内-2-甲基-双环[2.2.1]庚-5-烯-2-甲酰胺 | 51757-86-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 内-2-甲基-双环[2.2.1]庚-5-烯-2-甲酰胺
• 英文名称: 2-Norbornene-5-endo-carboxamide, 5-exo-methyl-
• 英文别名: 2-methylbicyclo[2.2.1]hept-5-ene-2-carboxamide
• CAS: 51757-86-9；51757-84-7
• 化学式: C₉H₁₃NO
• mdl: MFCD00970639
• 分子量: 151.21
• InChiKey: LUARJZGXWCWEEU-UHFFFAOYSA-N

物化性质

• 沸点：
  299.3±20.0 °C(Predicted)
• 密度：
  1.117±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

文献信息

• Olefin copolymer having functional group, production process thereof and rubber composition
  申请人：JSR Corporation

  公开号：EP1113027A1

  公开（公告）日：2001-07-04

  Disclosed herein are an olefin copolymer having a functional group, which comprises a structural unit (a) derived from ethylene, a structural unit (b) derived from an α-olefin having 3 to 12 carbon atoms, and a structural unit (c) represented by the following general formula (1), and has an intrinsic viscosity [η] of 0.1 to 10 dl/g as measured in decalin at 135°C, a production process thereof and a rubber composition containing the copolymer ; wherein X1 and X2 mean, independently of each other, a hydrogen atom, a hydrocarbon group or the following specific functional group, at least one of X1 and X2 is the specific functional group, R1 and R2 denote, independently of each other, a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, one of R1 and R2, which is bonded to a carbon atom to which the specific functional group is bonded, is the hydrocarbon group having 1 to 10 carbon atoms, and n stands for an integer of 0 to 2; Specific functional group:    a functional group selected from the group consisting of a hydroxyl group, a hydrocarbon group to which a hydroxyl group is bonded, a carboxyl group, a hydrocarbon group to which a carboxyl group is bonded, a primary or secondary amino group, a hydrocarbon group to which a primary or secondary amino group is bonded, a quaternary ammonium salt of a primary or secondary amino group and a hydrocarbon group to which a primary or secondary amino group is bonded, an amide group having at least one active hydrogen atom bonded to a nitrogen atom, a hydrocarbon group to which such an amide group is bonded, and an imide group composed of X1 and X2 and represented by -CO-NH-CO-.

  本发明公开了一种具有官能团的烯烃共聚物，该共聚物包括由乙烯衍生的结构单元(a)、由具有 3 至 12 个碳原子的 α-烯烃衍生的结构单元(b)和由下式通式(1)表示的结构单元(c)，并且在 135°C、癸二酸盐中测量的固有粘度[η]为 0.1 至 10 dl/g，还公开了其生产工艺和含有该共聚物的橡胶组合物； 其中，X1和X2互不相关地表示氢原子、烃基或下列特定官能团，X1和X2中至少有一个是特定官能团，R1和R2互不相关地表示氢原子或具有1至10个碳原子的烃基，R1和R2中与特定官能团键合的碳原子键合的一个是具有1至10个碳原子的烃基，n代表0至2的整数； 特定官能团： 选自以下组别的官能团：羟基、与羟基键合的烃基、羧基、与羧基键合的烃基、伯氨基或仲氨基、与伯氨基或仲氨基键合的烃基、伯氨基或仲氨基的季铵盐、伯氨基或仲氨基与之结合的烃基、至少有一个活泼氢原子与氮原子结合的酰胺基、与该酰胺基结合的烃基、以及由 X1 和 X2 组成并由 -CO-NH-CO- 表示的酰亚胺基。
• Flame-retardant rubber composition and flame-retardant elastomer
  申请人：JSR Corporation

  公开号：EP1191061A1

  公开（公告）日：2002-03-27

  The invention provides a flame-retardant rubber composition which may form a vulcanizate of an elastomer whose deterioration of mechanical strength is little to enjoy excellent mechanical properties, even when a nonhalogenated flame retardant is contained in a high proportion in the composition, and a flame-retardant elastomer obtained therefrom. The flame-retardant rubber composition contains (A) an olefin copolymer having a functional group, which comprises (a-1) a structural unit derived from ethylene, (a-2) a structural unit derived from an α-olefin compound having 3 to 10 carbon atoms, (a-3) a structural unit derived from a functional group-containing unsaturated compound, and optionally (a-4) a structural unit derived from a nonconjugated diene compound, and has an intrinsic viscosity [η] of 0.1 to 10 dL/g as measured in decalin at 135°C, (B) a vulcanizing agent and/or a crosslinking agent and (C) a nonhalogenated flame retardant. The flame-retardant elastomer is obtained by subjecting the flame-retardant rubber composition to a vulcanizing treatment.

  本发明提供了一种阻燃橡胶组合物，该组合物即使在组合物中含有高比例的非卤化阻燃剂时，也可形成机械强度几乎不会降低的弹性体硫化物，从而享有优异的机械性能，本发明还提供了由此获得的阻燃弹性体。 阻燃橡胶组合物含有 (A) 具有官能团的烯烃共聚物，它包括 (a-1) 源自乙烯的结构单元，(a-2) 源自具有 3 至 10 个碳原子的 α 烯烃化合物的结构单元，(a-3) 源自含官能团不饱和化合物的结构单元，以及可选的 (a-4) 源自非共轭二烯化合物的结构单元。(B) 硫化剂和/或交联剂，以及 (C) 非卤化阻燃剂。阻燃弹性体是通过对阻燃橡胶组合物进行硫化处理而获得的。
• US6403742B2
  申请人：——

  公开号：US6403742B2

  公开（公告）日：2002-06-11
• US6534586B2
  申请人：——

  公开号：US6534586B2

  公开（公告）日：2003-03-18