o-sulfophenylarsonic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-sulfophenylarsonic acid
• 英文别名: 2-arsono-benzenesulfonic acid；o-HO3S-C6H4AsO3H2；2-Sulfo-phenylarsonsaeure；2-Arsono-benzolsulfonsaeure；2-Arsonobenzenesulfonic acid；2-arsonobenzenesulfonic acid
• 化学式: C₆H₇AsO₆S
• 分子量: 282.106
• InChiKey: HNQQBBNICDIKDU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.51
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  120
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  copper(II) acetate monohydrate 、 o-sulfophenylarsonic acid 以 水 为溶剂， 以47%的产率得到Cu2.5(o-sulfophenylarsonic acid(-3H))(OH)2
  参考文献：
  名称：

  Novel copper(II) sulfonate–arsonates with discrete cluster, 1D chain and layered structures

  摘要：

  Hydrothermal reactions of copper(II) salts with o-sulfophenylarsonic acid (o-HO3S-C6H4-AsO3H2, H3L) led to a layered compound, Cu-2.5(L)(OH)(2) (1). Introduction of the auxiliary chelating ligands such as 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) and 2,2':6',2 ''-terpyridine (terpy) led to three new copper(II) sulfonate-arsonates with lower dimensional structures, namely, mononuclear Cu(HL)(bipy)(H2O)center dot 2H(2)O (2), dinuclear [Cu(HL)(phen)](2)center dot 4H(2)O (3) and one-dimensional Cu(HL)(terpy)center dot 2H(2)O (4). Magnetic property measurements indicate that 1 exhibits ordinary antiferromagnetic feature, without the geometric spin frustration as expected. 2 shows a typical paramagnetic behavior. There exists antiferromagnetic interactions between the magnetic centers in dimeric 3. 4 displays an antiferromagnetic magnetic exchange interaction propagated via O-S-O bridges. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2010.10.017
• 作为产物：
  描述：

  o-iodophenylarsonic acid 在 水 、 sodium sulfite 作用下， 生成 o-sulfophenylarsonic acid
  参考文献：
  名称：

  The Preparation of Phenylarsenoxides in Relation to a Projected Study of their Chemotherapeutic Activity. I. Monosubstituted Derivatives

  摘要：

  DOI：

  10.1021/ja01858a049

文献信息

• A Series of New Manganese(II) Sulfonate-Arsonates with 2D Layer, 1D Chain, and 0D Clusters Structures
  作者：Fei-Yan Yi、Qi-Pu Lin、Tian-Hua Zhou、Jiang-Gao Mao

  DOI：10.1021/ic100103k

  日期：2010.4.5

  5H2O (2), Mn(HL)(phen)2(H2O)·2H2O (3), [Mn(HL)(bipy)2][Mn(H2L)(bipy)2](ClO4)·3H2O (4), [Mn(HL)(phen)][Mn(HL)(phen)(H2O)] (5), [Mn2(HL)(phen)4(H2O)](ClO4)2·4H2O (6), [Mn2(HL)(phen)4(H2O)](ClO4)2·H2O (7), Mn2(HL)2(bipy)3(H2O)·H2O (8), [Mn(HL)(terpy)]2 (9), Mn7(OH)2(L)4(phen)8·10H2O·phen (10), and Mn(HL)(bipy)(H2O)·2H2O (11) have been obtained. 2−4 are mononuclear (4 contains two different mononuclear cluster

  锰（II）盐与邻磺基苯磺酸（o - HO 3 S-C 6 H 4 -AsO 3 H 2，H 3 L）的水热反应得到Mn 3（L）2（H 2 O）3 ·H 2 O（1）具有分层结构。当使用1,10-菲咯啉（phen），2,2'-联吡啶（bipy）和2,2'：6'，2''-吡啶（terpy）作为辅助螯合配体时，一系列混合配体Mn（HL）（phen）2 ] 2 ·8.5H的低维结构的磺酸锰（II）-磺酸盐2 O（2），Mn（HL）（phen）2（H 2 O）·2H 2 O（3），[Mn（HL）（bipy）2 ] [Mn（H 2 L）（bipy）2 ]（ ClO 4）·3H 2 O（4），[Mn（HL）（phen）] [Mn（HL）（phen）（H 2 O）]（5），[Mn 2（HL）（phen）4（H）2 O）]（ClO 4）2 ·4H 2 O（6），[Mn 2（HL）（phen）4（H 2 O）]（ClO
• New thorium(<scp>iv</scp>)–arsonates with a [Th₈O₁₃]⁶⁺ octanuclear core
  作者：Xiang-Ying Qian、Tian-Hua Zhou、Jiang-Gao Mao

  DOI：10.1039/c5dt01370d

  日期：——

  Three new Th(iv) organoarsonates have been hydrothermally synthesized. Their structures display 0D, 1D and 2D architectures based on novel [Th₈O₁₃]⁶⁺ clusters decorated by organoarsonate ligands.

  我们通过水热法合成了三种新的 Th(iv) 有机胂酸盐。它们的结构以有机砷酸盐配体装饰的新型 [Th8O13]6+ 簇为基础，呈现出 0D、1D 和 2D 结构。
• CCLXIV.—Aromatic arsenic compounds containing sulphur groups attached to the nucleus. Part I. Sulphonic acids and their derivatives
  作者：Harry James Barber

  DOI：10.1039/jr9300002047

  日期：——
• Novel copper(II) sulfonate–arsonates with discrete cluster, 1D chain and layered structures
  作者：Fei-Yan Yi、Qi-Pu Lin、Tian-Hua Zhou、Jiang-Gao Mao

  DOI：10.1016/j.molstruc.2010.10.017

  日期：2010.12

  Hydrothermal reactions of copper(II) salts with o-sulfophenylarsonic acid (o-HO3S-C6H4-AsO3H2, H3L) led to a layered compound, Cu-2.5(L)(OH)(2) (1). Introduction of the auxiliary chelating ligands such as 2,2'-bipyridine (bipy) or 1,10-phenanthroline (phen) and 2,2':6',2 ''-terpyridine (terpy) led to three new copper(II) sulfonate-arsonates with lower dimensional structures, namely, mononuclear Cu(HL)(bipy)(H2O)center dot 2H(2)O (2), dinuclear [Cu(HL)(phen)](2)center dot 4H(2)O (3) and one-dimensional Cu(HL)(terpy)center dot 2H(2)O (4). Magnetic property measurements indicate that 1 exhibits ordinary antiferromagnetic feature, without the geometric spin frustration as expected. 2 shows a typical paramagnetic behavior. There exists antiferromagnetic interactions between the magnetic centers in dimeric 3. 4 displays an antiferromagnetic magnetic exchange interaction propagated via O-S-O bridges. (C) 2010 Elsevier B.V. All rights reserved.
• The Preparation of Phenylarsenoxides in Relation to a Projected Study of their Chemotherapeutic Activity. I. Monosubstituted Derivatives
  作者：G. O. Doak、Harry Eagle、H. G. Steinman

  DOI：10.1021/ja01858a049

  日期：1940.1