piperidine o-phthalate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: piperidine o-phthalate
• 英文别名: piperidinium phthalate；Phthalic acid;piperidine
• 化学式: 2C₅H₁₁N*C₈H₆O₄
• 分子量: 336.431
• InChiKey: FSDDNHGQVBYPDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.84
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  86.6
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  nickel(II) perchlorate hexahydrate 、 piperidine o-phthalate 在 2,2'-bipyridyl 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Novel structure of nickel(II) complex Ni(phth)(bpy)(H2O)3 (phth2− = the dianion of phthalic acid; bpy = 2,2′-bipyridine)

  摘要：

  In the title compound the coordination environment around nickel(II) is an octahedron composed of atoms N(1) and N(2) of 2,2'-bipyridine. O(5). O(6) and O(7) of three aquamolecules and O(3) of one carboxyl of the phthalate. The oxygen. O(1). of the other carboxyl of the phthalate does not coordinate to nickel(II). There is an electrostatic interaction between the negative ion of this carboxyl and the nickel(II) positive ion.

  DOI：

  10.1016/s0277-5387(00)80060-1

文献信息

• Antiferromagnetism tuned by the topology of the intervening bridging ligand. Crystal structure and magnetic properties of the (μ-phthalato){[bis(piperidine)]Cu(II)} chain complex
  作者：Evangelos G. Bakalbassis、Aris Terzis

  DOI：10.1016/0020-1693(94)03806-6

  日期：1994.4

  compound is a chain copper(II) complex, [(pip) 2 Cu(μ-phth)] n being the polymeric entity. Within the chain the copper(II) ions are bridged by the phth ligand in an anisobidentate fashion, the coordination geometry about each Cu(II) ion is distorted octahedral; two nitrogen atoms belonging to two piperidine molecules along with two carboxylato oxygen atoms of two different phthalato bridges occupy the

  摘要用单晶X射线法测定了[（μ-phth）（pip）2 Cu] n链状配合物的晶体结构，其中phth为邻苯二甲酸的二价阴离子，pip为哌啶。该复合物在单斜空间群I 2 / a中结晶，其中α= 15.853（2），b = 10.785（1），c = 11.629（1）A，β= 111.321（3）°，Z = 4和V = 1852.11 A 3。对结构的求解导致R = 0.0298和R w = 0.0330的最终值，其中F o>6.5σ（F o）的1578次唯一反射的167个最小二乘参数。该化合物是链状铜（II）络合物，[（pip）2 Cu（μ-phth）] n是聚合物。在链中，铜（II）离子被phth配体以异源方式桥接，围绕每个Cu（II）离子的配位几何结构呈八面体形；属于两个哌啶分子的两个氮原子与两个不同邻苯二甲酸桥的两个羧基氧原子一起占据赤道位置，而相同羧基的两个剩余氧原子占据轴向位置。
• Synthesis and magnetism of μ-phthalato binuclear lanthanide(III) complexes (Ln = Gd, Tb, Ho, Er)
  作者：Xiao-Ying Li、Zong-Hui Jiang、Dai-Zheng Liao、Shi-Ping Yan、Yan-Tuan Li、Geng-Lin Wang

  DOI：10.1016/s0277-5387(00)86643-7

  日期：1994.1

  Abstract Four novel binuclear Ln(III) complexes containing the dianion of phthalic acid(phth) as a bridging ligand have been synthesized, namely [(Ln2(phth)(phen)4] (ClO4)4·xH2O (Ln = Gd, Tb, Ho, Er; Phen = 1,10-phenanthroline; phth = dianion of phthalic acid). The complexes have been characterized by elemental analyses, IR, electronic spectra, ESR and conductances. The variable-temperature magnetic

  摘要合成了四种新型的双核Ln（III）配合物，它们以邻苯二甲酸（phth）的二价阴离子为桥联配体，即[（Ln2（phth）（phen）4]（ClO4）4·xH2O（Ln = Gd，Tb ，Ho，Er; Phen = 1,10-菲咯啉; phth =邻苯二甲酸二阴离子）。通过元素分析，红外光谱，电子光谱，ESR和电导对络合物进行了表征。可变温度磁化率（4–300 K确定了复数Gd2 [（phth）（phen）4]（ ）4，并通过最小二乘法获得了自旋哈密顿算子Ĥ= −2JŜ1·Ŝ2的理论曲线的满意拟合。交换相互作用参数为J = -0.25 cm-1，表明络合物中镧系元素离子之间存在弱的反铁磁自旋交换相互作用。
• Composition for film formation, method of film formation, and silica-based film
  申请人：JSR CORPORATION

  公开号：US20030091838A1

  公开（公告）日：2003-05-15

  A composition for film formation which comprises: (A) a product of hydrolysis and condensation obtained by hydrolyzing and condensing at least one silane compound selected from the group consisting of compounds represented by the formula (1), compounds represented by the formula (2), and compounds represented by the formula (3) in the presence of water and an ammonium compound, and (B) an organic solvent.

  一种用于成膜的组合物，它包括 (A) 至少一种硅烷化合物的水解和缩合产物，该硅烷化合物选自由式（1）、式（2）和式（3）所代表的化合物组成的组，在水和铵化合物存在下水解和缩合得到，以及 (B) 有机溶剂。
• Synthesis, structure and magnetic properties of a novel 4,4′-azopyridine-bridged cobalt coordination polymer
  作者：Li-Na Zhu、Mao Liang、Qing-Lun Wang、Wen-Zhen Wang、Dai-Zheng Liao、Zong-Hui Jiang、Shi-Ping Yan、Peng Cheng

  DOI：10.1016/s0022-2860(03)00365-x

  日期：2003.9

  A novel coordination polymer [Co(azpy)(pht)(H2O)(3)](n) 1 (azpy = 4,4'-Azopyridine, pht = o-phtalate), has been synthesized and characterized by X-ray diffraction. 1 crystallizes in the monoclinic space group P2(1)/c, a = 10.469(5) Angstrom, b = 24.607(13) Angstrom, c = 7.818(4) Angstrom, beta = 96.506(9)degrees, V = 2001.0(18) Angstrom(3), Z = 4. Its structure consists of one-dimensional chains formed by the connecting of the adjacent cobalt(II) ions via azpy ligand bridges. The one-dimensional chains are braced by interchain hydrogen bonds and C-(HO)-O-... interactions to construct a compact high-dimensional network structure. The most striking feature of 1 is that the adjacent cobalt(II) ions bridged by azpy ligand are in different distorted octahedral coordination environment. Magnetic susceptibility measurements in the range 77-300 K show very weak antiferromagnetic exchange between the cobalt(H) ions (zJ = -8.40 cm(-1)). (C) 2003 Elsevier B.V. All rights reserved.
• Ma, Shu-Lin; Liao, Dai-Zheng; Jiang, Zong-Hui, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1994, vol. 24, p. 137 - 146
  作者：Ma, Shu-Lin、Liao, Dai-Zheng、Jiang, Zong-Hui、Yan, Shi-Ping、Xue, Feng-Chun、Wang, Geng-Lin

  DOI：——

  日期：——