TlOC6H4(CH=N-2,6-(i-Pr)2C6H3)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: TlOC6H4(CH=N-2,6-(i-Pr)2C6H3)
• 英文别名: 2-[[2,6-Di(propan-2-yl)phenyl]iminomethyl]phenolate;thallium(1+)；2-[[2,6-di(propan-2-yl)phenyl]iminomethyl]phenolate;thallium(1+)
• 化学式: C₁₉H₂₂NO*Tl
• 分子量: 484.773
• InChiKey: NADZCIIUEIXFMQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.38
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  35.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II) 、 TlOC6H4(CH=N-2,6-(i-Pr)2C6H3) 以 四氢呋喃 为溶剂， 以26%的产率得到[RuCl(OC6H4CHNC6H3(CH(CH3)2)2)(CHC6H5)(1,3-bis-(2,4,6-trimethylphenyl)imidazolin-2-ylidene)]
  参考文献：
  名称：

  Synthesis and activity for ROMP of bidentate Schiff base substituted second generation Grubbs catalysts

  摘要：

  The synthesis and characterisation of Schiff base substituted second generation Grubbs catalysts is described using the pyridine functionalised second generation catalyst and a Schiff base-TI salt. The complexes are less active for the ROMP of COD (cycloocadiene) than their second generation analogues though their activity for the ROMP of DCPD (dicyclopentadiene) at high temperatures shows great potential due to the thermal stability of the catalysts. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.07.006
• 作为产物：
  描述：

  thallium (I) ethoxide 、 苯酚,2-[[[2,6-二(1-甲基乙基)苯基]亚氨基]甲基]- 以 苯 为溶剂， 以98%的产率得到TlOC6H4(CH=N-2,6-(i-Pr)2C6H3)
  参考文献：
  名称：

  Synthesis and Characterization of New Ruthenium-Based Olefin Metathesis Catalysts Coordinated with Bidentate Schiff-Base Ligands

  摘要：

  A novel series of Schiff-base-substituted ruthenium carbene complexes have been prepared by the treatment of RuCl2(=CHPh)(PCy3)(2) with a variety of Schiff-base ligands as the thallium salts. Modification of the Schiff-base electronic and/or structural substituents allowed for the tuning of the complexes activities in olefin metathesis reactions. The structures of the complexes were unambiguously characterized by NMR studies and X-ray analysis. These newly prepared complexes are highly stable to air, moisture, and temperature and even exhibit catalytic activity in polar protic solvents.

  DOI：

  10.1021/om970910y

文献信息

• [EN] METAL COMPLEXES FOR USE IN OLEFIN METATHESIS AND ATOM GROUP TRANSFER REACTIONS<br/>[FR] COMPLEXES METALLIQUES S'UTILISANT DANS LA METATHESE D'OLEFINE ET LES REACTIONS DE TRANSFERT D'ATOMES OU DE GROUPES
  申请人：UNIV GENT

  公开号：WO2005082819A3

  公开（公告）日：2005-10-20