N3P(Ph2)(CCl)2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N3P(Ph2)(CCl)2
• 英文别名: 4,6-Dichloro-2,2-diphenyl-1,3,5-triaza-2lambda5-phosphacyclohexa-1,3,5-triene；4,6-dichloro-2,2-diphenyl-1,3,5-triaza-2λ5-phosphacyclohexa-1,3,5-triene
• 化学式: C₁₄H₁₀Cl₂N₃P
• 分子量: 322.133
• InChiKey: CFKCORDADPGCAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  咪唑钠 、 N3P(Ph2)(CCl)2 以 四氢呋喃 为溶剂， 反应 20.0h， 以75%的产率得到
  参考文献：
  名称：

  Unexpected reactions of dicarbaphosphazenes with fluoride and N-methyl imidazole

  摘要：

  Reactions of dicarbaphosphazenes with N-methyl imidazole and fluoride ion have been studied. In contrast to earlier observations of dealkylation reactions, these reactions with imidazole led to quaternized products. Attempted fluorination of dicarbaphosphazene led to rupture of the phosphazene ring explaining the non-existence of fluorinated analog of carbaphosphazenes. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.032

文献信息

• Unexpected reactions of dicarbaphosphazenes with fluoride and N-methyl imidazole
  作者：Khevath Praveen Kumar Naik、Krishnamurthi Muralidharan、Jean’ne M. Shreeve

  DOI：10.1016/j.ica.2011.02.032

  日期：2011.6

  Reactions of dicarbaphosphazenes with N-methyl imidazole and fluoride ion have been studied. In contrast to earlier observations of dealkylation reactions, these reactions with imidazole led to quaternized products. Attempted fluorination of dicarbaphosphazene led to rupture of the phosphazene ring explaining the non-existence of fluorinated analog of carbaphosphazenes. (C) 2011 Elsevier B.V. All rights reserved.