N-((2-anthryl)methylene)thiobenzhydrazone

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-((2-anthryl)methylene)thiobenzhydrazone
• 英文别名: N-[(E)-anthracen-9-ylmethylideneamino]benzenecarbothioamide
• 化学式: C₂₂H₁₆N₂S
• 分子量: 340.448
• InChiKey: GCBOADHXGFAGNR-HZHRSRAPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-((2-anthryl)methylene)thiobenzhydrazone 、 三甲基镓 以 环己烷 、 苯 为溶剂， 以87%的产率得到dimethyl[N-((9-anthryl)methylene)thiobenzhydrazonato]gallium
  参考文献：
  名称：

  Synthesis, structural characterization and electroluminescence study of alkylgallium derivatives of thiobenzhydrazones

  摘要：

  Six dimethylgallium complexes of type Me2GaL [L = N-benzylidenethiobenzahydrazonato (1), N-(4-methoxy)benzylidenethiobenzahydrazonato (2), N-(3,4-dimethoxy)benzylidenethiobenzahydrazonato (3), N-(4-N,N-dimethylamino)benzylidenethiobenzahydrazonato (4), N-(2-naphthyl)methylenethiobenzahydrazonato (5) and N-(9-anthryl)methylenethiobenzahydrazonato (6)] have been synthesized by reaction of trimethylgallium with appropriate N-arylmethylenethiobenzahydrazones. The complexes obtained have been characterized by elemental analysis, H-1-NMR, IR and mass spectroscopy. Structure of 2 has been determined by X-ray single-crystal analysis, in which Ga atom is four-coordinated. Compounds 2-4 emit blue colors at lambda(max) = 432-479 nm when irradiated by UV light. The electroluminescent (EL) properties of 2, 3 and 4 were examined by fabricating EL devices using 2, 3 and 4 as emitter, respectively. The EL bands are located in the blue region (451, 454 and 479 nm for complexes 2, 3 and 4, respectively). (C) 2003 Published by Elsevier B.V.

  DOI：

  10.1016/s0022-328x(03)00530-8