N,N,N-Tris[4-{2-(4-{5-[4-(tert-butyl)phenyl]-1,3,4-oxadiazol-2-yl}phenyl)-1-ethenyl}phenyl]amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-Tris[4-{2-(4-{5-[4-(tert-butyl)phenyl]-1,3,4-oxadiazol-2-yl}phenyl)-1-ethenyl}phenyl]amine
• 英文别名: 4-[(E)-2-[4-[5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl]phenyl]ethenyl]-N,N-bis[4-[(E)-2-[4-[5-(4-tert-butylphenyl)-1,3,4-oxadiazol-2-yl]phenyl]ethenyl]phenyl]aniline
• 化学式: C₇₈H₆₉N₇O₃
• 分子量: 1152.45
• InChiKey: HVLZFRZLTWVJMO-DZURWXOBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.4
• 重原子数：
  88
• 可旋转键数：
  18
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  120
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  对甲苯甲酰肼 在 Pd catalyst sodium hydroxide 、 N-溴代丁二酰亚胺(NBS) 、 三氯氧磷 、 过氧化苯甲酰 作用下， 以 四氢呋喃 、 四氯化碳 、 苯 为溶剂， 生成 N,N,N-Tris[4-{2-(4-{5-[4-(tert-butyl)phenyl]-1,3,4-oxadiazol-2-yl}phenyl)-1-ethenyl}phenyl]amine
  参考文献：
  名称：

  Cooperative Enhancement of Two-Photon Absorption in Multi-branched Structures

  摘要：

  Recent reports of molecular structures with considerably enhanced two-photon absorption cross-section have generated considerable interest in this phenomenon from both fundamental and applications perspectives. In this letter, we report cooperative enhancement of two-photon absorption in multi-branched structures which may lead to new design criteria for development of highly efficient two-photon materials. The multi-branched structures were synthesized using coupling of two and three two-photon active asymmetric donor-acceptor chromophores linked together by a common amine group. The two-photon cross-sections measured both with nanosecond and femtosecond pulses show that the value for the trimer is more than six times larger than that for the monomer, and not just three times larger as expected from the number density increase.

  DOI：

  10.1021/jp992846z

文献信息

• Cooperative Enhancement of Two-Photon Absorption in Multi-branched Structures
  作者：Sung-Jae Chung、Kyoung-Soo Kim、Tzu-Chau Lin、Guang S. He、Jacek Swiatkiewicz、Paras N. Prasad

  DOI：10.1021/jp992846z

  日期：1999.12.1

  Recent reports of molecular structures with considerably enhanced two-photon absorption cross-section have generated considerable interest in this phenomenon from both fundamental and applications perspectives. In this letter, we report cooperative enhancement of two-photon absorption in multi-branched structures which may lead to new design criteria for development of highly efficient two-photon materials. The multi-branched structures were synthesized using coupling of two and three two-photon active asymmetric donor-acceptor chromophores linked together by a common amine group. The two-photon cross-sections measured both with nanosecond and femtosecond pulses show that the value for the trimer is more than six times larger than that for the monomer, and not just three times larger as expected from the number density increase.