3-(4-benzoylphenoxy)propanol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(4-benzoylphenoxy)propanol
• 英文别名: [4-(3-dihydroxy-propoxy)phenyl]phenyl-methanone；[4-(3-Hydroxy-propoxy)-phenyl]-phenyl-methanone；[4-(3-hydroxypropoxy)phenyl]-phenylmethanone
• 化学式: C₁₆H₁₆O₃
• 分子量: 256.301
• InChiKey: JHXQMAGGDYUIMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,7-二溴-9,9-二甲基芴 、 3-(4-benzoylphenoxy)propanol 在 potassium phosphate 、 copper(l) iodide 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  벤조페논 작용기 함유 화합물, 상기 화합물의 광경화물을 포함한 유기물층을 구비한 유기전자소자

  摘要：

  本发明提供了一种含有苯甲酮作用基的化合物作为有机电子器件的有机材料层，并且所述化合物是以下所示的含有苯甲酮作用基的化合物：以下化学式I或化学式II所示的含有苯甲酮作用基的化合物：\[化学式I\] Ar-(R-R-Bp)在上述化学式中，m为1到10，Ar是具有m个连接基的取代或未取代的C-C芳基，具有m个连接基的取代或未取代的C-C杂环芳基，或具有m个连接基的取代或未取代的融合的C-C芳基，R和R分别独立地是简单键，-O-，取代或未取代的C-C芳基基，取代或未取代的C-C杂环芳基，取代或未取代的C-C烷基基，Bp是源自苯甲酮作用基的1价连接基。\[化学式II\] 在上述化学式中，n大于等于1，Ar'是具有m个连接基的取代或未取代的C-C芳基，具有m个连接基的取代或未取代的C-C杂环芳基，或具有m个连接基的取代或未取代的融合的C-C芳基，R和R分别独立地是简单键，-O-，取代或未取代的C-C芳基基，取代或未取代的C-C杂环芳基，取代或未取代的C-C融合芳基，取代或未取代的C-C烷基基，Bp'是源自苯甲酮作用基的1价连接基。

  公开号：

  KR20210023952A
• 作为产物：
  描述：

  4-羟基-二苯甲酮 、 3-溴-1-丙醇 在 potassium phosphate 、 copper(l) iodide 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 生成 3-(4-benzoylphenoxy)propanol
  参考文献：
  名称：

  벤조페논 작용기 함유 화합물, 상기 화합물의 광경화물을 포함한 유기물층을 구비한 유기전자소자

  摘要：

  本发明提供了一种含有苯甲酮作用基的化合物作为有机电子器件的有机材料层，并且所述化合物是以下所示的含有苯甲酮作用基的化合物：以下化学式I或化学式II所示的含有苯甲酮作用基的化合物：\[化学式I\] Ar-(R-R-Bp)在上述化学式中，m为1到10，Ar是具有m个连接基的取代或未取代的C-C芳基，具有m个连接基的取代或未取代的C-C杂环芳基，或具有m个连接基的取代或未取代的融合的C-C芳基，R和R分别独立地是简单键，-O-，取代或未取代的C-C芳基基，取代或未取代的C-C杂环芳基，取代或未取代的C-C烷基基，Bp是源自苯甲酮作用基的1价连接基。\[化学式II\] 在上述化学式中，n大于等于1，Ar'是具有m个连接基的取代或未取代的C-C芳基，具有m个连接基的取代或未取代的C-C杂环芳基，或具有m个连接基的取代或未取代的融合的C-C芳基，R和R分别独立地是简单键，-O-，取代或未取代的C-C芳基基，取代或未取代的C-C杂环芳基，取代或未取代的C-C融合芳基，取代或未取代的C-C烷基基，Bp'是源自苯甲酮作用基的1价连接基。

  公开号：

  KR20210023952A

文献信息

• [EN] SILSESQUIOXANE PHOTOINITIATORS<br/>[FR] PHOTO-INITIATEURS SILSESQUIOXANES
  申请人：BASF SE

  公开号：WO2010063612A1

  公开（公告）日：2010-06-10

  Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1') wherein n is 2m; m is an integer of 2 to 30; the sum of n' + a is an integer 4-60; n' is an even-numbered integer; a is an even-or uneven-numbered integer; and for example different A C1-C12alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C1-C3alkylene, preferably propylene; R1 and R2 for example are a photoactive moiety Q, or C2-20alkyl; Q is for example a group of formula (4); Z2 is for example C1-C6alkylene which is unsubstituted or substituted by one or more OR6; and R6, R12, R13 and R14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.

  具有光活性基团和胺基官能团的光引发剂化合物，与多面体寡聚硅氧烷结合，该光引发剂由公式（1）或（1'）表示，其中n为2m；m为2至30的整数；n'+a的总和为4-60的整数；n'为偶数整数；a为偶数或奇数整数；例如不同的A C1-C12烷基，或光活性基团Q1，或公式（2）的基团；例如E为直接键，L为线性或支链C1-C3烷基，优选丙烯基；例如R1和R2为光活性基团Q，或C2-20烷基；例如Q为公式（4）的基团；例如Z2为未取代或取代一个或多个OR6的C1-C6烷基；例如R6、R12、R13和R14为氢；特别适用于低迁移光引发剂。
• Modulators of peroxisome proliferator activated receptors
  申请人：Brooks Alisa Dawn

