trimethyl((2,3,5,6-tetramethylphenyl)ethynyl)silane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trimethyl((2,3,5,6-tetramethylphenyl)ethynyl)silane
• 英文别名: Trimethyl-[2-(2,3,5,6-tetramethylphenyl)ethynyl]silane；trimethyl-[2-(2,3,5,6-tetramethylphenyl)ethynyl]silane
• 化学式: C₁₅H₂₂Si
• 分子量: 230.425
• InChiKey: RFLDQPFZNKCJSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.15
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  trimethyl((2,3,5,6-tetramethylphenyl)ethynyl)silane 在 N-溴代丁二酰亚胺(NBS) 、 Sodium thiosulfate pentahydrate 、 过氧化苯甲酰 作用下， 以 四氯化碳 、 乙醇 、 水 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Synthesis and Structure of a Novel Alkynyl-Containing Disulfide Compound as Cathode Materials for Secondary Lithium Batteries

  摘要：

  A novel alkynyl-containing disulfide compound, 5,8-dihydro-1H,4H-2,3,6,7-tetrathia-anthracen (TMSEDTTA), was synthesized. The structures of the target compound and the intermediates have been identified by H-1 NMR, C-13 NMR, mass spectrometry, Fourier-transform infrared, Raman spectra, x-ray photoelectron spectroscopy, and elemental analysis. In addition, the structure of (Z)-(1,2-dibromo-2-(2,3,5,6-tetrakis(bromomethyl)phenyl)vinyl)trimethylsilane (5) was determined by single x-ray analysis. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]

  DOI：

  10.1080/00397911.2013.789526
• 作为产物：
  描述：

  1,2,4,5-四甲苯 在 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 、 碘 、 silver nitrate 作用下， 以 二乙胺 为溶剂， 反应 1.03h， 生成 trimethyl((2,3,5,6-tetramethylphenyl)ethynyl)silane
  参考文献：
  名称：

  Synthesis and Structure of a Novel Alkynyl-Containing Disulfide Compound as Cathode Materials for Secondary Lithium Batteries

  摘要：

  A novel alkynyl-containing disulfide compound, 5,8-dihydro-1H,4H-2,3,6,7-tetrathia-anthracen (TMSEDTTA), was synthesized. The structures of the target compound and the intermediates have been identified by H-1 NMR, C-13 NMR, mass spectrometry, Fourier-transform infrared, Raman spectra, x-ray photoelectron spectroscopy, and elemental analysis. In addition, the structure of (Z)-(1,2-dibromo-2-(2,3,5,6-tetrakis(bromomethyl)phenyl)vinyl)trimethylsilane (5) was determined by single x-ray analysis. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]

  DOI：

  10.1080/00397911.2013.789526

文献信息

• Synthesis and Structure of a Novel Alkynyl-Containing Disulfide Compound as Cathode Materials for Secondary Lithium Batteries
  作者：Zuxi Jin、Yunguo Lu、Shixi Li、Zaoying Li

  DOI：10.1080/00397911.2013.789526

  日期：2014.1.2

  A novel alkynyl-containing disulfide compound, 5,8-dihydro-1H,4H-2,3,6,7-tetrathia-anthracen (TMSEDTTA), was synthesized. The structures of the target compound and the intermediates have been identified by H-1 NMR, C-13 NMR, mass spectrometry, Fourier-transform infrared, Raman spectra, x-ray photoelectron spectroscopy, and elemental analysis. In addition, the structure of (Z)-(1,2-dibromo-2-(2,3,5,6-tetrakis(bromomethyl)phenyl)vinyl)trimethylsilane (5) was determined by single x-ray analysis. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resource(s): Full experimental and spectral details.]