1,2,3,4,5-pentafluoro-6-{2,3,5,6-tetrafluoro-4-[4-(1,1,1,3,3,3-hexafluoro-2-{4-[2,3,5,6-tetrafluoro-4-(2,3,4,5,6-pentafluorophenyl)phenoxy]phenyl}propan-2-yl)phenoxy]phenyl}benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,3,4,5-pentafluoro-6-{2,3,5,6-tetrafluoro-4-[4-(1,1,1,3,3,3-hexafluoro-2-{4-[2,3,5,6-tetrafluoro-4-(2,3,4,5,6-pentafluorophenyl)phenoxy]phenyl}propan-2-yl)phenoxy]phenyl}benzene
• 英文别名: 1,2,3,4,5-Pentafluoro-6-[2,3,5,6-tetrafluoro-4-[4-[1,1,1,3,3,3-hexafluoro-2-[4-[2,3,5,6-tetrafluoro-4-(2,3,4,5,6-pentafluorophenyl)phenoxy]phenyl]propan-2-yl]phenoxy]phenyl]benzene
• 化学式: C₃₉H₈F₂₄O₂
• 分子量: 964.453
• InChiKey: HIJXFFMOUSNQEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14
• 重原子数：
  65
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  2-(2-{2-[1,1-difluoro-2-(2,3,5,6-tetrafluoro-4-vinyl-phenoxy)-ethoxy]-1,1,2,2-tetrafluoro-ethoxy}-1,1,2,2-tetrafluoro-ethoxy)-2,2-difluoro-ethanol 、 1,2,3,4,5-pentafluoro-6-{2,3,5,6-tetrafluoro-4-[4-(1,1,1,3,3,3-hexafluoro-2-{4-[2,3,5,6-tetrafluoro-4-(2,3,4,5,6-pentafluorophenyl)phenoxy]phenyl}propan-2-yl)phenoxy]phenyl}benzene 在 calcium hydride 、 cesium fluoride 作用下， 以 N,N-二甲基乙酰胺 为溶剂， 反应 48.0h， 以86%的产率得到
  参考文献：
  名称：

  Blend prepared by mixing a prepolymer and a vinyl monomer and a polymer sheet obtained therefrom

  摘要：

  本文披露了一种混合物，由预聚物和乙烯单体混合制备而成。其中，预聚物通过第一化合物（化学式为Ar-H）和第二化合物（含有芳香基团）之间的缩合反应制备而成。其中Ar在一端包含可交联的基团(a)，在另一端包含选自以下基团组合的基团(b)：—O—、—S—、—COO—、—CO—、—COS—、—SO2—和—NH—，以及选自以下重复单元组合的一个或两个重复单元(c)：其中A为碳或氮，X为氢或卤素。此外，本文还披露了一种由该混合物交联而成的聚合物片。

  公开号：

  US09864104B2
• 作为产物：
  描述：

  六氟双酚 A 、 十氟联苯 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 以85%的产率得到1,2,3,4,5-pentafluoro-6-{2,3,5,6-tetrafluoro-4-[4-(1,1,1,3,3,3-hexafluoro-2-{4-[2,3,5,6-tetrafluoro-4-(2,3,4,5,6-pentafluorophenyl)phenoxy]phenyl}propan-2-yl)phenoxy]phenyl}benzene
  参考文献：
  名称：

  由含双（五氟苯基）和双（九氟联苯）的新型单体合成具有二苯并二恶英和螺双茚满单元的氟化聚（亚芳基醚）

  摘要：

  基于六氟苯或十氟联苯以及对位和间位连接的二羟基取代化合物或四氟苯的新系列含4,4'-双（五氟苯基）和4,4'-双（九氟苯基）的单体和1合成了1,1,1,3,3,3-六氟丙烷基二羟基取代的化合物。通过合成的核心氟化单体与5,5'，6,6'-四羟基-3,3,3的相互作用，成功获得了具有全氟芳族单元以及刚性二苯并二恶英和螺双双茚满片段的氟化聚亚芳基醚。 ′，3′-四甲基-1，1′-螺双茚满。制备的单体和聚合物的化学结构使用1 H，13 C，19确定F NMR和FTIR光谱技术。所有获得的聚合物完全溶于氯仿，四氢呋喃，二甲基甲酰胺和二甲基亚砜。衍生自含4,4'-双（九氟苯基）单体的聚合物具有在47,000-88,300范围内的较高平均分子量（M w），并能够形成坚固的溶剂铸膜。在所有氟化聚合物中，均在空气中（高达350°C）具有良好的热稳定性。Brunauer-Emmett-Teller比表面积和

  DOI：

  10.1016/j.jfluchem.2017.01.008

文献信息

• Coating composition comprising compound, and organic light emitting device comprising same
  申请人：LG Chem, Ltd.

