十三烷基苯磺酸 | 25496-01-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 十三烷基苯磺酸
• 英文名称: Tridecylbenzolsulfonsaeure
• 英文别名: Benzenesulfonic acid, tridecyl-；4-tridecylbenzenesulfonic acid
• CAS: 25496-01-9
• 化学式: C₁₉H₃₂O₃S
• 分子量: 340.527
• InChiKey: ANZWOARUBDXLMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  23
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  62.8
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 危险等级：
  8
• 包装等级：
  III

制备方法与用途

制备方法：由氯代烷与苯缩合得到烷基苯，再用三氧化硫或发烟硫酸等进行磺化。

合成制备方法：同样由氯代烷与苯缩合得到烷基苯，随后使用三氧化硫、发烟硫酸等进行磺化。

反应信息

• 作为反应物：
  描述：

  十三烷基苯磺酸 、 manganese(III) acetylacetonate 以 苯 为溶剂， 生成
  参考文献：
  名称：

  摘要：

  Mixed-ligand Mn(Ill) complexes were prepared from manganese tris(acetylacetonate) and alkyl-benzenesulfonic acid, and their surface activity and initiating power with respect to polymerization of vinyl monomers differing in reactivity and water solubility were studied.

  DOI：

  10.1023/a:1013722816708
• 作为产物：
  描述：

  十三烷基苯 在 氯磺酸 作用下， 以 氯仿 为溶剂， 反应 3.0h， 以80%的产率得到十三烷基苯磺酸
  参考文献：
  名称：

  有机金属苄基钠的连续流动制备

  摘要：

  据报道，在 TMEDA 存在下，使用按需生成的 (2-乙基己基)钠对烷基（杂）芳烃进行横向钠化。使用各种亲电子试剂来捕获连续流动以及批量产生的苄基钠物质。使用在线淬火放大连续流金属化。该方法用于多种工业相关化合物的合成。

  DOI：

  10.1002/anie.202203807

文献信息

• Photoresist remover compositions
  申请人：Merck Patent GmbH

  公开号：US11366392B2

  公开（公告）日：2022-06-21

  The present invention relates to a composition consisting essentially of an alkylbenzenesulfonic acid having structure (I) (wherein n is an integer from 0 to 16); a solvent which is either selected from the group consisting of solvents having structures (II), (wherein R is selected from the group consisting of —(—O—CH2—CH2—)n—OH, —OH, —O—C(═O)—CH3, wherein n′ is equal to 1, 2, 3, or 4), a solvent having structure (III), a solvent having structure (IV), and a solvent having structure (V), or a solvent mixture, of at least two solvents selected from this group. In another embodiment, the composition also consists of, additionally, a surfactant component. This invention also relates to using either of these compositions to remove a patterned photoresist from a substrate.

  本发明涉及一种组合物，其主要成分为具有结构（I）的烷基苯磺酸（其中 n 为 0 至 16 的整数）；溶剂，该溶剂可以选自具有结构(II)的溶剂（其中R选自-(-O-CH2- -)n-OH、-OH、-O-C(═O)-CH3组成的组，其中n′等于1、2、3或4）、具有结构(III)的溶剂、具有结构(IV)的溶剂和具有结构(V)的溶剂，或至少两种选自该组的溶剂混合物。在另一个实施方案中，组合物还包括表面活性剂成分。本发明还涉及使用这些组合物中的任一种从基底上去除图案化光阻。
• Rubber modified asphalt cement compositions and methods
  申请人：RAM Technologies Group, Inc.

  公开号：US20040225036A1

  公开（公告）日：2004-11-11

  The present invention discloses methods of making improved rubber modified asphalt cement compositions, and compositions made by the method, where the compositions are useful in paving, roofing, coating and other sealing applications. In one aspect, the method comprises combining asphalt, RVPR (or a blended mixture of asphalt and RVPR) and at least one dodecyl or tridecylbenzene sulfonic acid (SA), which can be linear (LAS) or branched (BAS), in the presence of moderate heat. After heating the resultant RMAC mixture exhibits at least one of the following: ( 1 ) an increase in softening point, ( 2 ) an increase in hardness, or ( 3 ) improved recovery from deformation. In another aspect, the invention teaches addition of at least one SA to previously manufactured RMAC to accomplish at least one of the following: ( 1 ) an increase in softening point, ( 2 ) an increase in hardness, or ( 3 ) improved recovery from deformation. For paving compositions, the resultant RMAC mixtures made by the methods of the invention are mixed with an appropriate grade of aggregate composition, and other paving materials as desired.

