四(对甲苯基)氯化锑 | 61705-00-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 四(对甲苯基)氯化锑
• 英文名称: tetra(para-tolyl)stibonium chloride
• 英文别名: tetra-p-tolylantimony chloride；Tetrakis(4-methylphenyl)stibanium chloride；tetrakis(4-methylphenyl)stibanium;chloride
• CAS: 61705-00-8；85987-40-2
• 化学式: C₂₈H₂₈Sb*Cl
• 分子量: 521.733
• InChiKey: FZNZEFZLUICUNU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.99
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  sodium perrhenate 、 四(对甲苯基)氯化锑 以 水 为溶剂， 以71%的产率得到[tetra-p-tolylantimony][ReO4]
  参考文献：
  名称：

  Synthesis and structure of tetra-p-tolylantimony complexes [(4-MeC6H4)4Sb] 2 + [Hg2I6]2−, [(4-MeC6H4)4Sb] 2 + [HgI4]2−, [(4-MeC6H4)4Sb] 3 + [Sb3I12]2−, and [(4-MeC6H4)4Sb]+[ReO4]−

  摘要：

  Complexes [(4-MeC6H4)(4)Sb] (2) (+) [Hg2I6](2-) (I), [(4-MeC6H4)(4)Sb] (2) (+) [HgI4](2-) (II), [(4-MeC6H4)(4)Sb] (3) (+) [Sb3I12](2-) (III), were synthesized by reactions of tetra-p-tolylantimony iodide with mercury iodide and antimony iodide, respectively. Tetra-p-tolylantimony perrhenate [(4-MeC6H4)(4)Sb](+)[ReO4](-) (IV) was prepared from tetra-p-tolylantimony chloride and sodium perrhenate in acetone. Crystal structures of complexes I, II, and IV were determined by X-ray crystallography. Mercury and rhenium atoms have tetrahedral coordinations in these complexes. The Hg-I and Re-O distances in the structures of I, II, and IV vary within 2.7719(13)-2.7908(12), 2.7028(3)-2.9163(3) , and 1.693(3)-1.744(3) , respectively. Antimony atoms in two crystallographically independent trinuclear centrosymmetric [Sb3I12](2-) anions of complex III have an octahedral environment. Each terminal SbI3 fragment (Sb-I-t, 2.8265(9)-2.8333(10)) is bound to the central atom through tree bridging iodine atoms (Sb(2)-I-br, 3.2275(9)-3.3620(10)). The distances between the central Sb atom and bridging iodine atoms are much shorter (Sb(1)-I-br, 3.0153(6)-3.0316(6) ; Sb(3)-I-br, 2.9926(6)-3.0074(6) ).

  DOI：

  10.1134/s0036023610071010
• 作为产物：
  描述：

  盐酸 、 penta(p-tolyl)antimony(V) 以 丙酮 为溶剂， 以95%的产率得到四(对甲苯基)氯化锑
  参考文献：
  名称：

  The structure of tetraarylantimony halides and tetraphenylantimony isothiocyanate

  摘要：

  利用热量滴定法获得了四丁基酞菁酸锌（II）与苯中电子供体配体相互作用的标准热力学特性。研究发现，Zn(t-Bu)4Pc 与配体（六甲基磷酰胺、吡啶、哌啶和吗啉）形成的分子配合物在很大程度上受到配位配体的电子供体和极化特性以及介质的溶解效应的影响。研究表明，四叔丁基酞菁酸锌（II）与电子供体溶剂形成热力学上稳定的分子配合物（稳定常数 Ks> 104），有利于金属酞菁酸盐在从给定溶剂中结晶时形成 α-多晶修饰。

  DOI：

  10.1007/s11173-005-0006-5

文献信息

• Synthesis and structure of osmium complexes: [Ph4Sb] 2 + [OsCl6]2–, and [p-Tol4Sb] 2 + [OsCl6]2—
  作者：V. V. Sharutin、O. K. Sharutina、V. S. Senchurin

