四十八基氧硅烷 | 18816-28-9

• 物质功能分类: 有机原料 - 无机酸酯
• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 四十八基氧硅烷
• 中文别名: 硅酸四辛酯
• 英文名称: silicic acid tetraoctadecyl ester
• 英文别名: Kieselsaeure-tetraoctadecylester；Tetraoctadecylorthosilicat；Tetraoctadecyl orthosilicate；tetraoctadecyl silicate
• CAS: 18816-28-9
• 化学式: C₇₂H₁₄₈O₄Si
• 分子量: 1106.05
• InChiKey: KZGQDFWIISLOKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.53
• 重原子数：
  77
• 可旋转键数：
  72
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2920909090

SDS

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Section 1: Product Identification
Chemical Name: Tetraoctadecyloxysilane
CAS Registry Number: 18816-28-9
Formula: Si(OC18H37)4
EINECS Number: 242-596-7
Chemical Family: organosilicon compounds
Synonym: Silicic acid, tetraoctadecyl ester, tetra(tetraoctadecyl)silicate

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 18816-28-9 100% no data no data

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Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes, and respiratory tract.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes.
Eye Contact: Causes moderate irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No specific information is available on the physiological effects of ingestion.
Acute Health Affects: Irritating to skin, eyes, and respiratory tract.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: no data
Autoignition Temperature: no data
Explosion Limits: no data
Extinguishing Medium: carbon dioxide or dry powder
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion and If involved in a fire, this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Sweep up the solid and dispose of properly.

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SECTION 7: Handling and Storage
Handling and Storage: Store the material in a sealed container. Keep away from heat and moisture.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation: Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: white pwdr.
Molecular Weight: 1106.06
Melting Point: no data
Boiling Point: no data
Vapor Pressure: no data
Specific Gravity: no data
Odor: not determined
Solubility in Water: insoluble

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SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: Contact with moisture
Incompatibility: Water, strong acids, strong oxidizing agents and halogens
Decomposition Products: carbon monoxide, carbon dioxide, silicon dioxide and organic fumes.

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SECTION 11: Toxicological Information
RTECS Data: No information available in the RTECS files.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to federal, state, and local regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为产物：
  描述：

  硬脂醇 、 硅酸四乙酯 在 CH₃ONa 作用下， 以84%的产率得到四十八基氧硅烷
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 128, page 355 - 356

  摘要：

  DOI：

文献信息

• Falkenburg; Teeter; Cowan, Journal of the American Chemical Society, 1947, vol. 69, p. 487
  作者：Falkenburg、Teeter、Cowan

  DOI：——

  日期：——
• C-18 Alcohol Esters of Orthosilicic Acid
  作者：L. B. Falkenburg、H. M. Teeter、J. C. Cowan

  DOI：10.1021/ja01195a002

  日期：1947.3
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 128, page 355 - 356
  作者：

  DOI：——

  日期：——