4-(6-acryloylhex-1-yloxy)benzoic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(6-acryloylhex-1-yloxy)benzoic acid
• 英文别名: 4-(6-acryloyl-hex-1-yloxy)benzoic acid；4-(6-acryloyl-hexyloxy)benzoic acid；4-(6-acryloylhexyloxy)-benzoic acid；4-(6-Acryloylhexyloxy)benzoic acid；4-(7-oxonon-8-enoxy)benzoic acid
• 化学式: C₁₆H₂₀O₄
• 分子量: 276.332
• InChiKey: DTBNPTQBRPZVCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,5-二羟基苯甲醛 、 4-(6-acryloylhex-1-yloxy)benzoic acid 在 4-二甲氨基吡啶 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 12.0h， 以75.4%的产率得到[3-formyl-4-[4-(6-prop-2-enoyloxyhexoxy)benzoyl]oxy-phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
  参考文献：
  名称：

  POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC PRODUCT

  摘要：

  这项发明提供了一种可聚合化合物，其表示为式(I)，一种含有该可聚合化合物和聚合引发剂的可聚合组合物，通过聚合该可聚合化合物或可聚合组合物而制备的聚合物，以及作为构成材料的聚合物的光学各向异性产品。在式(1)中，Y1至Y9代表—O—、—S—、—O—C(═O)—、—C(═O)—O—或类似物，G1和G2代表具有1至20个碳原子的双价直链脂肪族基或类似物，Z1至Z3代表具有2至10个碳原子的烯基基团或类似物，Ax代表由式(II)表示的基团，其中X代表氧原子、硫原子或类似物，D代表具有1至20个碳原子的烷基基团或类似物，A1代表三价芳香族基或类似物，A2和A3代表具有3至30个碳原子的双价脂环烃基或类似物，A4和A5代表具有4至30个碳原子的双价芳香族基或类似物，Q1代表具有1至6个碳原子的烷基基团或类似物，m和n为0或1。

  公开号：

  US20160257659A1

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC BODY, AND METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20150175564A1

  公开（公告）日：2015-06-25

  A polymerizable compound has a practical low melting point, excellent solubility in a general-purpose solvent, and can produce an optical film at low cost, exhibits low reflected luminance, and achieves uniform conversion of polarized light over a wide wavelength band, an optically anisotropic article. A carbonyl compound is useful as a raw material for producing the polymerizable compound. (In the formula (I), Y 1 to Y 8 represent —C(═O)—O—, G 1 and G 2 represent a C 1-20 divalent linear aliphatic group, Z 1 and Z 2 represent a C 2-10 alkenyl group that is unsubstituted, or substituted with a halogen atom, A x represents a C 2-30 organic group with at least one aromatic ring, A y represents a hydrogen atom or C 1-20 alkyl group, A 1 represents a trivalent aromatic group, A 2 and A 3 represent a C 3-30 divalent alicyclic hydrocarbon group, A 4 and A 5 represent a C 6-30 divalent aromatic group or the like, and Q 1 represents a hydrogen atom.)

  一种可聚合的化合物具有实用的低熔点、在通用溶剂中良好的溶解性，并且可以以低成本制备光学薄膜，表现出较低的反射亮度，并且在宽波长范围内实现偏振光的均匀转换，是一种光学各向异性材料。一种羰基化合物可作为制备可聚合化合物的原料。（在式（I）中，Y1至Y8代表—C(═O)—O—，G1和G2代表C1-20二价线性脂肪族基团，Z1和Z2代表未取代或取代有卤素原子的C2-10烯基基团，Ax代表至少具有一个芳香环的C2-30有机基团，Ay代表氢原子或C1-20烷基基团，A1代表三价芳香族基团，A2和A3代表C3-30二价脂环碳氢基团，A4和A5代表C6-30二价芳香族基团或类似物，Q1代表氢原子。）
• POLYMERIZABLE COMPOUND, POLYMERIZABLE LIQUID CRYSTAL MIXTURE, POLYMER, OPTICAL FILM, OPTICALLY ANISOTROPIC BODY, POLARIZING PLATE, DISPLAY DEVICE, ANTIREFLECTION FILM, AND COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20200031786A1

  公开（公告）日：2020-01-30

  Disclosed is a polymerizable compound useful for preparing a polymer that enables the production of a film, such as an optical film, which has a good balance of lightness and saturation and which can improve reverse wavelength dispersion on the short wavelength side while achieving reverse wavelength dispersion on the longer wavelength side. The polymerizable compound of the present disclosure is represented by: where in the formula (I-1), A 1 and A 2 each independently represent an aromatic group which may have a substituent, B 1 and B 2 each independently represent a cyclic aliphatic group which may have a substituent, or, an aromatic group which may have a substituent, and p and q each independently represent an integer from 0 to 2.

  本公开揭示了一种可用于制备聚合物的聚合物化合物，该聚合物使得可以生产具有良好轻度和饱和度平衡的薄膜，例如光学薄膜，该薄膜可以改善短波长侧的反向波长色散，同时实现长波长侧的反向波长色散。本公开的聚合物化合物由以下式表示：在公式（I-1）中，A1和A2各自独立表示可能具有取代基的芳香族，B1和B2各自独立表示可能具有取代基的环状脂肪族，或者可能具有取代基的芳香族，p和q各自独立地表示0到2之间的整数。
• METHOD OF PRODUCING POLYMERIZABLE COMPOUND, AND SOLUTION OF POLYMERIZABLE COMPOUND
  申请人：ZEON CORPORATION

  公开号：US20200283399A1

  公开（公告）日：2020-09-10

  Disclosed is a method of producing a polymerizable compound that enables production of, in high yield, a polymerizable compound used for producing an optical film or the like. The disclosed method of producing a polymerizable compound comprises reacting a compound represented by formula (I) with a compound represented by formula (II) in an organic solvent in which a base having a pKa from 6.1 to 9.5 is present, so as to obtain a reaction solution containing a polymerizable compound represented by formula (III).

