sodium 6-hydroxyhexyl-1-sulfonate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: sodium 6-hydroxyhexyl-1-sulfonate
• 英文别名: Sodium;6-hydroxyhexane-1-sulfonate；sodium;6-hydroxyhexane-1-sulfonate
• 化学式: C₆H₁₃O₄S*Na
• 分子量: 204.223
• InChiKey: PEGMSBLSDOBIHO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.91
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  85.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  6-氯-1-己醇 在 sodium sulfite 作用下， 以 水 为溶剂， 反应 12.0h， 以80%的产率得到sodium 6-hydroxyhexyl-1-sulfonate
  参考文献：
  名称：

  Catalytic Conversions in Water. Part 21: Mechanistic Investigations on the Palladium-Catalysed Aerobic Oxidation of Alcohols in Water†

  摘要：

  Water-soluble complexes of palladium(II) with phenanthroline-derivatives are stable, recyclable catalysts for the selective aerobic oxidation of a wide range of alcohols to aldehydes, ketones, and carboxylic acids in a biphasic liquid-liquid system. The active catalyst is a dihydroxy-bridged palladium dimer. Kinetics of the reaction, ligand and anion effects are discussed.

  DOI：

  10.1002/1615-4169(200206)344:3/4<355::aid-adsc355>3.0.co;2-s

文献信息

• Catalytic Conversions in Water. Part 21: Mechanistic Investigations on the Palladium-Catalysed Aerobic Oxidation of Alcohols in Water†
  作者：Gerd-Jan ten??Brink、Isabel??W.??C.??E. Arends、Roger??A. Sheldon

  DOI：10.1002/1615-4169(200206)344:3/4<355::aid-adsc355>3.0.co;2-s

  日期：2002.6

  Water-soluble complexes of palladium(II) with phenanthroline-derivatives are stable, recyclable catalysts for the selective aerobic oxidation of a wide range of alcohols to aldehydes, ketones, and carboxylic acids in a biphasic liquid-liquid system. The active catalyst is a dihydroxy-bridged palladium dimer. Kinetics of the reaction, ligand and anion effects are discussed.