(3-carboxyl-phenyl)-(4-(2'-carboxyl-phenyl)-benzyl)ether

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (3-carboxyl-phenyl)-(4-(2'-carboxyl-phenyl)-benzyl)ether
• 英文别名: 2-[4-[(3-Carboxyphenoxy)methyl]phenyl]benzoic acid；2-[4-[(3-carboxyphenoxy)methyl]phenyl]benzoic acid
• 化学式: C₂₁H₁₆O₅
• 分子量: 348.355
• InChiKey: DTQUQSBOYFZUPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  (3-carboxyl-phenyl)-(4-(2'-carboxyl-phenyl)-benzyl)ether 、 manganese (II) acetate tetrahydrate 、 1,3-双(1-咪唑)丙烷 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 72.0h， 以38%的产率得到[Mn((3-carboxyl-phenyl)-(4-(2'-carboxyl-phenyl)-benzyl)ether(-2H))(1,3-bis(imidazol-1'-yl)propane)]
  参考文献：
  名称：

  半刚性二元羧酸配体配位聚合物的合成与结构

  摘要：

  配合物[Co(L1)(mpy)] (1), [Ni(L1)(mpy)] (2), [Co(L1)(tbpy)]·2H2O (3), [Ni2(L1)2( tbpy)2]·5H2O (4), [Mn2(L1)2(tbpy)2]·3H2O (5), [Mn(L1)(biim-3)] (6), [Ni2(L1)2(btb) )2(H2O)]·2H2O (7), [Cu(L2)(mpy)]·7H2O (8), [Co(L2)(tbpy)(H2O)] (9), [Ni(L2)(tbpy) )(H2O)]·H2O (10)、[Cu(L2)(bib)]·2H2O (11) 和 [Cu(L2)(btb)]·2H2O (12) [H2L1 = (3-羧基-苯基) )-(4-(2'-羧基-苯基)-苄基)醚，H2L2 = 3-羧基-1-(4'-羧基苄基)-2-氧化吡啶鎓，mpy = 2-(4-(4'-甲基苯基)

  DOI：

  10.1002/zaac.201400206

文献信息

• Four new coordination polymers constructed by (3-carboxyl-phenyl)-(4-(2’-carboxyl-phenyl)-benzyl) ether and 2,2'-bipyridine
  作者：Yuan-Chun He、Ying-Hui Zhou、Yu Zhao、Ya-Nan Zhang、Lingyan Wang、Shuang Wu、Fang-Hua Zhao

  DOI：10.1016/j.inoche.2022.109611

  日期：2022.8

  analyses, and thermogravimetric analyses. The results exhibit that the structures of compounds 1-3 are essentially isomorphic and display similar ladder-like double-chain structures. The adjacent chains are extended to the 2D supramolecular layer by intermolecular π-π interactions. Compound 4 shows a 0D metallomacrocyclic structure, which can penetrate adjacent metallomacrocyclic to generate a 0D → 1D

  配位聚合物因其迷人的结构和潜在的应用而受到广泛关注。众所周知，有几个因素会影响所需配位聚合物的最终结构。在这项工作中，四种新型配位聚合物[Mn(L)(bpy)]·H 2 O ( 1 )、[Co(L)(bpy)]·H 2 O ( 2 )、[Cd(L)(bpy) ]·H 2 O ( 3 )和[Zn(L)(bpy)]·H 2 O ( 4 )由(3-羧基-苯基)-(4-(2'-羧基-苯基)-苄基构成) 醚 (H 2L) 和 2,2'-联吡啶 (bpy)。它们的结构通过单晶 X 射线衍射分析确定，并通过 IR 光谱、元素分析和热重分析进一步表征。结果表明，化合物1-3的结构基本上是同构的，并显示出类似的梯状双链结构。相邻的链通过分子间的 π-π 相互作用延伸到二维超分子层。化合物4显示了一个 0D 金属大环结构，它可以穿透相邻的金属大环以产生 0D → 1D 叉指结构。此外，叉指型超分子链通过分子间
• Syntheses and Structures of Coordination Polymers Constructed by Semi-Rigid Bicarboxylic Acid Ligands
  作者：Ying-Ying Liu、Jin Yang、Jian-Fang Ma

  DOI：10.1002/zaac.201400206

  日期：2014.9

  ethyl)benzene] were synthesized. Compounds 1–6 have similar 1D chain structures, which are further linked by π–π interactions to generate supramolecular double chains for 1 and 2, and supramolecular layers for 3–6. Compound 7 displays a 3D 6-connected framework with (44·611) topology. Compound 8 features a monomolecular structure, which is further linked by hydrogen bonds between the lattice water

  配合物[Co(L1)(mpy)] (1), [Ni(L1)(mpy)] (2), [Co(L1)(tbpy)]·2H2O (3), [Ni2(L1)2( tbpy)2]·5H2O (4), [Mn2(L1)2(tbpy)2]·3H2O (5), [Mn(L1)(biim-3)] (6), [Ni2(L1)2(btb) )2(H2O)]·2H2O (7), [Cu(L2)(mpy)]·7H2O (8), [Co(L2)(tbpy)(H2O)] (9), [Ni(L2)(tbpy) )(H2O)]·H2O (10)、[Cu(L2)(bib)]·2H2O (11) 和 [Cu(L2)(btb)]·2H2O (12) [H2L1 = (3-羧基-苯基) )-(4-(2'-羧基-苯基)-苄基)醚，H2L2 = 3-羧基-1-(4'-羧基苄基)-2-氧化吡啶鎓，mpy = 2-(4-(4'-甲基苯基)