benzyldimethyl[(E)-1-tetradecenyl]silane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyldimethyl[(E)-1-tetradecenyl]silane
• 英文别名: benzyl-dimethyl-[(E)-tetradec-1-enyl]silane
• 化学式: C₂₃H₄₀Si
• 分子量: 344.656
• InChiKey: YAHYPYSGUVWGJO-DYTRJAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.88
• 重原子数：
  24
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-十四烯 、 1,1-dimethyl-1-silabenzocyclobutene 在 bis(1,5-cyclooctadiene)nickel (0) 、 三环己基膦 作用下， 以 甲苯 为溶剂， 反应 12.0h， 生成 benzyldimethyl[(E)-1-tetradecenyl]silane 、 benzyldimethyl[(Z)-1-tetradecenyl]silane 、 dimethyl(2-methylphenyl)[(E)-1-tetradecenyl]silane
  参考文献：
  名称：

  Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes with Silacyclobutanes:  Facile Access to Vinylsilanes from Alkenes

  摘要：

  Treatment of terminal alkenes with silacyclobutanes under nickel catalysis resulted in silylation of the alkenes and yielded the corresponding vinylsilanes in a highly regio- and stereoselective fashion. The reaction provides a facile access to vinylsilanes starting from trivial terminal alkenes as well as styrenes, 1,3-dienes, and acrylate esters.

  DOI：

  10.1021/ja070938t

文献信息

• Nickel-Catalyzed Regio- and Stereoselective Silylation of Terminal Alkenes with Silacyclobutanes:  Facile Access to Vinylsilanes from Alkenes
  作者：Koji Hirano、Hideki Yorimitsu、Koichiro Oshima

  DOI：10.1021/ja070938t

  日期：2007.5.1

  Treatment of terminal alkenes with silacyclobutanes under nickel catalysis resulted in silylation of the alkenes and yielded the corresponding vinylsilanes in a highly regio- and stereoselective fashion. The reaction provides a facile access to vinylsilanes starting from trivial terminal alkenes as well as styrenes, 1,3-dienes, and acrylate esters.