tetrakis[2-(triphenylstannyl)ethylene]silane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrakis[2-(triphenylstannyl)ethylene]silane
• 化学式: C₈₀H₇₆SiSn₄
• 分子量: 1540.41
• InChiKey: GERFPZBSMVBIQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  19.09
• 重原子数：
  85
• 可旋转键数：
  4
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetrakis[2-(triphenylstannyl)ethylene]silane 、 溴 以 四氯化碳 为溶剂， 以71%的产率得到tetrakis[2-(tribromostannyl)ethyl]silane
  参考文献：
  名称：

  Si(CH2CH2SnH3)4—a unique organotin hydride featuring 12 SnH units in a dendritic molecule. Single-crystal X-ray structures of tetrakis(2-stannylethylene)silane and tetrakis[2-(triphenylstannyl)ethylene]silane

  摘要：

  Fourfold hydrostannation of tetravinylsilane affords the first generation metallodendrimer Si(CH2CH2SnPh3)(4) (1). Selective bromination yields Si(CH2CH2SnBr3)(4) (2), which can be reduced by LiAlH4 to give Si(CH2CH2SnH3)(4) (3), containing 12 reactive Sn-H bonds. These novel dendritic organotin compounds were characterized by elemental analysis, spectroscopic studies (H-1-, C-13-, Sn-119-NMR; IR) and by single-crystal X-ray structure determination. The molecular structures of 1 and 3 reveal increased conformational constraint in 1; the average Sn-H bond length in 3 is 1.60(7) Angstrom. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00188-1
• 作为产物：
  描述：

  四乙烯硅烷 、 三苯基氢化锡 在 H₂PtCl₆ 作用下， 以 neat (no solvent) 为溶剂， 以90%的产率得到tetrakis[2-(triphenylstannyl)ethylene]silane
  参考文献：
  名称：

  Si(CH2CH2SnH3)4—a unique organotin hydride featuring 12 SnH units in a dendritic molecule. Single-crystal X-ray structures of tetrakis(2-stannylethylene)silane and tetrakis[2-(triphenylstannyl)ethylene]silane

  摘要：

  Fourfold hydrostannation of tetravinylsilane affords the first generation metallodendrimer Si(CH2CH2SnPh3)(4) (1). Selective bromination yields Si(CH2CH2SnBr3)(4) (2), which can be reduced by LiAlH4 to give Si(CH2CH2SnH3)(4) (3), containing 12 reactive Sn-H bonds. These novel dendritic organotin compounds were characterized by elemental analysis, spectroscopic studies (H-1-, C-13-, Sn-119-NMR; IR) and by single-crystal X-ray structure determination. The molecular structures of 1 and 3 reveal increased conformational constraint in 1; the average Sn-H bond length in 3 is 1.60(7) Angstrom. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00188-1

文献信息

• Si(CH2CH2SnH3)4—a unique organotin hydride featuring 12 SnH units in a dendritic molecule. Single-crystal X-ray structures of tetrakis(2-stannylethylene)silane and tetrakis[2-(triphenylstannyl)ethylene]silane
  作者：Herbert Schumann、Birgit C. Wassermann、Michaela Frackowiak、Bamidele Omotowa、Stefan Schutte、Janna Velder、Stefan H. Mühle、Werner Krause

  DOI：10.1016/s0022-328x(00)00188-1

  日期：2000.9

  Fourfold hydrostannation of tetravinylsilane affords the first generation metallodendrimer Si(CH2CH2SnPh3)(4) (1). Selective bromination yields Si(CH2CH2SnBr3)(4) (2), which can be reduced by LiAlH4 to give Si(CH2CH2SnH3)(4) (3), containing 12 reactive Sn-H bonds. These novel dendritic organotin compounds were characterized by elemental analysis, spectroscopic studies (H-1-, C-13-, Sn-119-NMR; IR) and by single-crystal X-ray structure determination. The molecular structures of 1 and 3 reveal increased conformational constraint in 1; the average Sn-H bond length in 3 is 1.60(7) Angstrom. (C) 2000 Elsevier Science S.A. All rights reserved.