2-(2,6-dichlorophenyl)-1H-phenanthro[9,10-d]imidazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: 2-(2,6-dichlorophenyl)-1H-phenanthro[9,10-d]imidazole
• 化学式: C₂₁H₁₂Cl₂N₂
• 分子量: 363.246
• InChiKey: CLNSGAYZAYIHRE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  25
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.7
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,6-二氯苯甲醛 、 菲醌 在 ammonium acetate 、 溶剂黄146 作用下， 反应 0.33h， 以90%的产率得到2-(2,6-dichlorophenyl)-1H-phenanthro[9,10-d]imidazole
  参考文献：
  名称：

  Synthesis of 2,4,5-Trisubstituted Phenanthroimidazole Derivatives using SBA-Pr-SO3H as a Nanocatalyst

  摘要：

  An efficient one-pot approach for the preparation of 2,4,5-trisubstituted phenanthroimidazole derivatives is described. The three-component reaction between 9,10-phenanthraquinone, benzaldehyde derivatives, and ammonium acetate proceeds in the presence of SBA-Pr-SO3H as a nanoporous solid acid catalyst in short reaction times and good to excellent yields.

  DOI：

  10.17344/acsi.2016.3111

文献信息

• Synthesis of 2,4,5-Trisubstituted Phenanthroimidazole Derivatives using SBA-Pr-SO3H as a Nanocatalyst
  作者：Ghodsi Mohammadi Ziarani、Elham Tavaf、Vaezeh Fathi Vavsari、Alireza Badiei

  DOI：10.17344/acsi.2016.3111

  日期：2017.9.10

  An efficient one-pot approach for the preparation of 2,4,5-trisubstituted phenanthroimidazole derivatives is described. The three-component reaction between 9,10-phenanthraquinone, benzaldehyde derivatives, and ammonium acetate proceeds in the presence of SBA-Pr-SO3H as a nanoporous solid acid catalyst in short reaction times and good to excellent yields.