  公开了一种生产可聚合化合物的方法，该方法能够高产地生产用于制备光学薄膜等的可聚合化合物。所公开的生产可聚合化合物的方法包括在含有具有pKa值在6.1至9.5之间的碱的有机溶剂中，将式(I)所代表的化合物与式(II)所代表的化合物反应，以获得含有式(III)所代表的可聚合化合物的反应溶液。
• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICALLY ANISOTROPIC SUBSTANCE
  申请人：ZEON CORPORATION

  公开号：US20150274647A1

  公开（公告）日：2015-10-01

  The present invention relates to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer [in the formula, Y 1 to Y 8 are a chemical single bond, —O—, —O—C(═O)—, —C(═O)—O—, or the like; G 1 and G 2 are a divalent aliphatic group having 1 to 20 carbon atoms, or the like; Z 1 and Z 2 are an alkenyl group having 2 to 10 carbon atoms, or the like; A 1 is a tetravalent aromatic group, or the like; A 2 and A 3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, or the like; A 4 and A 5 are a divalent aromatic group having 4 to 30 carbon atoms, or the like; A x1 and A x2 are an organic group having 2 to 30 carbon atoms that includes an aromatic ring, or the like; A y1 and A y2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; Q 1 and Q 2 are a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, or the like; and m and n are 0 or 1]. According to the present invention, a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article.

  本发明涉及：由式(I)表示的可聚合化合物；包括所述可聚合化合物和引发剂的可聚合组合物；通过聚合所述可聚合化合物或可聚合组合物得到的聚合物；以及包括所述聚合物的光学各向异性物品[在该式中，Y1至Y8为化学单键，—O—，—O—C(═O)—，—C(═O)—O—等；G1和G2为具有1至20个碳原子的二价脂肪族基等；Z1和Z2为具有2至10个碳原子的烯基基团等；A1为四价芳香族基等；A2和A3为具有3至30个碳原子的二价脂环烃基等；A4和A5为具有4至30个碳原子的二价芳香族基等；Ax1和Ax2为包括芳香环的具有2至30个碳原子的有机基团等；Ay1和Ay2为氢原子、具有1至6个碳原子的烷基基团等；Q1和Q2为氢原子、具有1至6个碳原子的烷基基团等；m和n为0或1]。根据本发明，可以制备具有实用低熔点、在通用溶剂中具有优异溶解性、成本低廉的可聚合化合物、可聚合组合物和聚合物，并且可以生产出在宽波长范围内实现偏振光均匀转换的光学薄膜，同时提供光学各向异性物品。
• POLYMERIZABLE CHIRAL COMPOUND, POLYMERIZABLE LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL POLYMER AND OPTICALLY ANISOTROPIC BODY
  申请人：Sakamoto Kei

  公开号：US20130023637A1

  公开（公告）日：2013-01-24

  The present invention is to provide a novel polymerizable chiral compound (chiral agent) having high left-handed helical twisting power, a polymerizable liquid crystal composition comprising the polymerizable chiral compound and a polymerizable liquid crystal compound, a liquid crystal polymer, and an optically anisotropic body. The object was achieved by a left-handed-helix-inducing polymerizable chiral compound represented by the following formula (I), a polymerizable liquid crystal composition comprising the polymerizable chiral compound and a polymerizable liquid crystal compound, a liquid crystal polymer and an optically anisotropic body: wherein X represents the following formula (X-i) or (X-ii) wherein * represents a bond: wherein Y1 to Y6 are each one selected from the group consisting of —O—, —S—, —O—C(═O)—, —C(═O)—O— and so on; Yx is one selected from the group consisting of —C(═O)—, —O—C(═O)—, —CH═CH—C(═O)—, —CH 2 — and so on; Yz is one selected from the group consisting of —C(═O)—, —C(═O)—O—, —C(═O)—CH═CH— and so on; G1 and G2 are each a divalent aliphatic group which has 1 to 20 carbon atoms and which may have a substituent; Z1 and Z2 are each an alkenyl group which has 2 to 10 carbon atoms and which may be substituted by a halogen atom; Q1 to Q4 are each a hydrogen atom or an alkyl group which has 1 to 6 carbon atoms and which may have a substituent; A1 to A6 are each a divalent organic group having 1 to 30 carbon atoms; and a and b are each 0 or 1.

  本发明提供了一种具有高左旋螺旋扭曲功的新型可聚合手性化合物（手性剂），以及包含可聚合手性化合物和可聚合液晶化合物的可聚合液晶组合物，液晶聚合物和光学各向异性体。通过以下式（I）表示的左旋螺旋诱导可聚合手性化合物，包括可聚合手性化合物和可聚合液晶化合物的可聚合液晶组合物，液晶聚合物和光学各向异性体，达到了该目的：其中X表示以下式（X-i）或（X-ii），其中*表示键；Y1到Y6各自选自由—O—，—S—，—O—C（═O）—，—C（═O）—O—等组成的群；Yx选自—C（═O）—，—O—C（═O）—，—CH═CH—C（═O）—，—CH2—等组成的群；Yz选自—C（═O）—，—C（═O）—O—，—C（═O）—CH═CH—等组成的群；G1和G2各自是具有1至20个碳原子且可能具有取代基的二价脂肪族基；Z1和Z2各自是具有2至10个碳原子且可能被卤素原子取代的烯基基团；Q1至Q4各自是氢原子或具有1至6个碳原子且可能具有取代基的烷基基团；A1至A6各自是具有1至30个碳原子的二价有机基团；a和b各自为0或1。