  公开号：US20050020684A1

  公开（公告）日：2005-01-27

  Disclosed is a compound represented by Structural Formula (I): Ar is a substituted or unsubstituted aromatic group. Q is a covalent bond, —CH 2 — or —CH 2 CH 2 —; W is a substituted or unsubstituted alkylene or a substituted or unsubstituted heteroalkylene linking group from two to ten atoms in length, preferably from two to seven atoms in length. Phenyl Ring A is optionally substituted with up to four substituents in addition to R 1 and W, R 2 is (CH 2 ) n —CH(OR 2 )—(CH 2 ) n E, —(CH)═C(OR 2 )—(CH 2 ) n E, —(CH 2 ) n —CH(Y)—(CH 2 ) m E or (CH)═C(Y)(CH 2 ) m E; wherein E is COOR 3 , C 1 -C 3 alkylnitrile, carboxamide, sulfonamide, acylsulfonamide or tetrazole and wherein sulfonamide, acylsulfonamide and tetrazole are optionally substituted with one or more substituents independently selected from: C 1 -C 6 alkyl, haloalkyl and aryl-C o - 4 -alkyl; R 2 is H, an aliphatic group, a substituted aliphatic group, haloalkyl, an aromatic group, a substituted aromatic group, —COR 4 , —COOR 4 , —CONR 5 R 6 , —C(S)R 4 , —C(S)OR 4 or C(S)NR 5 R 6 , R 3 is H, an aliphatic group, a substituted aliphatic group, an aromatic group or a substituted aromatic group. Y is O—, CH 2 —, CH 2 CH 2 — or CH═CH— and is bonded to a carbon atom in Phenyl Ring A that is ortho to R 1 . R 4 -R 6 are independently H, an aliphatic group, a substituted aliphatic group, an aromatic group or a substituted aromatic group. n and m are independently 0, 1 or 2.

  本发明公开了一种由结构式（I）表示的化合物：其中Ar是取代或未取代的芳香基团。Q是共价键，-CH2-或-CH2CH2-; W是取代或未取代的烷基或取代或未取代的异烷基连接基，长度为两到十个原子，优选长度为两到七个原子。苯环A可选地与R1和W以外的最多四个取代基取代，R2是（CH2）n-CH（OR2）-（CH2）nE，-（CH）=C（OR2）-（CH2）nE，-（CH2）n-CH（Y）-（CH2）mE或（CH）=C（Y）（CH2）mE;其中E是COOR3，C1-C3烷基腈，羧酰胺，磺酰胺，酰基磺酰胺或四唑，磺酰胺，酰基磺酰胺和四唑可选地与一个或多个取代基取代，独立地选自：C1-C6烷基，卤代烷基和芳基-Co-4-烷基; R2是H，脂肪基，取代脂肪基，卤代烷基，芳基，取代芳基，-COR4，-COOR4，-CONR5R6，-C（S）R4，-C（S）OR4或C（S）NR5R6，R3是H，脂肪基，取代脂肪基，芳基或取代芳基。Y是O-，CH2-，CH2CH2-或CH═CH-，并与Phenyl环A中与R1相邻的碳原子键合。R4-R6独立地是H，脂肪基，取代脂肪基，芳基或取代芳基。n和m独立地为0、1或2。
• Polymerizable photoinitiators and radiation curable compositions
  申请人：AGFA NV

  公开号：EP2199273B1

  公开（公告）日：2018-02-21
• Synthesis of lithium ω-(m- and p-lithiophenoxy)alkoxides modified with magnesium 2-ethoxyethoxide. Crystal structures of bis[4-(2-hydroxyethoxy)phenyl]mercury and bis[4-(3-hydroxypropoxy)phenyl]mercury
  作者：Constantinos S Salteris、Ioannis D Kostas、Maria Micha-Screttas、Barry R Steele、George A Heropoulos、Constantinos G Screttas、Aris Terzis

  DOI：10.1016/s0022-328x(99)00425-8

  日期：1999.11

  m- and p-Chlorinated omega-phenoxyalcohols 1, were transformed into the corresponding lithium omega-(m- and p-lithiophenoxy)alkoxides 4, respectively, by successive deprotonation with n-butyllithium and subsequent chlorine-lithium exchange by lithium naphthalene radical anion in THF-methylcyclohexane. Lithium 2-(4-lithiophenoxy)ethoxide (4a') was also prepared by bromine-lithium exchange of 2-(4-bromophenoxy)ethanol (2a') with two equivalents of n-butyllithium. The organolithiums were modified with magnesium 2-ethoxyethoxide in order to avoid ortho-metallation of the above-mentioned substituted arenes. Subsequent reaction of these intermediates with the electrophiles carbon dioxide, benzophenone, benzonitrile and 0.5 equivalents of mercuric chloride yielded the expected m- and p-substituted (omega-hydroxyalkoxy)benzenes in yields ranging from 50 to 75%. The crystal structures of the organomercurials 8a' and 8b' have been determined and revealed the HE atom to occupy a crystallographic center of symmetry in a linear C-Hg-C arrangement. (C) 1999 Elsevier Science S.A. All rights reserved.
• MODULATORS OF PEROXISOME PROLIFERATOR ACTIVATED RECEPTORS
  申请人：ELI LILLY AND COMPANY

  公开号：EP1392637A2

  公开（公告）日：2004-03-03