nickel(II) di(dithizonate)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: nickel(II) di(dithizonate)
• 化学式: 2C₁₃H₁₁N₄S*Ni
• 分子量: 569.336
• InChiKey: BXBHIQVAGVEAHF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.26
• 重原子数：
  19.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.85
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  nickel(II) di(dithizonate) 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  A thermal analysis study of some transition-metal dithizonates

  摘要：

  Solid dithizonates of Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(lI) and Pb(II), have been prepared. Thermogravimetry (DTG), derivative thermogravimetry (DTG), differential scanning calorimetry (DSC), X-ray diffraction powder patterns and elemental analysis have been used to characterize and study the thermal stability and thermal decomposition of these compounds. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(98)00467-5
• 作为产物：
  描述：

  nickel(II) sulphate 、 双硫腙 以 水 为溶剂， 生成 nickel(II) di(dithizonate)
  参考文献：
  名称：

  A thermal analysis study of some transition-metal dithizonates

  摘要：

  Solid dithizonates of Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(lI) and Pb(II), have been prepared. Thermogravimetry (DTG), derivative thermogravimetry (DTG), differential scanning calorimetry (DSC), X-ray diffraction powder patterns and elemental analysis have been used to characterize and study the thermal stability and thermal decomposition of these compounds. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s0040-6031(98)00467-5

文献信息

• Unexpected stabilization of the heterocyclic form of oxidized dithizone: Synthesis and molecular structures of chromium and tungsten 5-mercapto-2,3-diphenyltetrazolium pentacarbonyls
  作者：A. A. Pasynskii、A. N. Il’in、S. S. Shapovalov、Yu. V. Torubaev

  DOI：10.1134/s0036023607060101

  日期：2007.6

  New chromium and tungsten pentacarbonyl complexes with 5-mercapto-2,3-diphenyltetrazole coordinated through the sulfur atom (Cr-S, 2.4655(7) angstrom; W-S, 2.5755(13) angstrom) were synthesized and structurally characterized.