Methyl 3-(furan-2-ylmethylimino)butanoate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: Methyl 3-(furan-2-ylmethylimino)butanoate
• 化学式: C₁₀H₁₃NO₃
• 分子量: 195.21
• InChiKey: QZAMIPDEEJGIPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Photopolymerization synergist
  申请人：Piedmont Chemical Industries, LLC

  公开号：US11421049B2

  公开（公告）日：2022-08-23

  An a photopolymerization formulation is provided as is an improved method for forming an object using the formulation. The formulation comprises a polymerizable ethylenically unsaturated monomer, oligomer or polymer; a photoinitiator; and a synergist selected from the group consisting of Formula I, Formula II and Formula III; wherein: R1, R4, R6 and R9 are independently selected from an alkene, a cyclic olefin, aryl, cyclic heteroatom containing group or acylic heteroatom containing group each of which is optionally substituted; R2 and R8 are independently selected from hydrogen; linear or branched alkyl of 1 to 10 carbons; aryl; —C(O)R10; —NR11R12; or —COR15; R3, R5 and R7 are independently selected from hydrogen, saturated or unsaturated, cyclic or acyclic, optionally substituted alkyl of 1-20 carbons or optionally substituted aryl of no more than four fused aromatic rings; R2 and R3 or R7 and R8 may be taken together in each Formula to form a saturated or unsaturated optionally substituted ring; R10 and R15 independently a saturated or unsaturated, cyclic or acyclic, optionally substituted alkyl of 1-20 carbons; carboxylic acid; ketone or an ester; and R11 and R12 are independently selected from hydrogen; saturated or unsaturated, cyclic or acyclic, optionally substituted alkyl of 1-20 carbons; optionally substituted aryl with up to five fused aromatic rings.

  本发明提供了一种光聚合配方，以及使用该配方形成物体的改进方法。该配方包括可聚合的乙烯基不饱和单体、低聚物或聚合物；光引发剂；以及选自式 I、式 II 和式 III 组的增效剂； 其中 R1、R4、R6 和 R9 分别独立地选自烯烃、环状烯烃、芳基、含环状杂原子的基团或含酰基杂原子的基团，其中每个基团都被任选取代； R2 和 R8 独立选自氢、1 至 10 个碳原子的直链或支链烷基、芳基、-C(O)R10、-NR11R12 或 -COR15； R3、R5 和 R7 独立选自氢、饱和或不饱和、环状或无环、1-20 个碳原子的任选取代的烷基或不多于四个融合芳环的任选取代的芳基； R2 和 R3 或 R7 和 R8 可在各式中组合成饱和或不饱和的任选取代环； R10和R15各自为饱和或不饱和、环状或非环状、1-20个碳原子的任选取代的烷基；羧酸；酮或酯；以及 R11 和 R12 分别独立地选自氢；饱和或不饱和、环状或无环、可选取代的 1-20 碳烷基；可选取代的具有最多五个融合芳环的芳基。
• Photopolymerization Synergist
  申请人：Piedmont Chemical Industries, LLC

  公开号：US20210139616A1

  公开（公告）日：2021-05-13

  An a photopolymerization formulation is provided as is an improved method for forming an object using the formulation. The formulation comprises a polymerizable ethylenically unsaturated monomer, oligomer or polymer; a photoinitiator; and a synergist selected from the group consisting of Formula I, Formula II and Formula III; wherein: R 1 , R 4 , R 6 and R 9 are independently selected from an alkene, a cyclic olefin, aryl, cyclic heteroatom containing group or acylic heteroatom containing group each of which is optionally substituted; R 2 and R 8 are independently selected from hydrogen; linear or branched alkyl of 1 to 10 carbons; aryl; —C(O)R 10 ; —NR 11 R 12 ; or —COR 15 ; R 3 , R 5 and R 7 are independently selected from hydrogen, saturated or unsaturated, cyclic or acyclic, optionally substituted alkyl of 1-20 carbons or optionally substituted aryl of no more than four fused aromatic rings; R 2 and R 3 or R 7 and R 8 may be taken together in each Formula to form a saturated or unsaturated optionally substituted ring; R 10 and R 15 independently a saturated or unsaturated, cyclic or acyclic, optionally substituted alkyl of 1-20 carbons; carboxylic acid; ketone or an ester; and R 11 and R 12 are independently selected from hydrogen; saturated or unsaturated, cyclic or acyclic, optionally substituted alkyl of 1-20 carbons; optionally substituted aryl with up to five fused aromatic rings.