9,9-dimethyl-N²,N²,N⁷,N⁷-tetraphenyl-10-(6-phenylpyridin-3-yl)-9,10-dihydroacridine-2,7-diamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 9,9-dimethyl-N²,N²,N⁷,N⁷-tetraphenyl-10-(6-phenylpyridin-3-yl)-9,10-dihydroacridine-2,7-diamine
• 英文别名: 9,9-dimethyl-2-N,2-N,7-N,7-N-tetraphenyl-10-(6-phenylpyridin-3-yl)acridine-2,7-diamine
• 化学式: C₅₀H₄₀N₄
• 分子量: 696.894
• InChiKey: UUHXRFFRCNPUHX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.1
• 重原子数：
  54
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  22.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N-苯基邻氨基苯甲酸 在 tris-(dibenzylideneacetone)dipalladium(0) 、 N-溴代丁二酰亚胺(NBS) 、 磷酸 、 potassium tert-butylate 、 potassium carbonate 、 2-二环己基磷-2,4,6-三异丙基联苯 作用下， 以 四氢呋喃 、 二氯甲烷 、 丙酮 、 甲苯 为溶剂， 反应 57.17h， 生成 9,9-dimethyl-N²,N²,N⁷,N⁷-tetraphenyl-10-(6-phenylpyridin-3-yl)-9,10-dihydroacridine-2,7-diamine
  参考文献：
  名称：

  전계발광 디바이스용 발광 성분으로서의 N-아릴-하이드로아크리딘

  摘要：

  具有三环核并具有以下结构（I）的化合物中，其中Ar是C-C芳基，至少有一个芳香族环原子是氮；X是O、S或CRR；R、R、R、R、R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基；R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基，或者连接到氮原子的R和R基团通过单键、O、S或CRR形成单一氮含有取代基；R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基；R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基；但是，Ar不包含连接到具有两个以上芳环环氮原子的三环核的芳环。

  公开号：

  KR20180030860A

文献信息

• Photopatterned growth of electronically active brush polymers for light emitting diode displays
  申请人：The Regents of the University of California

  公开号：US10228619B2

  公开（公告）日：2019-03-12

  Disclosed herein is an article comprising a substrate; a first region having a first brush polymer chemically bonded to the substrate; where the first brush polymer comprises repeat units of a first ethylenically unsaturated monomer and a second ethylenically unsaturated monomer; where the first ethylenically unsaturated monomer comprises a first electroactive moiety and where the second ethylenically unsaturated monomer comprises a second electroactive moiety that is different from the first electroactive moiety; where at least one of the first electroactive moiety or the second electroactive moiety is an emitter moiety and where the repeat units of the first ethylenically unsaturated monomer are covalently bonded to repeat units of the second ethylenically unsaturated monomer.

  本文公开了一种物品，该物品包括基材；第一区域，该区域具有与基材化学键合的第一电刷聚合物；其中第一电刷聚合物包括第一乙烯基不饱和单体和第二乙烯基不饱和单体的重复单元；第一乙烯基不饱和单体包括第一电活性分子，第二乙烯基不饱和单体包括不同于第一电活性分子的第二电活性分子；第一电活性分子或第二电活性分子中至少有一个是发射分子，第一乙烯基不饱和单体的重复单元与第二乙烯基不饱和单体的重复单元共价键合。
• N-ARYL-HYDROACRIDINES AS LIGHT EMITTING ELEMENTS FOR ELECTROLUMINESCENT DEVICES
  申请人：Dow Global Technologies LLC

