2,4,7,9-tetramethyl-tricyclo[6.2.0.0^3,6]deca-1(8),2,6-triene-4,9-diol

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 2,4,7,9-tetramethyl-tricyclo[6.2.0.0^3,6]deca-1(8),2,6-triene-4,9-diol
• 英文别名: bBCB-ol；2,4,7,9-Tetramethyltricyclo[6.2.0.03,6]deca-1,3(6),7-triene-4,9-diol；2,4,7,9-tetramethyltricyclo[6.2.0.03,6]deca-1,3(6),7-triene-4,9-diol
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.296
• InChiKey: KVXIPOIXMKNNPF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,4,7,9-tetramethyl-tricyclo[6.2.0.0^3,6]deca-1(8),2,6-triene-4,9-diol 在 盐酸 、 calcium chloride 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成 4,9-dichloro-2,4,7,9-tetramethyl-tricyclo[6.2.0.0^3,6]deca-1(8),2,6-triene
  参考文献：
  名称：

  [EN] NOVEL INITIATORS FOR LIVING CARBOCATIONIC POLYMERIZATION
  [FR] NOUVEAUX INITIATEURS DE POLYMÉRISATION CARBOCATIONIQUE VIVANTE

  摘要：

  在各种实施方式中，本发明涉及用于生产明确定义的端基为电离子聚合物的新型低成本引发剂组合物（通过异丁烯的LC+P）。在其他各种实施方式中，本发明涉及将这些新型组合物用作异丁烯（IB）和其他阳离子聚合单体（例如苯乙烯及其衍生物）的引发剂的方法。在其他实施方式中，本发明涉及由这些新型引发剂组合物及其衍生物（特别是羟基端基PIB和胺端基PIB）形成的结构新的烯丙基（和氯）端基PIB。在其他实施方式中，本发明涉及使用从这些新型引发剂组合物形成的端基为电离子聚合物制得的结构新的聚氨酯、聚脲和聚氨酯脲。

  公开号：

  WO2017127642A1
• 作为产物：
  描述：

  1,2,4,5-四甲苯 在 aluminum (III) chloride 作用下， 以 二硫化碳 、 苯 为溶剂， 反应 80.0h， 生成 2,4,7,9-tetramethyl-tricyclo[6.2.0.0^3,6]deca-1(8),2,6-triene-4,9-diol
  参考文献：
  名称：

  [EN] NOVEL INITIATORS FOR LIVING CARBOCATIONIC POLYMERIZATION
  [FR] NOUVEAUX INITIATEURS DE POLYMÉRISATION CARBOCATIONIQUE VIVANTE

  摘要：

  在各种实施方式中，本发明涉及用于生产明确定义的端基为电离子聚合物的新型低成本引发剂组合物（通过异丁烯的LC+P）。在其他各种实施方式中，本发明涉及将这些新型组合物用作异丁烯（IB）和其他阳离子聚合单体（例如苯乙烯及其衍生物）的引发剂的方法。在其他实施方式中，本发明涉及由这些新型引发剂组合物及其衍生物（特别是羟基端基PIB和胺端基PIB）形成的结构新的烯丙基（和氯）端基PIB。在其他实施方式中，本发明涉及使用从这些新型引发剂组合物形成的端基为电离子聚合物制得的结构新的聚氨酯、聚脲和聚氨酯脲。

  公开号：

  WO2017127642A1

文献信息

• Initiators for living carbocationic polymerization
  申请人：Kennedy Joseph

  公开号：US10472457B2

  公开（公告）日：2019-11-12

  In various embodiments, the present invention is directed to new low cost initiator compositions for use with the production of well-defined telechelic PIBs (by LC+P of isobutylene). In various other embodiments, the present invention is directed to methods for using these novel compositions as initiators for isobutylene (IB) and other cationically polymerizable monomers, such as styrene and its derivatives. In still other embodiments, the present invention is directed to structurally new, allyl (and chlorine) telechelic PIBs formed from these new initiator compositions and their derivatives (in particular, hydroxyl telechelic PIB and amine telechelic PIB). In yet other embodiments, the present invention is directed to structurally new polyurethanes, polyureas, and polyurethane ureas made using telechelic PIBs formed from these new initiator compositions.

  在各种实施方案中，本发明涉及用于生产定义明确的远切 PIB 的新型低成本引发剂组合物（通过异丁烯的 LC+P）。在其他各种实施方案中，本发明涉及将这些新型组合物用作异丁烯 (IB) 和其他阳离子可聚合单体（如苯乙烯及其衍生物）的引发剂的方法。在另一些实施方案中，本发明涉及由这些新型引发剂组合物及其衍生物（特别是羟基引发剂 PIB 和胺引发剂 PIB）形成的结构新颖的烯丙基（和氯）引发剂 PIB。在另一些实施例中，本发明涉及使用由这些新引发剂组合物形成的远志 PIB 制成的结构新的聚氨酯、聚氨酯和聚氨酯脲。
• Centrally functionalizable living cationic polymer or copolymer and methods of synthesizing the same
  申请人：Kennedy Joseph P.

  公开号：US10774185B2

  公开（公告）日：2020-09-15

  In various embodiments, the present invention is directed to a centrally-functionalizable living cationic polymer or copolymer having a centrally-substituted tetraene group having the formula wherein each R is selected from the group consisting of a polymer or a copolymer, such as a polyisobutylene polymer or a poly(isobutylene-b-styrene) copolymer.

  在不同的实施方案中，本发明涉及一种可中心官能化的活阳离子聚合物或共聚物，该聚合物具有中心取代的四烯基，其式为 其中每个 R 选自聚合物或共聚物组成的组，例如聚异丁烯聚合物或聚（异丁烯-苯乙烯）共聚物。
• NOVEL INITIATORS FOR LIVING CARBOCATIONIC POLYMERIZATION
  申请人：KENNEDY Joseph

  公开号：US20190127510A1

  公开（公告）日：2019-05-02

  In various embodiments, the present invention is directed to new low cost initiator compositions for use with the production of well-defined telechelic PIBs (by LC + P of isobutylene). In various other embodiments, the present invention is directed to methods for using these novel compositions as initiators for isobutylene (IB) and other cationically polymerizable monomers, such as styrene and its derivatives. In still other embodiments, the present invention is directed to structurally new, allyl (and chlorine) telechelic PIBs formed from these new initiator compositions and their derivatives (in particular, hydroxyl telechelic PIB and amine telechelic PIB). In yet other embodiments, the present invention is directed to structurally new polyurethanes, polyureas, and polyurethane ureas made using telechelic PIBs formed from these new initiator compositions.
• CENTRALLY FUNCTIONALIZABLE LIVING CATIONIC POLYMER OR COPOLYMER AND METHODS OF SYNTHESIZING THE SAME
  申请人：KENNEDY JOSEPH P.

  公开号：US20190225757A1

  公开（公告）日：2019-07-25

  In various embodiments, the present invention is directed to a centrally-functionalizable living cationic polymer or copolymer having a centrally-substituted tetraene group having the formula wherein each R is selected from the group consisting of a polymer or a copolymer, such as a polyisobutylene polymer or a poly(isobutylene-b-styrene) copolymer.