terephthalic acid bis(2-oxo-[1,3]dioxolan-4-ylmethyl)ester

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: terephthalic acid bis(2-oxo-[1,3]dioxolan-4-ylmethyl)ester
• 英文别名: Bis[(2-oxo-1,3-dioxolan-4-yl)methyl] benzene-1,4-dicarboxylate；bis[(2-oxo-1,3-dioxolan-4-yl)methyl] benzene-1,4-dicarboxylate
• 化学式: C₁₆H₁₄O₁₀
• 分子量: 366.281
• InChiKey: FYJDBOHPQGLISO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  124
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  羟甲基二氧杂戊环酮 、 对苯二甲酰氯 在 吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 4.5h， 以30.61%的产率得到terephthalic acid bis(2-oxo-[1,3]dioxolan-4-ylmethyl)ester
  参考文献：
  名称：

  The investigation of thermal pyrolysis of glycerol carbonate derivatives by TG–FTIR

  摘要：

  Three new GC derivatives, carbonic acid bis-(2-oxo-[1,3]dioxolan-4-ylmethyl) ester (CARE), succinic acid bis-(2-oxo-[1,3]dioxolan-4-ylmethyl) ester (SABE) and terephthalic acid bis-(2-oxo-[1,3]dioxolan-4-ylmethyl) ester (TABE), were designed and synthesized. We investigated the thermal stability and the thermal pyrolysis of three compounds by TG-FTIR, and the bond dissociation energy was calculated to further demonstrate the decomposition process. The results showed that the three GC derivatives had one, two, three weight loss stages, respectively. Their initial decomposition temperature was as high as 200 degrees C, which means that the compounds have good thermal stability. 5% weight loss temperature was increased in the order of TABE> SABE > CABE. In thermal pyrolysis process, the C-C, C-O bonds of cyclic carbonate fractured preferentially, and then the C-O bonds nearby cyclic carbonate of SABE and TABE continued to fracture to produce linear ester in the form of fragment. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.tca.2015.12.002

文献信息

• ５員環環状カーボネート化合物の製造方法
  申请人：大日精化工業株式会社

  公开号：JP2016190799A

  公开（公告）日：2016-11-10

  【課題】エポキシ化合物と二酸化炭素を触媒存在下で反応させる５員環環状カーボネート製造において、高圧用の反応装置を不要とし、未反応ガスを削減し、かつ、短時間に効率よく５員環環状カーボネート化合物を製造する方法の提供。【解決手段】エポキシ化合物と二酸化炭素から５員環環状カーボネート化合物を製造する方法において、エポキシ化合物と触媒が存在する常圧の反応系内に、二酸化炭素を、気泡直径５０μｍ以下となるマイクロナノバブルにて連続的に供給し、反応させる５員環環状カーボネート化合物の製造方法。【選択図】 図１

  在存在催化剂的情况下，将环氧化合物和二氧化碳在5元环状碳酸酯制备过程中反应，无需高压反应装置，减少未反应气体，同时高效地在短时间内制备5元环状碳酸酯化合物的方法。在环氧化合物和二氧化碳制备5元环状碳酸酯化合物的方法中，将二氧化碳以微纳气泡直径小于50μm的形式连续供应到环氧化合物和催化剂存在的常压反应系统中，进行反应制备5元环状碳酸酯化合物的方法。【选择图】图1
• Odor neutralizer for ammonia and primary or secondary amines
  申请人：Firmenich SA

  公开号：US10662395B2

  公开（公告）日：2020-05-26

  The present invention relates to the field of perfumery and more particularly to the field of malodor counteractancy. In particular, it relates to the use of glycerol carbonate or glycerol carbonate derivatives to neutralize the odor from ammonia and primary or secondary amines. Perfuming compositions and perfuming consumer products comprising those malodour neutralizers are also objects of the invention.

  本发明涉及香水领域，尤其是恶臭抑制领域。本发明尤其涉及使用碳酸甘油酯或碳酸甘油酯衍生物来中和来自氨和伯胺或仲胺的气味。包含这些恶臭中和剂的香水组合物和香水消费品也是本发明的目标。
• ODOR NEUTRALIZER FOR AMMONIA AND PRIMARY OR SECONDARY AMINES
  申请人：Firmenich SA

  公开号：EP3377031A1

  公开（公告）日：2018-09-26
• A CROSSLINKED POLYMER AND RELATED METHODS THEREOF
  申请人：AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH

  公开号：US20210024698A1

  公开（公告）日：2021-01-28

  There is provided a method of crosslinking a polyhydroxyurethane (PHU) polymer having a plurality of diene moieties, preferably furan in the backbone and a crosslinked PHU polymer by reacting with a crosslinking agent having two or more dienophile moieties. Also provided is a method of removing the crosslinks of a crosslinked PHU polymer comprising a plurality of diene-dienophile adducts.
• The investigation of thermal pyrolysis of glycerol carbonate derivatives by TG–FTIR
  作者：Rujuan Li、Jing Liu、Hairong Tao、Donglan Sun、Dagang Xiao、Chunjing Liu

  DOI：10.1016/j.tca.2015.12.002

  日期：2016.1

  Three new GC derivatives, carbonic acid bis-(2-oxo-[1,3]dioxolan-4-ylmethyl) ester (CARE), succinic acid bis-(2-oxo-[1,3]dioxolan-4-ylmethyl) ester (SABE) and terephthalic acid bis-(2-oxo-[1,3]dioxolan-4-ylmethyl) ester (TABE), were designed and synthesized. We investigated the thermal stability and the thermal pyrolysis of three compounds by TG-FTIR, and the bond dissociation energy was calculated to further demonstrate the decomposition process. The results showed that the three GC derivatives had one, two, three weight loss stages, respectively. Their initial decomposition temperature was as high as 200 degrees C, which means that the compounds have good thermal stability. 5% weight loss temperature was increased in the order of TABE> SABE > CABE. In thermal pyrolysis process, the C-C, C-O bonds of cyclic carbonate fractured preferentially, and then the C-O bonds nearby cyclic carbonate of SABE and TABE continued to fracture to produce linear ester in the form of fragment. (C) 2015 Elsevier B.V. All rights reserved.