4-methoxy-N-methyl-N-(3-tolyl)aniline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-methoxy-N-methyl-N-(3-tolyl)aniline
• 英文别名: N-(4-methoxyphenyl)-N,3-dimethylaniline
• 化学式: C₁₅H₁₇NO
• 分子量: 227.306
• InChiKey: RIJYGFQSRAQUCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (4-甲氧基苯基)-二甲胺 、 2-氯甲苯 在 potassium tert-butylate 、 二甲基亚砜 作用下， 以 1,4-二氧六环 为溶剂， 反应 12.0h， 以80%的产率得到4-methoxy-N-methyl-N-(3-tolyl)aniline
  参考文献：
  名称：

  叔胺与芳基卤化物之间无过渡金属的叔丁醇钾/二甲基亚砜介导的胺化作用

  摘要：

  摘要 据报道，叔胺和卤代芳基之间没有过渡金属的C–N键形成反应。在最佳条件下，各种芳族和脂肪族叔胺与芳基卤化物（包括碘化物，溴化物和氯化物）反应，以高收率或高收率得到单胺化产物N，N-二烷基苯胺和N-烷基-N-芳基苯胺。 。根据实验结果，认为该反应通过衍生自芳基卤化物的芳烃中间体发生。 据报道，叔胺和卤代芳基之间没有过渡金属的C–N键形成反应。在最佳条件下，各种芳族和脂肪族叔胺与芳基卤化物（包括碘化物，溴化物和氯化物）反应，以高收率或高收率得到单胺化产物N，N-二烷基苯胺和N-烷基-N-芳基苯胺。 。根据实验结果，认为该反应通过衍生自芳基卤化物的芳烃中间体发生。

  DOI：

  10.1055/s-0034-1379367

文献信息

• Composition For Charge-Transporting Film And Ion Compound, Charge-Transporting Film And Organic Electroluminescent Device Using Same, And Method For Manufacturing Organic Electroluminescent Device And Method For Producing Charge-Transporting Film
  申请人：Iida Koichiro

  公开号：US20070207341A1

  公开（公告）日：2007-09-06

  An excellent composition for a charge-transport film, which can be used to produce an organic electroluminescence device having excellent heat-resistant property, high hole injection/transport capacity and capable of functioning at a low voltage, is proposed. It comprises at least an ionic compound expressed by the following general formula (1) or the like and a charge-transporting compound, (R 11 -A 1 + -R 12 ) n 1 Z 1 n 1 − ( 1 ) wherein in general formula (1): R 11 represents an organic group bound to A 1 via a carbon atom; R 12 represents an arbitrary group; R 11 and R 12 may combine together to form a ring; A 1 represents an element belonging to the third and subsequent periods and group 17 of the long form periodic table; Z 11 n1− represents a counter anion; and n 1 represents an ionic valency of the counter anion.
• COMPOSITION FOR CHARGE-TRANSPORTING FILM AND ION COMPOUND, CHARGE-TRANSPORTING FILM AND ORGANIC ELECTROLUMINESCENT DEVICE USING SAME, AND METHOD FOR MANUFACTURING ORGANIC ELECTROLUMINESCENT DEVICE AND METHOD FOR PRODUCING CHARGE-TRANSPORTING FILM
  申请人：IIDA Koichiro

  公开号：US20110001134A1

  公开（公告）日：2011-01-06

  An excellent composition for a charge-transport film, which can be used to produce an organic electroluminescence device having excellent heat-resistant property, high hole injection/transport capacity and capable of functioning at a low voltage, is proposed. It comprises at least an ionic compound expressed by the following general formula (1) or the like and a charge-transporting compound, (R 11 -A 1 + -R 12 ) n 1 Z 1 n 1 − (1) wherein in general formula (1): R 11 represents an organic group bound to A 1 via a carbon atom; R 12 represents an arbitrary group; R 11 and R 12 may combine together to form a ring; A 1 represents an element belonging to the third and subsequent periods and group 17 of the long form periodic table; Z 1 n1− represents a counter anion; and n 1 represents an ionic valency of the counter anion.
• US7879461B2
  申请人：——

  公开号：US7879461B2

  公开（公告）日：2011-02-01
• US8252432B2
  申请人：——

  公开号：US8252432B2

  公开（公告）日：2012-08-28