4-methoxy-N-methyl-N-(3-tolyl)aniline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-methoxy-N-methyl-N-(3-tolyl)aniline
• 英文别名: N-(4-methoxyphenyl)-N,3-dimethylaniline
• 化学式: C₁₅H₁₇NO
• 分子量: 227.306
• InChiKey: RIJYGFQSRAQUCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (4-甲氧基苯基)-二甲胺 、 2-氯甲苯 在 potassium tert-butylate 、 二甲基亚砜 作用下， 以 1,4-二氧六环 为溶剂， 反应 12.0h， 以80%的产率得到4-methoxy-N-methyl-N-(3-tolyl)aniline
  参考文献：
  名称：

  叔胺与芳基卤化物之间无过渡金属的叔丁醇钾/二甲基亚砜介导的胺化作用

  摘要：

  摘要 据报道，叔胺和卤代芳基之间没有过渡金属的C–N键形成反应。在最佳条件下，各种芳族和脂肪族叔胺与芳基卤化物（包括碘化物，溴化物和氯化物）反应，以高收率或高收率得到单胺化产物N，N-二烷基苯胺和N-烷基-N-芳基苯胺。 。根据实验结果，认为该反应通过衍生自芳基卤化物的芳烃中间体发生。 据报道，叔胺和卤代芳基之间没有过渡金属的C–N键形成反应。在最佳条件下，各种芳族和脂肪族叔胺与芳基卤化物（包括碘化物，溴化物和氯化物）反应，以高收率或高收率得到单胺化产物N，N-二烷基苯胺和N-烷基-N-芳基苯胺。 。根据实验结果，认为该反应通过衍生自芳基卤化物的芳烃中间体发生。

  DOI：

  10.1055/s-0034-1379367

文献信息

• Composition For Charge-Transporting Film And Ion Compound, Charge-Transporting Film And Organic Electroluminescent Device Using Same, And Method For Manufacturing Organic Electroluminescent Device And Method For Producing Charge-Transporting Film
  申请人：Iida Koichiro

  公开号：US20070207341A1

  公开（公告）日：2007-09-06

  An excellent composition for a charge-transport film, which can be used to produce an organic electroluminescence device having excellent heat-resistant property, high hole injection/transport capacity and capable of functioning at a low voltage, is proposed. It comprises at least an ionic compound expressed by the following general formula (1) or the like and a charge-transporting compound, (R 11 -A 1 + -R 12 ) n 1 Z 1 n 1 − ( 1 ) wherein in general formula (1): R 11 represents an organic group bound to A 1 via a carbon atom; R 12 represents an arbitrary group; R 11 and R 12 may combine together to form a ring; A 1 represents an element belonging to the third and subsequent periods and group 17 of the long form periodic table; Z 11 n1− represents a counter anion; and n 1 represents an ionic valency of the counter anion.
• COMPOSITION FOR CHARGE-TRANSPORTING FILM AND ION COMPOUND, CHARGE-TRANSPORTING FILM AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME, AND METHOD FOR MANUFACTURING ORGANIC ELECTROLUMINESCENT DEVICE AND METHOD FOR PRODUCING CHARGE-TRANSPORTING FILM
  申请人：IIDA Koichiro

  公开号：US20110001134A1

  公开（公告）日：2011-01-06

  An excellent composition for a charge-transport film, which can be used to produce an organic electroluminescence device having excellent heat-resistant property, high hole injection/transport capacity and capable of functioning at a low voltage, is proposed. It comprises at least an ionic compound expressed by the following general formula (1) or the like and a charge-transporting compound, (R 11 -A 1 + -R 12 ) n 1 Z 1 n 1 − (1) wherein in general formula (1): R 11 represents an organic group bound to A 1 via a carbon atom; R 12 represents an arbitrary group; R 11 and R 12 may combine together to form a ring; A 1 represents an element belonging to the third and subsequent periods and group 17 of the long form periodic table; Z 1 n1− represents a counter anion; and n 1 represents an ionic valency of the counter anion.
• US7879461B2
  申请人：——

  公开号：US7879461B2

  公开（公告）日：2011-02-01
• US8252432B2
  申请人：——

  公开号：US8252432B2

  公开（公告）日：2012-08-28
• Transition-Metal-Free, Potassium tert-Butoxide/Dimethyl Sulfoxide Mediated Amination between Tertiary Amines and Aryl Halides
  作者：Jian-Mei Lu、Pei Huang、Bang-Yue He、Hui-Min Wang

  DOI：10.1055/s-0034-1379367

  日期：——

  C–N bond-formation reaction between tertiary amines and aryl halides is reported. Under the optimal conditions, various aromatic and aliphatic tertiary amines react with aryl halides, including iodides, bromides, and chlorides, to give mono-aminated products, N,N-dialkylanilines and N-alkyl-N-arylanilines, in good to high yields. Based on the experimental results, the reaction is believed to occur

  摘要 据报道，叔胺和卤代芳基之间没有过渡金属的C–N键形成反应。在最佳条件下，各种芳族和脂肪族叔胺与芳基卤化物（包括碘化物，溴化物和氯化物）反应，以高收率或高收率得到单胺化产物N，N-二烷基苯胺和N-烷基-N-芳基苯胺。 。根据实验结果，认为该反应通过衍生自芳基卤化物的芳烃中间体发生。 据报道，叔胺和卤代芳基之间没有过渡金属的C–N键形成反应。在最佳条件下，各种芳族和脂肪族叔胺与芳基卤化物（包括碘化物，溴化物和氯化物）反应，以高收率或高收率得到单胺化产物N，N-二烷基苯胺和N-烷基-N-芳基苯胺。 。根据实验结果，认为该反应通过衍生自芳基卤化物的芳烃中间体发生。