十三烷基二甲基苯甲基氯化铵 | 1641-93-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 十三烷基二甲基苯甲基氯化铵
• 英文名称: N-tridecyl-N,N-dimethyl N-benzyl ammonium chloride
• 英文别名: dimethyl(tridecyl)benzylammonium chloride；dimethyltridecylbenzylammonium chloride；benzyldimethyltridecylazanium chloride；benzalkonium chloride；Benzyldimethyl(tridecyl)ammonium chloride；benzyl-dimethyl-tridecylazanium;chloride
• CAS: 1641-93-6
• 化学式: C₂₂H₄₀N*Cl
• 分子量: 354.019
• InChiKey: XIWFQDBQMCDYJT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.58
• 重原子数：
  24
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2923900090

反应信息

• 作为反应物：
  描述：

  十三烷基二甲基苯甲基氯化铵 在 硝酸 作用下， 以 水 为溶剂， 反应 1.0h， 生成
  参考文献：
  名称：

  The Effect of Alkoxide Ionic Liquids on the Synthesis of Dimethyl Carbonate from CO2 and Methanol over ZrO2–MgO

  摘要：

  The use of carbon dioxide in the synthesis of chemicals, such as dimethyl carbonate (DMC), constitutes an environmentally attractive alternative to hazardous and toxic reagents. However, the direct synthesis of DMC from methanol and CO2 is characterized by low yields due to the reaction equilibrium and the thermodynamic limitations (Delta G(298K)(0) = + 26.3 kj/mol). Alkoxide ionic liquids possessing alkylimidazolium and benzalkonium cations were prepared, characterised and tested together with ZrO2-MgO catalyst for the synthesis of DMC from methanol and CO2. By using the novel ionic liquid as additives, ca. 12% conversion of methanol, and 90% selectivity to DMC was obtained at 120 A degrees C and 7.5 MPa. The water abstracting potential of the ionic liquids influenced the conversion of methanol and the selectivity to DMC. The alkoxide ionic liquids were recovered and reused in DMC synthesis without loss in activity and selectivity.

  DOI：

  10.1007/s10562-011-0666-3
• 作为产物：
  描述：

  N,N-二甲基十三烷胺 、 氯化苄 生成 十三烷基二甲基苯甲基氯化铵
  参考文献：
  名称：

  FUDZITA, KOITI

  摘要：

  DOI：

文献信息

• Antimicrobial material
  申请人：Tessier Dominic

  公开号：US20060141015A1

  公开（公告）日：2006-06-29

  The present invention relates to an antimicrobial material comprising sheet of fabric and- metallic salt crystals embedded in an adhesive material covering the sheet of fabric.

  本发明涉及一种抗菌材料，包括一块织物和嵌入在覆盖织物的粘合材料中的金属盐晶体。
• Metal complexes, the preparation thereof and use as biocides
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0392648A1

  公开（公告）日：1990-10-17

  A metal complex of the general formula [R1CSNRO]xM(L)y where R and R1 are optionally substituted hydrocarbyl groups, M is a metal of Group IIIA to VA and IB to VIIB, with the exception of copper, L is a ligand, x has a value of 1 to 3 and y is zero or has a value of up to 4. The complex may be prepared by the reaction of a metal salt with an N-hydroxythiobenzamide. Complexes of this type have anti-microbial properties, and can be used as industrial biocides.

  通用公式[R1CSNRO]xM(L)y的金属配合物，其中R和R1是可选择取代的烃基，M是III A到VA族和IB到VIIB族的金属，但不包括铜，L是配体，x的值为1到3，y为零或最多为4。该配合物可以通过金属盐与N-羟基硫代苯甲酰胺反应制备而成。这种类型的配合物具有抗微生物特性，可用作工业杀菌剂。
• Possibilities for removal of chlorinated dye Mordant Blue 9 from model waste water‡
  作者：Miroslav Šimek、Petr Mikulášek、Petr Kalenda、Tomáš Weidlich

  DOI：10.1515/chempap-2015-0225

  日期：2016.1.1

  dye Mordant Blue 9. Low-cost and commercially available ionic liquids — benzalkonium chloride and Aliquat 336 — were applied as liquid ion-exchangers to precipitate the Mordant Blue 9 by way of ion pair formation between the bulky ammonium cations of ionic liquids and anions of the above dye. The decolorisation efficiency of the ionic liquid application and the effect on reduction of the absorbance

