tetramethoxytriptycene quinone

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: tetramethoxytriptycene quinone
• 英文别名: 4,5,10,13-Tetramethoxypentacyclo[6.6.6.02,7.09,14.015,20]icosa-2(7),4,9,11,13,15,17,19-octaene-3,6-dione；4,5,10,13-tetramethoxypentacyclo[6.6.6.02,7.09,14.015,20]icosa-2(7),4,9,11,13,15,17,19-octaene-3,6-dione
• 化学式: C₂₄H₂₀O₆
• 分子量: 404.419
• InChiKey: DOGKMVJGEDZJLH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  甲醇 、 dimethoxytriptycene chloroquinone 在 sodium methylate 作用下， 以10%的产率得到tetramethoxypentiptycene quinone
  参考文献：
  名称：

  The reaction of triptycene haloquinones with alkoxides. An unusual route to pentiptycene quinones

  摘要：

  Triptycene haloquinones 3 react with sodium alkoxides in refluxing alcohol to afford, besides the expected substitution products, pentiptycene quinone 4. This approach to 4 is compared with a Diels-Alder strategy to the same compound. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00755-x

文献信息

• The reaction of triptycene haloquinones with alkoxides. An unusual route to pentiptycene quinones
  作者：Spyros Spyroudis、Nikoletta Xanthopoulou

  DOI：10.1016/s0040-4039(03)00755-x

  日期：2003.5

  Triptycene haloquinones 3 react with sodium alkoxides in refluxing alcohol to afford, besides the expected substitution products, pentiptycene quinone 4. This approach to 4 is compared with a Diels-Alder strategy to the same compound. (C) 2003 Elsevier Science Ltd. All rights reserved.