  DOI：10.1134/s1070328416030088

  日期：2016.3

  tetra(para-tolyl)stibonium chloride in dimethyl sulfoxide gave the complexes [Ph4Sb]2[OsCl6] (I) and [p-Tol4Sb]2[OsCl6] (II). According to X-ray diffraction data, the CSbC angles in the tetrahedral cations [Ph4Sb]+ and [p-Tol4Sb]+ are 105.97(17)°–117.98(16)° in I and 103.1(3)°–118.0(2)° in II; the Sb–C bond lengths vary in the ranges of 2.090(4)–2.104(4) Å (I) and 2.086(6)–2.107(7) Å (II). In the octahedral anions

  六氯膦酸钠与四苯基或四对甲苯基氯化锡在二甲亚砜中的反应得到配合物[Ph 4 Sb] 2 [OsCl 6 ]（I）和[ p -Tol 4 Sb] 2 [OsCl 6 ]（II）。根据X射线衍射数据，四面体阳离子[Ph 4 Sb] +和[ p -Tol 4 Sb] +中的CSbC角在I和103.1（3）°中分别为105.97（17）°–117.98（16 ）° –118.0（2）°in II; Sb–C键长在2.090（4）–2.104（4）Å（I）和2.086（6）–2.107（7）Å（II）的范围内变化。在八面体阴离子[OsCl6] 2–中，Os–Cl键长为2.3364（10）–2.3435（12）Å（I）和2.3159（16）–2.3361（19）Å（II）（CIF文件CCDC。 1000137（I），1010809（II））。
• A Method for the Synthesis of Tetra(para-tolyl)stibonium Benzenesulfonate from Tetra(para-tolyl)stibonium Chloride and Benzenesulfonic Acid
  作者：V. V. Sharutin

  DOI：10.1134/s1070328423600286

  日期：2023.6

  Abstract The reaction of tetra(para-tolyl)stibonium chloride p-Tol4SbCl (I) with benzenesulfonic acid in water affords tetra(para-tolyl)stibonium benzenesulfonate p-Tol4SbOSO2Ph (II). According to the X-ray diffraction (XRD) data (CIF files CCDC nos. 2167562 and 2126493, respectively), compounds I and II have molecular structures with the distorted trigonal bipyramidal coordination of the antimony

  摘要 四(对甲苯基)氯化锑p- Tol 4 SbCl ( I )与苯磺酸在水中反应，得到四(对甲苯基)氯化锑p -Tol 4 SbOSO 2 Ph( II )。根据X射线衍射（XRD）数据（CIF文件CCDC编号分别为2167562和2126493），化合物I和II具有锑原子扭曲的三角双锥配位的分子结构。化合物I分子的几何特征：角CSbC 96.12(8)°−124.83(8)°，轴角CSbCl 174.91(6)°，距离Sb–C和Sb−Cl分别为2.107(2)–2.170(2)和2.7230(13) Å；对于化合物II的分子，角CSbC 97.72(14)°−118.77(15)°，轴角CSbCl 174.91(6)°，距离Sb–C和Sb−Cl 2.107(2)–2.170(2)和2.7230(13)分别为 Å。
• Sharutin; Sharutina; Senchurin, Russian Journal of General Chemistry, 2000, vol. 70, # 1, p. 64 - 65
  作者：Sharutin、Sharutina、Senchurin、Kovaleva、Shcherbakov、Gladyshev

  DOI：——

  日期：——
• ——
  作者：V. V. Sharutin、O. K. Sharutina、T. P. Platonova、A. P. Pakusina、A. V. Gerasimenko、E. A. Gerasimenko、B. V. Bukvetskii、D. Yu. Popov

  DOI：10.1023/a:1021830614766

  日期：——

  Tetraphenylantimony N,N-dimethyldithiocarbamate (1) and tetra-p-tolylantimony N,N-dimethyldithiocarbamate (H) were synthesized via the reaction of tetraarylantimony chloride Ar4SbCl (Ar = C6H5 or C6H4Me-4) with sodium N,N-dimethyldithiocarbamate in water. According to the X-ray diffraction data, the tetraarylantimony N,N-dimethyldithiocarbamate molecules have a distorted octahedral configuration. The Sb-S bond lengths are equal to 2.7158(5) Angstrom, 2.7440(5) Angstrom and 2.761(2) Angstrom, 2.8002(2) Angstrom for I and H, respectively.