  这项比较研究的重点是用于处理被氯化酸性染料Mordant Blue 9污染的模型废水的不同方法。将低成本和市售离子液体（苯扎氯铵和Aliquat 336）用作液体离子交换剂以沉淀通过在离子液体的大铵阳离子与上述染料的阴离子之间形成离子对来形成媒染剂蓝9。与常规混凝，吸附和芬顿氧化技术比较了离子液体应用的脱色效率以及对降低吸收率，可吸收有机卤素，化学需氧量和生物需氧量的影响。
• Multifunctional long-alkyl-chain quaternary ammonium azolate based ionic liquids
  作者：Filip Walkiewicz、Katarzyna Materna、Aleksandra Kropacz、Alicja Michalczyk、Romuald Gwiazdowski、Tadeusz Praczyk、Juliusz Pernak

  DOI：10.1039/c0nj00228c

  日期：——

  A new group of quaternary ammonium ionic liquids with azolate (benzotriazolate, 1,2,4-triazolate, 4-nitroimidazolate, 2-methyl-4-nitroimidazolate) anions was prepared and characterized. The synthetic method employed was easy and quick, and required a polar solvent. The obtained ionic liquids were tested as anti-microbial and anti-fungal plant protection agents. Additionally, the surface-active properties

  一组新的第四纪 铵盐 离子液体 偶氮酸盐 （苯并三唑， 1,2,4-三唑盐， 4-硝基咪唑盐， 2-甲基-4-硝基咪唑啉）阴离子已制备并表征。所采用的合成方法简便快捷，并且需要极性溶剂。测试所得的离子液体作为抗微生物和抗真菌植物保护剂。此外，季铵盐的表面活性和植物毒性铵盐还研究了偶氮盐。发现这些明确定义的离子液体是非常有效的抗菌剂和抗真菌剂。
• [EN] SELECTIVE DETECTION OF THIOLS<br/>[FR] DÉTECTION SÉLECTIVE DE THIOLS
  申请人：OREGON STATE

  公开号：WO2013126816A1

  公开（公告）日：2013-08-29

  Probes for selectively detecting compounds comprising a thiol group and an amino group ("thiols") are disclosed. Exemplary thiols include cysteine, homocysteine, and glutathione. Embodiments of the disclosed probes produce a detectable change in absorbance spectrum and/or emission spectrum when reacted with one or more thiols in solution. Methods and kits for performing the detection also are disclosed. The probes have a general formula where each bond depicted as "¯¯¯¯¯¯ " is a single or double bond; R1, R3-R6 and R8 independently are hydrogen, hydroxyl, thiol, lower alkyl, carboxyalkyl, amino, alkoxy, or halogen; R2 is an α,β-unsaturated aliphatic ester; R7 is oxygen, sulfur, hydrogen, hydroxyl, thiol, lower alkyl, carboxyalkyl, amino, alkoxy, or halogen, or R7 and R8 together form a cycloalkyl or aryl ring; X1 is CH2, S, NH, O, Se, Si(CH3)2, Ge(CH3)2, Sn(CH3)2, or C(CH3)2; and X2 is CH, CH2, N, NH, or CR9 where R9 is aryl.

  本文揭示了用于选择性检测含有巯基和氨基（“巯基”）的化合物的探针。示例巯基包括半胱氨酸，同型半胱氨酸和谷胱甘肽。所述探针的实施例在与一个或多个溶液中的巯基反应时，产生可检测的吸收光谱和/或发射光谱的变化。本文还揭示了执行检测的方法和工具包。探针具有一般公式，其中每个表示为“¯¯¯¯¯¯”的键是单键或双键；R1、R3-R6和R8独立地是氢、羟基、巯基、低碳基、羧基烷基、氨基、烷氧基或卤素；R2是α，β-不饱和脂肪酸酯；R7是氧、硫、氢、羟基、巯基、低碳基、羧基烷基、氨基、烷氧基或卤素，或R7和R8一起形成环烷基或芳基环；X1是CH2、S、NH、O、Se、Si（CH3）2、Ge（ ）2、Sn（ ）2或C（ ）2；X2是CH、 、N、NH或CR9，其中R9是芳基。