(E)-acetophenone O-(2-vinyloxyethyl)oxime

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-acetophenone O-(2-vinyloxyethyl)oxime
• 英文别名: (E)-N-(2-ethenoxyethoxy)-1-phenylethanimine
• 化学式: C₁₂H₁₅NO₂
• 分子量: 205.257
• InChiKey: XZZGUWVKWUKYJL-ACCUITESSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  30.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  苯乙酮肟 、 2-氯乙基乙烯基醚 在 氢氧化钾 作用下， 以 二甲基亚砜 为溶剂， 反应 2.0h， 以88%的产率得到(E)-acetophenone O-(2-vinyloxyethyl)oxime
  参考文献：
  名称：

  First Representatives of O-(2-Vinyloxyethyl)oximes

  摘要：

  Previously unknown ketone and acetaldehyde O-(2-vinyloxyethyl)oximes were synthesized in 22-88% by reaction of the corresponding oximes with 2-chloroethyl vinyl ether in the system KOH-DMSO.

  DOI：

  10.1023/b:rujo.0000010550.07513.f0

文献信息

• CONTROLLED RELEASE OF ACTIVE COMPOUNDS FROM DYNAMIC MIXTURES
  申请人：Herrmann Andreas

  公开号：US20100226875A1

  公开（公告）日：2010-09-09

  The present invention relates to a dynamic mixture in the form of a dynamic mixture obtained by reacting together, in the presence of water, at least one O-substituted hydroxylamine or S-substituted thiohydroxylamine derivative with at least one perfuming, flavoring, insect repellent or attractant, bactericide or fungicide aldehyde or ketone. This mixture is capable of releasing in a controlled and prolonged manner the aldehyde or ketone into the surrounding environment. Furthermore, the present invention concerns also the use of these dynamic mixtures as perfuming ingredients as well as the perfuming compositions or perfumed articles that include these mixtures.

  本发明涉及一种动态混合物，其为通过在水的存在下将至少一种O-取代羟胺或S-取代硫羟胺衍生物与至少一种香料、调味剂、驱虫剂或诱引剂、杀菌剂或杀真菌剂醛或酮反应而得到的动态混合物。该混合物能够以受控和延长的方式释放醛或酮进入周围环境。此外，本发明还涉及将这些动态混合物用作调香成分以及包括这些混合物的调香组合物或香气物品的用途。
• CONTROLLED RELEASE OF ACTIVE COMPOUNDS FROM DYNAMIC MIXTURES
  申请人：Firmenich S.A.

  公开号：EP2010293A2

  公开（公告）日：2009-01-07
• [EN] CONTROLLED RELEASE OF ACTIVE COMPOUNDS FROM DYNAMIC MIXTURES<br/>[FR] LIBERATION REGULEE DE COMPOSES ACTIFS PROVENANT DE MELANGES DYNAMIQUES
  申请人：FIRMENICH & CIE

  公开号：WO2007085991A2

  公开（公告）日：2007-08-02

  [EN] The present invention relates to a dynamic mixture in the form of a dynamic mixture obtained by reacting together, in the presence of water, at least one O-substituted hydroxylamine or S-substituted thiohydroxylamine derivative with at least one perfuming, flavoring, insect repellent or attractant, bactericide and/or fungicide aldehyde or ketone. The invention's mixture is capable of releasing in a controlled and prolonged manner said aldehyde or ketone in the surrounding environment. Furthermore, the present invention concerns also the use of said dynamic mixtures as perfuming ingredients as well as the perfuming compositions or perfumed articles comprising the invention's mixtures.
  [FR] La présente invention concerne un mélange dynamique sous la forme d'un mélange dynamique obtenu par la réaction, en présence d'eau, d'au moins un dérivé hydroxylamine O-substituée ou thiohydroxylamine S-substituée avec au moins un aldéhyde ou une cétone parfumant, aromatisant, insecticide ou insecticide-appât, bactéricide et/ou fongicide. Le mélange de l'invention est capable de libérer ledit aldéhyde ou ladite cétone d'une manière régulée et prolongée dans l'environnement proche. En outre, la présente invention concerne également l'utilisation desdits mélanges dynamiques en tant qu'ingrédients de parfum ainsi que des compositions de parfum ou des articles parfumés comprenant les mélanges de l'invention.
• First Representatives of O-(2-Vinyloxyethyl)oximes
  作者：B. F. Kukharev、V. K. Stankevich、G. R. Klimenko

  DOI：10.1023/b:rujo.0000010550.07513.f0

  日期：2003.10

  Previously unknown ketone and acetaldehyde O-(2-vinyloxyethyl)oximes were synthesized in 22-88% by reaction of the corresponding oximes with 2-chloroethyl vinyl ether in the system KOH-DMSO.