Layer stack object formation method, including; forming layer of powder material containing calcium phosphate; and delivering hardening liquid to predetermined region of the layer to harden the region,
wherein these steps are repeated,
wherein 1) powder material satisfies A) or B), and hardened product of powder material has hydroxyapatite (HAp) transformation rate of ≦1%: A) organic compound having phosphate or carboxyl group is imparted over surface of calcium phosphate powder, and organic compound imparting amount is ≦10,000 ppm; and B) powder material further contains powder made of organic compound having phosphate or carboxyl group, and organic compound mixing amount to calcium phosphate powder is ≦50% by mass, or
wherein 2) hardening liquid contains at least organic compound having phosphate or carboxyl group, acid value of organic compound is ≧0.45 gKOH/g, and content of organic compound to whole amount of hardening liquid is ≧20% by mass.
层叠物体形成方法,包括:形成含有
磷酸钙粉末材料的层;并将硬化液体输送到层的预定区域以硬化该区域,其中重复执行这些步骤,其中1)粉末材料满足A)或B),并且粉末材料的硬化产物具有≦1%的
羟基磷灰石(HAp)转化率:A)在
磷酸钙粉末表面上赋予含有
磷酸酯或羧基的有机化合物,并且有机化合物赋予量≦10,000 ppm;和B)粉末材料进一步包含由含有
磷酸酯或羧基的有机化合物制成的粉末,且有机化合物混合量对
磷酸钙粉末的质量≦50%,或者2)硬化液体中含有至少含有
磷酸酯或羧基的有机化合物,有机化合物的酸值≧0.45 gKOH / g,且有机化合物含量占整个硬化液体的质量≧20%。