N³-(3-pyridoyl)-3-pyridinecarboxamidrazone

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: N³-(3-pyridoyl)-3-pyridinecarboxamidrazone
• 英文别名: ppad；N-[(Z)-[amino(pyridin-3-yl)methylidene]amino]pyridine-3-carboxamide
• 化学式: C₁₂H₁₁N₅O
• 分子量: 241.252
• InChiKey: IIWPKEKJLKZWSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  93.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N³-(3-pyridoyl)-3-pyridinecarboxamidrazone 、 cobalt(II) diacetate tetrahydrate 以 水 为溶剂， 反应 120.0h， 以67%的产率得到Co(ppad)₂
  参考文献：
  名称：

  Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from Co^II Nodes and a Pyridylhydrazone Derivative

  摘要：

  A novel two-dimensional (2D) coordination polymer, [Co(ppad)(2)](n) (1), resulted from the assembly of Co-II ions based on a versatile ligand termed N-3-(3-p-yridoyl)-3-pyridinecarboxamidrazone. Alternating/direct-current magnetic studies of compound 1 indicate that the spatially separated high-spin Co-II ions act as single-ion magnets (SIMs). The present work represents the first case of a 2D Co-II-based SIM composed of a monocomponent organic spacer.

  DOI：

  10.1021/acs.inorgchem.5b01651
• 作为产物：
  描述：

  3-氰基吡啶 、 3-吡啶甲酰肼 在 sodium 、 溶剂黄146 作用下， 以 甲醇 为溶剂， 反应 1.0h， 以72%的产率得到N³-(3-pyridoyl)-3-pyridinecarboxamidrazone
  参考文献：
  名称：

  Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from Co^II Nodes and a Pyridylhydrazone Derivative

  摘要：

  A novel two-dimensional (2D) coordination polymer, [Co(ppad)(2)](n) (1), resulted from the assembly of Co-II ions based on a versatile ligand termed N-3-(3-p-yridoyl)-3-pyridinecarboxamidrazone. Alternating/direct-current magnetic studies of compound 1 indicate that the spatially separated high-spin Co-II ions act as single-ion magnets (SIMs). The present work represents the first case of a 2D Co-II-based SIM composed of a monocomponent organic spacer.

  DOI：

  10.1021/acs.inorgchem.5b01651

文献信息

• Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from Co^II Nodes and a Pyridylhydrazone Derivative
  作者：Xiangyu Liu、Lin Sun、Huiliang Zhou、Peipei Cen、Xiaoyong Jin、Gang Xie、Sanping Chen、Qilin Hu

  DOI：10.1021/acs.inorgchem.5b01651

  日期：2015.9.21

  A novel two-dimensional (2D) coordination polymer, [Co(ppad)(2)](n) (1), resulted from the assembly of Co-II ions based on a versatile ligand termed N-3-(3-p-yridoyl)-3-pyridinecarboxamidrazone. Alternating/direct-current magnetic studies of compound 1 indicate that the spatially separated high-spin Co-II ions act as single-ion magnets (SIMs). The present work represents the first case of a 2D Co-II-based SIM composed of a monocomponent organic spacer.