight of from 1×103 to 5×105.

  提供一种可交联的含氟芳香族预聚物，它能够形成具有高透明度、低相对介电常数、高耐热性、低双折射和高柔韧性的固化产品及其用途。 一种可交联的含氟芳香族预聚物，它是将具有可聚合双键（A）和/或酚羟基的化合物 （Y-1）和具有可聚合双键（A）和含氟芳香环的化合物（Y-2）与下式（1）表示的含氟芳香族化合物 （B）在氢氟酸去除剂存在下进行缩合反应而得到的： (其中 n 为 0 至 3 的整数，a 和 b 互不相关，均为 0 至 3 的整数，Rf1 和 Rf2 均为最多具有 8 个碳原子的氟化烷基)，以及至少具有 3 个酚羟基的化合物(C)，各酚羟基不存在于同一芳香环中，该化合物具有可聚合双键(A)和醚键，平均分子量为 1×103 至 5×105。