triadimefon

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: triadimefon
• 英文别名: 1-(4-Chlorophenoxy)-3,3-dimethyl-1-(triazol-2-yl)butan-2-one
• 化学式: C₁₄H₁₆ClN₃O₂
• 分子量: 293.753
• InChiKey: VLXVPGWOLWIVTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  57
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  triadimefon 以 甲醇 为溶剂， 反应 24.0h， 以15%的产率得到对氯苯酚
  参考文献：
  名称：

  Photodegradation of Azole Fungicide Triadimefon

  摘要：

  To examine the photostability of the fungicide triadimefon [1-(4-chlorophenoxy)-3,3-dimethyl-1H-(1,2,4-triazol-1-yl)butan-2-one] in the field, model experiments with organic solvents were performed. Photolysis in methanol, hexane, and acetone resulted in considerable formation of 1-(4-chlorophenoxy)-3,3-dimethylbutan-2-one, 1-[(4-chlorophenoxy)methyl]-1H-1,2,4-triazole, 1H-(1,2,4-triazol-1-yl)-3,3-dimethylbutan-2-one, and 1-phenoxy-3,3-dimethyl-1H-(1,2,4-triazol-1-yl)butan-2-one. The rate of photodegradation in different solvents followed first-order rate kinetics with a significant correlation coefficient.

  DOI：

  10.1021/jf960074n

文献信息

• Photodegradation of Azole Fungicide Triadimefon
  作者：Subir K. Nag、Prem Dureja

  DOI：10.1021/jf960074n

  日期：1997.1.1

  To examine the photostability of the fungicide triadimefon [1-(4-chlorophenoxy)-3,3-dimethyl-1H-(1,2,4-triazol-1-yl)butan-2-one] in the field, model experiments with organic solvents were performed. Photolysis in methanol, hexane, and acetone resulted in considerable formation of 1-(4-chlorophenoxy)-3,3-dimethylbutan-2-one, 1-[(4-chlorophenoxy)methyl]-1H-1,2,4-triazole, 1H-(1,2,4-triazol-1-yl)-3,3-dimethylbutan-2-one, and 1-phenoxy-3,3-dimethyl-1H-(1,2,4-triazol-1-yl)butan-2-one. The rate of photodegradation in different solvents followed first-order rate kinetics with a significant correlation coefficient.