[RuCl2(PCy3)(CH(CH2)5C3H2N2Mes)]

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [RuCl2(PCy3)(CH(CH2)5C3H2N2Mes)]
• 化学式: C₃₆H₅₇Cl₂N₂PRu
• 分子量: 720.812
• InChiKey: JEVQKRSKTCJEGN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  11.96
• 重原子数：
  42
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.72
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  7-溴-1-庚烯 在 potassium tert-butylate 作用下， 以 正己烷 、 甲苯 、 苯 为溶剂， 反应 26.0h， 生成 [RuCl2(PCy3)(CH(CH2)5C3H2N2Mes)]
  参考文献：
  名称：

  Metallo-Supramolecular Cyclic Polymers

  摘要：

  Cyclic brush polymers represent an exciting new macromolecular topology. For the first time, this new topology has been combined with metallo-supramolecular interactions to construct novel cyclic brush polymers. Here, ring-expansion metathesis polymerization was used to synthesize a universal cyclic template with a polynorbornene backbone, which was further modified with the metal-chelating synthon terpyridine. The terpyridine side chains served as the key supramolecular unit for the creation of cyclic polymer brushes and gels. This metallo-supramolecular functionality allowed direct visualization of the cyclic brush polymers by transmission electron microscopy for the first time. This demonstration should open a new area in which supramolecular interactions are used to build an array of novel cyclic brush copolymers as well as other cyclic-polymer-based architectures generating new materials.

  DOI：

  10.1021/ja407381f

文献信息

• Cyclic Ruthenium-Alkylidene Catalysts for Ring-Expansion Metathesis Polymerization
  作者：Andrew J. Boydston、Yan Xia、Julia A. Kornfield、Irina A. Gorodetskaya、Robert H. Grubbs

  DOI：10.1021/ja8037849

  日期：2008.9.24

  in ring-expansion metathesis polymerization (REMP). The catalyst structures feature chelating tethers extending from one N-atom of an N-heterocyclic carbene (NHC) ligand to the Ru metal center. The catalyst design is modular in nature, which provided access to Ru complexes having varying tether lengths, as well as electronically different NHC ligands. Structural impacts of the tether length were unveiled

  已经制备了一系列环状 Ru-亚烷基催化剂并评估了它们在扩环复分解聚合 (REMP) 中的效率。催化剂结构的特点是螯合系链从 N-杂环卡宾 (NHC) 配体的一个 N 原子延伸到 Ru 金属中心。催化剂设计本质上是模块化的，它提供了对具有不同系链长度的 Ru 配合物的访问，以及电子不同的 NHC 配体。通过（1）H NMR光谱以及单晶X射线分析揭示了系绳长度的结构影响。通过环辛烯的聚合评估催化剂活性，并提供了关于增长速率、分子内链转移和催化剂稳定性的关键数据，这是通过 REMP 有效合成环状聚（烯烃）所必需的三个领域。从这些研究中确定，虽然增加催化剂的系链长度会导致聚合速率提高，但发现较短的系链有利于分子内链转移和催化剂从聚合物中的释放。发现通过骨架饱和对 NHC 进行电子修饰比系链的同系化在更大程度上提高了聚合速率。总体而言，发现带有 5 或 6 碳系链和饱和 NHC 配体的环状 Ru 配合物易于合成，可作为
• Metallo-Supramolecular Cyclic Polymers
  作者：Ke Zhang、Yongping Zha、Bo Peng、Yongming Chen、Gregory N. Tew

  DOI：10.1021/ja407381f

  日期：2013.10.30

  Cyclic brush polymers represent an exciting new macromolecular topology. For the first time, this new topology has been combined with metallo-supramolecular interactions to construct novel cyclic brush polymers. Here, ring-expansion metathesis polymerization was used to synthesize a universal cyclic template with a polynorbornene backbone, which was further modified with the metal-chelating synthon terpyridine. The terpyridine side chains served as the key supramolecular unit for the creation of cyclic polymer brushes and gels. This metallo-supramolecular functionality allowed direct visualization of the cyclic brush polymers by transmission electron microscopy for the first time. This demonstration should open a new area in which supramolecular interactions are used to build an array of novel cyclic brush copolymers as well as other cyclic-polymer-based architectures generating new materials.