diethyl diallyl malonate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: diethyl diallyl malonate
• 英文别名: Bis(prop-2-enyl) propanedioate;butane；bis(prop-2-enyl) propanedioate;butane
• 化学式: C₄H₁₀*C₉H₁₂O₄
• 分子量: 242.315
• InChiKey: KPOKVKZRDNQWFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.64
• 重原子数：
  17
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  CHPh 、 二烯丙基丙二酸二乙酯 生成 diethyl diallyl malonate
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• [EN] NOVEL TRANSITION METAL COMPLEXES, THEIR PREPARATION AND USE<br/>[FR] NOUVEAUX COMPLEXES DE MÉTAUX DE TRANSITION, LEUR PRÉPARATION ET UTILISATION
  申请人：LANXESS DEUTSCHLAND GMBH

  公开号：WO2014187973A1

  公开（公告）日：2014-11-27

  Novel transition metal complexes are provided which represent viable catalysts for a broad variety of reactions such as hydrogenation reactions and metathesis reactions. Novel preparation processes are made available via unprecedented routes inter alia not involving structures according to Grubbs I or Grubbs II catalysts.

  提供了新型过渡金属配合物，这些配合物可作为广泛反应的催化剂，如加氢反应和醇醚交换反应。通过前所未有的途径提供了新颖的制备方法，其中不涉及Grubbs I或Grubbs II催化剂的结构。
• [EN] RUTHENIUM OLEFIN METATHESIS CATALYSTS BEARING N-HETEROCYCLIC CARBENE LIGANDS WITH SUBSTITUTED BACKBONE<br/>[FR] CATALYSEURS DE MÉTATHÈSE D'OLÉFINES À BASE DE RUTHÉNIUM PORTANT DES LIGANDS CARBÈNES N-HÉTÉROCYCLIQUES À SQUELETTE SUBSTITUÉ
  申请人：MATERIA INC

  公开号：WO2009126831A1

  公开（公告）日：2009-10-15

  This invention relates generally to olefin metathesis, more particularly, to tri- or tetra-substituted imidazoliniυm salts which are precursors to N-heterocyclic carbene (NHC) ligands with tri- or tetra-substituted irnidazolinium rings, organometallic ruthenium complexes comprising gem di-substituted imidazoiinium NHC ligands, organometallic ruthenium complexes comprising tri- or tetra-substituted imidazoiinium NHC ligands, and to olefin metathesis methods using them. The catalysts and methods of the invention have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

  本发明通常涉及烯烃转化反应，更具体地涉及三取代或四取代咪唑啉盐，这些盐是N-杂环卡宾（NHC）配体的前体，具有三取代或四取代咪唑啉环的有机金属钌配合物，包含宝石二取代咪唑啉NHC配体的有机金属钌配合物，包含三取代或四取代咪唑啉NHC配体的有机金属钌配合物，以及使用它们的烯烃转化反应方法。本发明的催化剂和方法在催化、有机合成和工业化学领域具有实用性。
• Novel catalyst systems and a process for reacting chemical compounds in the presence of said catalyst systems
  申请人：Obrecht Werner

  公开号：US20070208206A1

  公开（公告）日：2007-09-06

  New catalyst systems for metathesis reactions, in particular for the metathesis of nitrile rubber, are provided.

  为亚胺橡胶的交换反应提供了新的催化剂系统。
• [EN] OLEFINIC METATHESIS IN THE PRESENCE OF PHENOLIC COMPOUNDS<br/>[FR] METATHESE OLEFINIQUE EN PRESENCE DE COMPOSES PHENOLIQUES
  申请人：SASOL TECHNOLOGY UK LTD

  公开号：WO2004056728A1

  公开（公告）日：2004-07-08

  According to the present invention there is provided a metathesis reaction between at least two olefinic compounds which are the same or different, each olefinic compound comprising a non-cyclic olefin or a compound which includes a non-cyclic olefinic moiety. The metathesis reaction is carried out in the presence of a Grubbs first generation catalyst and is characterised therein that it is carried out in the presence of a phenolic compound in the form of a phenol or a substituted phenol, which substituted phenol includes at least one hydroxyl and at least one further moiety other than H and OH attached to an arene ring.

  根据本发明，提供了至少两种相同或不同的烯烃化合物之间的交换反应，每种烯烃化合物包括非环烯烃或包含非环烯烃基团的化合物。交换反应在格鲁布斯第一代催化剂存在下进行，并且其特点在于在酚类化合物的存在下进行，所述酚类化合物为苯酚或取代苯酚，其中取代苯酚包括至少一个羟基和至少一个除H和OH之外的进一步基团连接到芳香环上。
• [EN] CATALYST COMPOSITION<br/>[FR] COMPOSITION CATALYTIQUE
  申请人：XIMO AG

  公开号：WO2014155185A1

  公开（公告）日：2014-10-02

  A composition comprising a molybdenum (VI)- based or tungsten(VI)-based organometallic complex dissolved or dispersed in an inert material having a melting point of about 50 to about 70 degrees centigrade.

  一种组合物，包括一种钼(VI)或钨(VI)基有机金属配合物，溶解或分散在一个熔点约为50到70摄氏度的惰性材料中。