2,3,6,7-tetrakis(dodecyloxy)anthracene-9,10-dione

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 2,3,6,7-tetrakis(dodecyloxy)anthracene-9,10-dione
• 英文别名: 2,3,6,7-Tetradodecoxyanthracene-9,10-dione；2,3,6,7-tetradodecoxyanthracene-9,10-dione
• 化学式: C₆₂H₁₀₄O₆
• 分子量: 945.504
• InChiKey: YMYQXFZAHOASAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.1
• 重原子数：
  68
• 可旋转键数：
  48
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.77
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3,6,7-tetrakis(dodecyloxy)anthracene-9,10-dione 在 copper(II) sulfide 、 sodium hydroxide 、 锌 作用下， 以 水 、 甲苯 为溶剂， 反应 15.0h， 生成 2,3,6,7-tetrakis(dodecyloxy)anthracene-9-one
  参考文献：
  名称：

  ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER

  摘要：

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。

  公开号：

  US20190031586A1
• 作为产物：
  描述：

  2,3,6,7-四甲氧基蒽醌 在 四丁基溴化铵 、 氢溴酸 、 potassium carbonate 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 25.5h， 生成 2,3,6,7-tetrakis(dodecyloxy)anthracene-9,10-dione
  参考文献：
  名称：

  유기 화합물 및 이를 사용하여 형성된 3차원 유기 구조체

  摘要：

  提供三维有机结构。 该有机结构包括通过非共价键合自组装而成的多个有机分子。 每个有机分子都具有第一对取代基和第二对取代基，它们分别与芳香环和相邻的取代位点上的取代基结合。 这些有机分子通过取代基之间的范德华力、伦敦分散作用或氢键以及芳香环之间的π-π相互作用进行自组装。

  公开号：

  KR20180043221A

文献信息

• 유기 화합물 및 이를 사용하여 형성된 3차원 유기 구조체
  申请人：IUCF-HYU (Industry-University Cooperation Foundation Hanyang University) 한양대학교 산학협력단(220040114276) BRN ▼206-82-07306

  公开号：KR20180043221A

  公开（公告）日：2018-04-27

  3차원 유기 구조체를 제공한다. 상기 유기 구조체는 비공유 결합에 의해 자기조립된 다수 개의 유기 분자들을 포함한다. 각 유기 분자는 방향족 고리와 상기 방향족 고리의 치환가능한 위치들 중 바로 인접한 위치들에 각각 결합된 치환기들의 제1 쌍과 나머지 치환가능한 위치들 중 바로 인접한 위치들에 각각 결합된 치환기들의 제2 쌍을 구비한다. 상기 유기 분자들은 상기 치환기들의 제1 쌍과 제2 쌍 사이의 반 데르 발스(Van Der Waals) 상호작용, 런던 분산력(London dispersion interaction) 또는 수소 결합(hydrogen bonding)과 방향족 고리들 사이의 파이-파이 상호작용에 의해 자기 조립된다.

  提供三维有机结构。 该有机结构包括通过非共价键合自组装而成的多个有机分子。 每个有机分子都具有第一对取代基和第二对取代基，它们分别与芳香环和相邻的取代位点上的取代基结合。 这些有机分子通过取代基之间的范德华力、伦敦分散作用或氢键以及芳香环之间的π-π相互作用进行自组装。
• Organic compound, three-dimensional organic framework formed by using organic compound, separation sieve and optical layer, which comprise organic framework, and optical device comprising optical layer as optical amplification layer
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US11066351B2

  公开（公告）日：2021-07-20

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  本文提供了一种有机化合物、利用该有机化合物形成的三维有机结构、具有该有机结构的分离筛和光学层，以及具有该光学层作为光放大层的光学设备。有机结构包括多个通过非共价键自组装的有机分子。每个单元有机分子都有一个芳香环，第一对取代基连接到芳香环可取代位置的紧邻位置，第二对取代基连接到芳香环其余可取代位置的紧邻位置。通过第一对和第二对取代基之间的范德华相互作用、伦敦色散相互作用或氢键作用，以及芳香环之间的π-π相互作用，单元有机分子得以自组装。
• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。