7-benzoperyleneacetaldehyde diethyl acetal

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 7-benzoperyleneacetaldehyde diethyl acetal
• 英文别名: 7-(2,2-diethoxyethyl)benzo[ghi]perylene；15-(2,2-Diethoxyethyl)hexacyclo[12.8.0.02,11.03,8.04,21.017,22]docosa-1(14),2(11),3(8),4,6,9,12,15,17(22),18,20-undecaene
• 化学式: C₂₈H₂₄O₂
• 分子量: 392.497
• InChiKey: VFLFOODSVUMPRX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  7-benzoperyleneacetaldehyde diethyl acetal 在 硫酸 作用下， 以 甲醇 为溶剂， 反应 0.5h， 以82%的产率得到晕苯
  参考文献：
  名称：

  Gram Scale Synthesis of Benzo[ghi]perylene and Coronene

  摘要：

  DOI：

  10.1021/jo951555t
• 作为产物：
  描述：

  苯并[ghi]苝 、 2-溴-1,1-二乙氧基乙烷 在 碘 、 sodium 作用下， 生成 7-benzoperyleneacetaldehyde diethyl acetal 、 5-benzoperyleneacetaldehyde diethyl acetal
  参考文献：
  名称：

  Gram Scale Synthesis of Benzo[ghi]perylene and Coronene

  摘要：

  DOI：

  10.1021/jo951555t

文献信息

• ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US20190031586A1

  公开（公告）日：2019-01-31

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  提供一种有机化合物，通过使用该有机化合物形成的三维有机结构、分离筛和具有该有机结构的光学层，以及具有光学层作为光学放大层的光学器件。该有机结构包括通过非共价键自组装的多个有机分子。每个单元有机分子具有芳香环，第一对取代基连接到芳香环的可取代位置的相邻位置，第二对取代基连接到芳香环的剩余可取代位置的相邻位置。单元有机分子通过范德华力相互作用、伦敦分散相互作用或氢键作用于第一和第二对取代基之间的π-π相互作用而自组装。
• Organic Silane Compound, Method of Producing the Same, and Organic Thin Film Using the Same
  申请人：Imada Hiroshi

  公开号：US20080312463A1

  公开（公告）日：2008-12-18

  The present invention provides a highly ordered, crystallized organic thin film superior in electroconductive properties that is resistant to exfoliation, a compound for preparation of the thin film, and a method of producing the same. An organic silane compound, characterized in that a molecule represented by General Formula (I) is substituted with a silyl group. A method of producing the organic silane compound, comprising halogenating a molecule (I) and allowing it to react with a silane derivative. An organic thin film, wherein the organic silane compound molecule is oriented with its silyl group located in the substrate side and the molecule (I) region in the film surface side. (wherein, x1 and x2 are integers satisfying 1≦x1, 1≦x2, and 2≦x1+x2≦8; each of y1 and z1 is independently an integer of 2 to 8; each of y2 and z2 is independently an integer of 0 to 8; and the skeleton may be substituted with a hydrophobic group).

  本发明提供了一种高度有序、结晶的有机薄膜，具有优越的导电性能，能够抵抗剥离，一种用于制备该薄膜的化合物，以及生产该薄膜的方法。一种有机硅烷化合物，其特征在于，由通用式（I）表示的分子被硅烷基取代。生产该有机硅烷化合物的方法，包括卤代化分子（I）并使其与硅烷衍生物发生反应。一种有机薄膜，其中有机硅烷化合物分子被定向，其硅烷基位于基底侧，而分子（I）区域位于薄膜表面侧。（其中，x1和x2是满足1≦x1，1≦x2，且2≦x1+x2≦8的整数；每个y1和z1独立地为2到8的整数；每个y2和z2独立地为0到8的整数；骨架可能被疏水基取代）。
• Organic compound, three-dimensional organic framework formed by using organic compound, separation sieve and optical layer, which comprise organic framework, and optical device comprising optical layer as optical amplification layer
  申请人：INDUSTRY-UNIVERSITY COOPERATION FOUNDATION HANYANG UNIVERSITY

  公开号：US11066351B2

  公开（公告）日：2021-07-20

  An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

  本文提供了一种有机化合物、利用该有机化合物形成的三维有机结构、具有该有机结构的分离筛和光学层，以及具有该光学层作为光放大层的光学设备。有机结构包括多个通过非共价键自组装的有机分子。每个单元有机分子都有一个芳香环，第一对取代基连接到芳香环可取代位置的紧邻位置，第二对取代基连接到芳香环其余可取代位置的紧邻位置。通过第一对和第二对取代基之间的范德华相互作用、伦敦色散相互作用或氢键作用，以及芳香环之间的π-π相互作用，单元有机分子得以自组装。
• Gram Scale Synthesis of Benzo[<i>ghi</i>]perylene and Coronene
  作者：Joost T. M. van Dijk、Astrid Hartwijk、Annemarie C. Bleeker、Johan Lugtenburg、Jan Cornelisse

  DOI：10.1021/jo951555t

  日期：1996.1.1