1-((heptyloxy)methyl)-4-vinylbenzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-((heptyloxy)methyl)-4-vinylbenzene
• 英文别名: 1-Ethenyl-4-(heptoxymethyl)benzene
• 化学式: C₁₆H₂₄O
• 分子量: 232.366
• InChiKey: IBYRUGJFSIKNJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  正庚醇 、 4-氯甲基苯乙烯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 26.0h， 以81%的产率得到1-((heptyloxy)methyl)-4-vinylbenzene
  参考文献：
  名称：

  通用的可溶性低聚苯乙烯载体，可用于肽合成

  摘要：

  此处报道的可溶性低聚苯乙烯载体具有1.5–1.6 mmol / g的高负载量，类似于固相肽合成中使用的树脂。将寡醚和烷基链掺入到支架中以改善载体的溶解性并充当连接位点之间的间隔基。氨基酸以59–85％的收率和0.87–1.3 mmol / g的负载量与载体连接。仅使用2当量的偶联剂，该载体就可以38-64％的产率合成三肽至六肽，这比固相合成中通常使用的试剂量要低得多。使用模块化的合成方法来获得支撑物，以便任何有效的基于苯乙烯的附着位点都可以轻松地整合到我们的可溶性支撑物支架中。©2015 Wiley Periodicals，Inc. J. Polym。科学，A部分：Polym。化学2015年，53，2501至2509年

  DOI：

  10.1002/pola.27714

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。
• Method for producing charge transport film
  申请人：Ishitsuka Kenichi

  公开号：US10566105B2

  公开（公告）日：2020-02-18

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y1-Y6 each independently represent a divalent linking group, R1-R6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R1, R2 and R3, or, R4-R6 can respectively combine and become a ring shape or a polymer shape) and L+ represents a monovalent cation.)

  本发明公开了一种有机电子材料，该材料由电荷传输化合物和离子化合物组成，离子化合物具有电子接受特性和在溶剂中的高溶解度。该有机电子材料的特点是由电荷传输化合物和离子化合物组成，其中至少一种离子化合物是通式（1b）-（3b）所代表的任何一种化合物。(在式中，Y1-Y6各自独立地代表二价连接基团，R1-R6各自独立地代表引电子有机取代基（这些结构可以进一步具有取代基和杂原子，R1、R2和R3，或，R4-R6可以分别结合成为环形或聚合物形），L+代表一价阳离子)。
• Organic electronic material, ink composition containing same, and organic thin film, organic electronic element, organic eletroluminescent element, lighting device, and display device formed therewith
  申请人：Hitachi Chemical Company, Ltd.

  公开号：US10840451B2

  公开（公告）日：2020-11-17

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  本发明提供了：易于多层化且可用于无法在高温下加工的树脂等基板的有机电子材料；含有该有机电子材料的油墨组合物；使用所述有机电子材料或所述油墨组合物形成的有机薄膜；以及使用所述有机薄膜形成的发光效率和发射寿命优于传统元件的有机电子元件和有机电致发光元件。具体地说，提供了：有机电子材料，其特征在于含有低聚物或聚合物，该低聚物或聚合物具有向三个或更多方向分支的结构，并具有至少一个可聚合的取代基；含有所述有机电子材料的油墨组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了含有上述有机薄膜的有机电子元件和有机电致发光元件。
• ORGANIC ELECTRONIC MATERIAL, INK COMPOSITION CONTAINING SAME, AND ORGANIC THIN FILM, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, AND DISPLAY DEVICE FORMED THEREWITH
  申请人：Showa Denko Materials Co., Ltd.

  公开号：EP2439804B1

  公开（公告）日：2021-07-21