  公开号：US20180127403A1

  公开（公告）日：2018-05-10

  A compound having a tricyclic nucleus and having formula (I) wherein Ar is C 3 -C 25 aryl in which at least one aromatic ring atom is nitrogen; X is O, S or CR 9 R 10 ; R 1 , R 2 , R 3 , R 4 , R 5 and R 6 independently are hydrogen, deuterium, C 1 -C 12 alkyl, C 4 -C 12 aryl or C 2 -C 12 alkenyl; R 7 and R 8 independently are hydrogen, deuterium, C 1 -C 12 alkyl, C 4 -C 12 aryl or C 2 -C 12 alkenyl or R 7 and R 8 groups attached to a nitrogen atom are joined by a single bond, O, S or CR 11 R 12 to form a single nitrogen-containing substituent; R 9 and R 10 independently are hydrogen, deuterium, C 1 -C 12 alkyl, C 4 -C 12 aryl or C 2 -C 12 alkenyl; and R 11 and R 12 independently are hydrogen, deuterium, C 1 -C 12 alkyl, C 4 -C 12 aryl or C 2 -C 12 alkenyl; provided that Ar does not contain an aromatic ring attached to the tricyclic nucleus which contains more than two aromatic ring nitrogen atoms.
• [EN] N-ARYL-HYDROACRIDINES AS LIGHT EMITTING ELEMENTS FOR ELECTROLUMINESCENT DEVICES<br/>[FR] N-ARYL-HYDROACRIDINES COMME ÉLÉMENTS ÉMETTANT DE LA LUMIÈRE POUR DISPOSITIFS ÉLECTROLUMINESCENTS
  申请人：DOW GLOBAL TECHNOLOGIES LLC

  公开号：WO2017014951A1

  公开（公告）日：2017-01-26

  A compound having a tricyclic nucleus and having formula (I) (I) wherein Ar is C3-C25 aryl in which at least one aromatic ring atom is nitrogen; X is O, S or CR9R10; R1, R2, R3, R4, R5 and R6 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl; R7 and R8 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl or R7 and R8 groups attached to a nitrogen atom are joined by a single bond, O, S or CR11R12 to form a single nitrogen-containing substituent; R9 and R10 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl; and R11 and R12 independently are hydrogen, deuterium, C1-C12 alkyl, C4-C12 aryl or C2-C12 alkenyl; provided that Ar does not contain an aromatic ring attached to the tricyclic nucleus which contains more than two aromatic ring nitrogen atoms.
• 전계발광 디바이스용 발광 성분으로서의 N-아릴-하이드로아크리딘
  申请人：Dow Global Technologies LLC 다우 글로벌 테크놀로지스 엘엘씨(520110293509)

  公开号：KR20180030860A

  公开（公告）日：2018-03-26

  삼환형 핵을 가지며 하기 식 (I)을 갖는 화합물 식 중, Ar은 C-C 아릴이되, 적어도 1개의 방향족 고리 원자는 질소이고; X는 O, S 또는 CRR이고; R, R, R, R, R 및 R는 독립적으로 수소, 중수소, C-C 알킬, C-C 아릴 또는 C-C 알케닐이고; R 및 R는 독립적으로 수소, 중수소, C-C 알킬, C-C 아릴 또는 C-C 알케닐이거나, 또는 질소 원자에 부착된 R 및 R 그룹은 단일 결합, O, S 또는 CRR에 의해 연결되어 단일 질소-함유 치환체를 형성하고; R 및 R는 독립적으로 수소, 중수소, C-C 알킬, C-C 아릴 또는 C-C 알케닐이고; 그리고 R 및 R는 독립적으로 수소, 중수소, C-C 알킬, C-C 아릴 또는 C-C 알케닐이고; 단, Ar은 2개 초과의 방향족 고리 질소 원자를 함유하는 삼환형 핵에 부착된 방향족 고리를 함유하지 않는다.

  具有三环核并具有以下结构（I）的化合物中，其中Ar是C-C芳基，至少有一个芳香族环原子是氮；X是O、S或CRR；R、R、R、R、R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基；R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基，或者连接到氮原子的R和R基团通过单键、O、S或CRR形成单一氮含有取代基；R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基；R和R独立地是氢、双氢、C-C烷基、C-C芳基或C-C烯基；但是，Ar不包含连接到具有两个以上芳环环氮原子的三环核的芳环。