  公开号：US11342507B2

  公开（公告）日：2022-05-24

  The present specification relates to a coating composition comprising a compound, and an organic light emitting device comprising the same.

  本规范涉及一种包括化合物的涂层组合物，以及包含该涂层组合物的有机发光装置。
• COMPOUND CONTAINING CROSSLINKABLE MOIETIES, PREPOLYMER, BLEND AND POLYMER SHEET OBTAINED THEREFROM, AND WAVEGUIDE FOR OPTICAL INTERCONNECTION
  申请人：PARK Seung Koo

  公开号：US20100172623A1

  公开（公告）日：2010-07-08

  A compound containing a crosslinkable moiety, a curable prepolymer, a blend, and a polymer sheet obtained therefrom, and an optical waveguide for optical interconnection. The compound is represented by the formula below: Ar—H wherein Ar includes a crosslinkable moiety at one end, a moiety selected from the group consisting of —O—, —S—, —COO—, —CO—, —COS—, —SO 2 —, and —NH—, and one or two repeating units selected from the group consisting of the following repeating units: wherein A in the repeating unit is carbon or nitrogen, and X is hydrogen or halogen. At least one of the core and the cladding in the optical waveguide includes the polymer sheet.
• Novel Sulfonic-Acid-Group-Containing Segmented Block Copolymer, Application Thereof, and Method of Manufacturing Novel Block Copolymer
  申请人：Kitamura Kouta

  公开号：US20110065021A1

  公开（公告）日：2011-03-17

  [Object] To provide a proton exchange membrane for a fuel cell having excellent proton conductivity, lower property of swelling with hot water, and excellent durability, as well as a block copolymer forming the proton exchange membrane, and a composition, a molded product, a fuel cell proton exchange membrane electrode assembly, and a fuel cell. [Solving Means] (1) A block copolymer having a hydrophilic segment and a hydrophobic segment and having a structure expressed by Chemical Formula 1 below (where X represents H or a univalent cation, Y represents sulfonyl group or carbonyl group, each of Z and z′ independently represents any of O and S atoms, W represents one or more group selected from the group consisting of direct bond between benzenes, sulfone group and carbonyl group, each of Ar 1 and Ar 2 independently represents divalent aromatic group, and each of n and m independently represents an integer from 2 to 100), and a molded product, a composition, and a proton exchange membrane, as well as a fuel cell including the proton exchange membrane.
• Compound containing crosslinkable moieties, prepolymer, blend and polymer sheet obtained therefrom, and waveguide for optical interconnection
  申请人：Electronics and Telecommunications Research Institute

  公开号：US20140219625A1

  公开（公告）日：2014-08-07

  An optical waveguide for optical interconnection including a polymer sheet comprising a crosslinked product of a prepolymer, the prepolymer prepared by condensation reaction between a first compound represented by the formula Ar—H, where Ar comprises (a) a crosslinkable moiety at one end, (b) a moiety selected from the group consisting of —O—, —S—, —COO—, —CO—, —COS—, —SO 2 —, and —NH—, and (c) one or two repeating units selected from the group consisting of: where A is carbon or nitrogen, and X is hydrogen or halogen; and a second compound consisting of an aromatic moiety.
• ANION EXCHANGE RESIN, ELECTROLYTE MEMBRANE FOR FUEL CELL, BINDER FOR FORMING ELECTRODE CATALYST LAYER, BATTERY ELECTRODE CATALYST LAYER AND FUEL CELL
  申请人：TAKAHATA PRECISION JAPAN CO., LTD.

  公开号：US20170087545A1

  公开（公告）日：2017-03-30

  An anion exchange resin having a hydrophobic unit with divalent hydrophobic groups bonded to each other via an ether bond, the divalent hydrophobic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group, carbon-carbon bond or the like; and a hydrophilic unit having divalent hydrophilic groups bonded to each other via carbon-carbon bond, the divalent hydrophilic groups being composed of one aromatic ring, or being composed of a plurality of aromatic rings which are bonded to each other via a divalent hydrocarbon group or carbon-carbon bond, the aromatic ring or at least one of the aromatic rings having an anion exchange group are bonded via carbon-carbon bond.