5'-(3,4-dihydroxyphenyl)-[1,1':3',1''-terphenyl]-3,3'',4,4''-tetraol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5'-(3,4-dihydroxyphenyl)-[1,1':3',1''-terphenyl]-3,3'',4,4''-tetraol
• 英文别名: 4-[3,5-Bis(3,4-dihydroxyphenyl)phenyl]benzene-1,2-diol
• 化学式: C₂₄H₁₈O₆
• 分子量: 402.403
• InChiKey: OYNKCMVXYRBNII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  30
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  121
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  壬酸 、 5'-(3,4-dihydroxyphenyl)-[1,1':3',1''-terphenyl]-3,3'',4,4''-tetraol 在 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 、 锌 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以77%的产率得到1,3,5-triphenylbenzene-tris(3',4'-bisnonanoat)
  参考文献：
  名称：

  Frackowiak, Esther; Scherowsky, Guenter, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1997, vol. 52, # 12, p. 1539 - 1543

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3,5-tris-(3,4-dimethoxyphenyl) benzene 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 5'-(3,4-dihydroxyphenyl)-[1,1':3',1''-terphenyl]-3,3'',4,4''-tetraol
  参考文献：
  名称：

  硼酸酯Sierpiński三角形分形：从前体设计到表面合成和自组装超结构

  摘要：

  本文中，我们设计并合成了具有三重节点的前体，并成功构建了具有硼酸酯键的共价Sierpiński三角（ST）分形，该分形在室温下在液/固界面上以及通过在环境条件下的水气氛中进行热退火而制得。值得注意的是，共价ST的大规模有序超结构是通过热退火构建的，这为ST的性质研究铺平了道路。

  DOI：

  10.1039/d0cc07047e

文献信息

• Synthesis of a highly crystalline, covalently linked porous network
  申请人：Lavigne John J.

  公开号：US10273339B2

  公开（公告）日：2019-04-30

  Porous networks are described linked by boronates. Also described are processes for producing the porous networks. The porous networks are formed by reacting a polyboronic acid with itself or with a polydiol, a polydiamine, or a polyamino alcohol. The resulting boronate linkage is covalently bonded. The characteristics and properties of the resulting porous material can be varied and altered by changing the reactants and by incorporating functional groups into the reactants. Of particular advantage, the porous materials can be formed at or near atmospheric pressure and at low temperature in the presence of one or more solvents.

  多孔网络是由硼酸盐连接而成的。还描述了制备多孔网络的过程。多孔网络是通过将聚硼酸与自身或聚二醇、聚二胺或聚氨基醇反应形成的。所得的硼酸盐键是共价键。通过改变反应物和将功能基团纳入反应物中，可以改变所得多孔材料的特性和性质。特别优点是，多孔材料可以在一个或多个溶剂存在的情况下，在大气压力或接近大气压力的低温下形成。
• SYNTHESIS OF A HIGHLY CRYSTALLINE, COVALENTLY LINKED POROUS NETWORK
  申请人：Lavigne John J.

  公开号：US20090227697A1

  公开（公告）日：2009-09-10

  Porous networks are described linked by boronates. Also described are processes for producing the porous networks. The porous networks are formed by reacting a polyboronic acid with itself or with a polydiol, a polydiamine, or a polyamino alcohol. The resulting boronate linkage is covalently bonded. The characteristics and properties of the resulting porous material can be varied and altered by changing the reactants and by incorporating functional groups into the reactants. Of particular advantage, the porous materials can be formed at or near atmospheric pressure and at low temperature in the presence of one or more solvents.
• Synthesis of a Highly Crystalline, Covalently Linked Porous Network
  申请人：Lavigne John J.

  公开号：US20130030072A1

  公开（公告）日：2013-01-31

  Porous networks are described linked by boronates. Also described are processes for producing the porous networks. The porous networks are formed by reacting a polyboronic acid with itself or with a polydiol, a polydiamine, or a polyamino alcohol. The resulting boronate linkage is covalently bonded. The characteristics and properties of the resulting porous material can be varied and altered by changing the reactants and by incorporating functional groups into the reactants. Of particular advantage, the porous materials can be formed at or near atmospheric pressure and at low temperature in the presence of one or more solvents.
• US8258197B2
  申请人：——

  公开号：US8258197B2

  公开（公告）日：2012-09-04
• US8829065B2
  申请人：——

  公开号：US8829065B2

  公开（公告）日：2014-09-09