  本发明公开了制造改进型橡胶改性沥青水泥组合物的方法，以及用该方法制造的组合物，其中组合物可用于铺路、屋顶、涂层和其他密封应用。在一个方面，该方法包括在适度加热的情况下，将沥青、RVPR（或沥青和 RVPR 的混合混合物）和至少一种十二烷基或十三烷基苯磺酸（SA）（SA 可以是线性的（LAS）或支链的（BAS））混合在一起。加热后，得到的 RMAC 混合物至少表现出以下一种特性：( 1 软化点升高， ( 2 ) 硬度增加，或 ( 3 ) 提高变形恢复能力。在另一方面，本发明教导在先前制造的 RMAC 中添加至少一种 SA，以实现以下至少一项：( 1 提高软化点 2 增加硬度，或 3 提高变形恢复能力。对于铺路组合物，用本发明的方法制成的 RMAC 混合物可与适当等级的骨料组合物以及所需的其他铺路材料混合。
• Smectic Liquid Crystals from Supramolecular Guanidinium Alkylbenzenesulfonates
  作者：Fabrice Mathevet、Patrick Masson、Jean-François Nicoud、Antoine Skoulios

  DOI：10.1002/1521-3765(20020517)8:10<2248::aid-chem2248>3.0.co;2-b

  日期：2002.5.17

  A homologous series of guanidinium alkylbenzenesulfonates from ethyl to tetradecyl were synthesized and characterised. Their thermotropic polymorphism was investigated by polarizing optical microscopy. differential scanning calorimetry, and dilatometry. The structure of the smectic liquid crystal phases obtained at high temperature with the compounds from octyl to tetradecyl was analysed by X-ray diffraction. The supramolecular assembling of the ionic species inside the smectic layers was investigated by infrared spectroscopy.
• Method for producing binder resin, particulate resin dispersion and method for producing same, electrostatic image development toner and method for producing same, electrostatic image developer, and image forming method
  申请人：Sasaki Yuki

  公开号：US20070122730A1

  公开（公告）日：2007-05-31

  A method for producing a binder resin comprises polycondensing a polycondensable monomer by using a polycondensation catalyst that comprises: at least one of compounds of formula (I) or (II); and at least one of compounds represented of formula (III) or (IV), wherein weight ratio of total amount of the compounds of formula (I) or (II) to total amount of the compounds of formula (III) or (IV) is from 5:95 to 95:5: wherein R 1 represents a C 8 -C 20 straight-chain alkyl group; R 2 represents a monovalent organic group; and number n of substituents R 2 represents an integer of from 0 to 4; R 3 —SO 3 H  (II) wherein R 3 represents a C 8 -C 20 straight-chain alkyl group; wherein R 4 represents a C 8 -C 20 branched alkyl group; R 5 represents a monovalent organic group; and number m of substituents R 5 represents an integer of from 0 to 4; and R 6 —SO 3 H  (IV) wherein R 6 represents a C 8 -C 20 branched alkyl group.
• Mechanical Element
  申请人：Kawata Ken

  公开号：US20080081772A1

  公开（公告）日：2008-04-03

  A novel mechanical element is disclosed. The mechanical element comprises at least two surfaces movable at peripheral speeds differed from each other, and a lubricant composition disposed between said two surfaces, a surface of at least one said two surfaces having an organic residue having carboxyl group, sulfoxyl group, cyclic or non-cyclic carbamoyl group, cyclic or non-cyclic ureylene group, cyclic or non-cyclic sulfarnoyl group, or cyclic or non-cyclic amidino group, and said lubricant composition comprising a discotic compound having at least one tautomeric group represented by a formula (1) in which A is a ring in which from 5 to 7 atoms are embedded, wherein one of, or two or more of the ring-composing atoms may have a substituent, or may be condensed with other ring.